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The preparation of LaSr3Fe3O10 − δ and its electrochemical performance

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Abstract

LaSr3Fe3O10 − δ powders were synthesized by hydrothermal method and characterized by XRD and SEM. The XRD patterns showed that the sample calcined at 1000 °C was single phase and the sample calcined at 900 °C had tiny amount of LaSrFeO4 phase. The single-phase LaSr3Fe3O10 − δ powders were used to prepare test electrode. The capacitive behaviors of LaSr3Fe3O10 − δ electrode were analyzed by cyclic voltammetry, galvanostatic charge-discharge techniques, and electrochemical impedance spectroscopy. The electrochemical results showed a capacity as high as 470 F g−1 at a scan rate of 1 mV s−1 and 380 F g−1 at a charge-discharge current density of 0.1 A g−1 in 6 M KOH solution. The electrode showed good cyclic stability since its capacitive retention is 87.1% after 1000 charge-discharge cycles. The electrochemical performances suggest that LaSr3Fe3O10 − δ could be a potential candidate as a capacitive electrode material.

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Acknowledgements

This work was financially supported by the Natural Science Foundation of China (no. 51062015) and Science and Technology Program of Jiangxi Education Department, China (no. GJJ14535).

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Correspondence to Guoguang Zhang.

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Huang, L., Li, Q., Zhang, G. et al. The preparation of LaSr3Fe3O10 − δ and its electrochemical performance. J Solid State Electrochem 21, 1343–1348 (2017). https://doi.org/10.1007/s10008-016-3493-z

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  • DOI: https://doi.org/10.1007/s10008-016-3493-z

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