Abstract
LaSr3Fe3O10 − δ powders were synthesized by hydrothermal method and characterized by XRD and SEM. The XRD patterns showed that the sample calcined at 1000 °C was single phase and the sample calcined at 900 °C had tiny amount of LaSrFeO4 phase. The single-phase LaSr3Fe3O10 − δ powders were used to prepare test electrode. The capacitive behaviors of LaSr3Fe3O10 − δ electrode were analyzed by cyclic voltammetry, galvanostatic charge-discharge techniques, and electrochemical impedance spectroscopy. The electrochemical results showed a capacity as high as 470 F g−1 at a scan rate of 1 mV s−1 and 380 F g−1 at a charge-discharge current density of 0.1 A g−1 in 6 M KOH solution. The electrode showed good cyclic stability since its capacitive retention is 87.1% after 1000 charge-discharge cycles. The electrochemical performances suggest that LaSr3Fe3O10 − δ could be a potential candidate as a capacitive electrode material.
Similar content being viewed by others
References
Yang PH, Sun P, Mai WJ (2016) Electrochromic energy storage devices. Mater Today 19:394–402
Xiong P, Zhu JW, Wang X (2015) Recent advances on multi-component hybrid nanostructures for electrochemical capacitors. J Power Sources 294:31–50
Yi H, Wang HW, Jing YT, Peng TQ (2015) Asymmetric supercapacitors based on carbon nanotubes@NiO ultrathin nanosheets core-shell composites and MOF-derived porous carbon polyhedrons with super long cycle life. J Power Sources 285:281–290
Inagaki M, Konno H, Tanaike O (2010) Carbon materials for electrochemical capacitors. J Power Sources 195:7880–7903
Abioye AM, Ani FN (2015) Recent development in the production of activated carbon electrodes from agricultural waste biomass for supercapacitors: a review. Renew Sust Energ Rev 52:1282–1293
Xing BL, Huang GX, Chen LJ, Zhang GX, Xu B (2012) Current situation and prospect of research on electrode materials for supercapacitor. Mater Rev Rev 26:21–25
Wang G, Zhang L, Zhang J (2012) A review of electrode materials for supercapacitors. Chem Soc Rev 41:797–828
Zhang Y, Feng H, Wu X, Wang L, Zhang A, Xia T, Dong H, Li X, Zhang L (2009) Progress of electrochemical capacitor electrode materials: a review. Int J Hydrog Energy 34:4889–4899
Gonzalez A, Goikolea E, Barrena JA, Mysyk R (2016) Review on supercapacitors: technologies and materials. Renew Sust Energ Rev 58:1189–1206
Jiang J, Li Y, Liu J, Huang X, Yuan C, Lou XW (2012) Recent advances in metal oxide-based electrode architecture design for electrochemical energy storage. Adv Mater 24:5166–5180
Wang K, Wu HP, Meng YN, Wei ZX (2014) Conducting polymer nanowire arrays for high performance supercapacitors. Small 10:12–31
Xu Y, Bao YY, Du LF, Cao DX, Wang GL (2013) The electrochemical capacitance performance of La1-xSrxCoO3 perovskites. J Electrochem Soc 19:174–177
Mefford JT, Hardin WG, Dai S, Johnston KP, Stevenson KJ (2014) Anion charge storage through oxygen intercalation in LaMnO3 perovskite pseudocapacitor electrodes. Nat Mater 13:726–732
Cao Y, Lin BP, Sun Y, Yang H, Zhang XQ (2015) Sr-doped lanthanum nickelate nanofibers for high energy density supercapacitors. Electrochim Acta 174:41–50
Cao Y, Lin BP, Sun Y, Yang H, Zhang XQ (2015) Symmetric/asymmetric supercapacitor based on the perovskite-type lanthanum cobaltate nanofibers with Sr-substitution. Electrochim Acta 178:398–406
Chaianansutcharit S, Hyodo K, Hyodo J, Ju YW, Ishihara T (2015) Ruddlesden popper oxides of LnSr3Fe3O10-δ (Ln = La, Pr, Nd, Sm, Eu, and Gd) as active cathodes for low temperature solid oxide fuel cells. J Mater Chem A 3:12357–12366
Zhang GG, Li Q, Cao JQ, Cui MJ (2010) Defect structure and electrical properties of LaSr3Fe3O10–δ. J Rare Earth 28:270–273
Armstrong T, Prado F, Manthiram A (2001) Synthesis, crystal chemistry and oxygen permeation properties of LaSr3Fe3-xCoxO10 (0 ≤ x ≤ 1.5). Solid State Ionics 140:89–96
Lee JY, Swinnea JS, Steinfink H, Reief WM, Pei S, Jorgensen JD (1993) The crystal chemistry and the physical properties of the triple layer perovskite intergrowths of LaSr3Fe3O10-δ and LaSr3(Fe3-xAlx)O10-δ. J Solid State Chem 103:1–15
Kim JH, Lee KT, Kim YN, Manthiram A (2011) Crystal chemistry and electrochemical properties of Ln(Sr,Ca)3(Fe,Co)3O10 intergrowth oxide cathodes for solid oxide fuel cells. J Mater Chem 21:2482–2488
Cui MJ, Zhang GG, Li Q, Liu T (2007) Studies on the structure and oxygen nonstoichiometry of LaSr3Fe3O10-δ mixed conductor. J Nanchang Hangkong University (Natural Science) 21:84–89
Takeguchi T, Yamanaka T, Takahashi H, Watanabe H, Kuroki T, Nakanishi H, Orikasa Y, Uchimoto Y, Takano H, Ohguri N, Matsuda M, Murota T, Uosaki K, Ueda W (2013) Layered perovskite oxide: a reversible air electrode for oxygen evolution/reduction in rechargeable metal-air batteries. J Am Chem Soc 135:11125–11130
Cheng JP, Li M, Zhang WF, Wu JS, Liu F, Zhang XB (2013) Evolution of cobalt hydroxide from 2D microplatelets to 3D hierarchical structure mediated by precursor concentration. RSC Adv 3:13304
Rauda IE, Augustyn V, Dunn B, Tolbert SH (2013) Enhancing pseudocapacitive charge storage in polymer templated mesoporous materials. Acc Chem Res 46:1113–1124
Alia GAM, Wahba OAG, Hassan AM, Fouad OAD, Chong KF (2015) Calcium-based nanosized mixed metal oxides for supercapacitor application. Ceram Int 41:8230–8234
Rai A, Sharma AL, Thakur AK (2014) Evaluation of aluminium doped lanthanum ferrite based electrodes for supercapacitor design. Solid State Ionics 262:230–233
Zhu L, Liu Y, Su C, Zhou W, Liu ML, Shao ZP (2016) Perovskite SrCo0.9Nb0.1O3−δ as an anion-intercalated electrode material for supercapacitors with ultrahigh volumetric energy density. Angew Chem 128:9728–9731
CaoY LBP, Sun Y, Yang H, Zhang XQ (2015) Structure, morphology and electrochemical properties of LaxSr1-xCo0.1Mn0.9O3−δ perovskite nanofibers prepared by electrospinning method. J Alloys Compd 624:31–39
Fan M, Ren B, Yu L, Song D, Liu Q, Liu J, Wang J, Jing X, Liu L (2015) Facile synthesis of Co3O4 nanowires grown on hollow NiO microspheres with superior electrochemical performance. Electrochim Acta 166:168–173
Vidhyadharan B, Zain NKM, Misnon II, Aziz RA, Ismail J, Yusoff MM, Jose R (2014) High performance supercapacitor electrodes from electrospun nickel oxide nanowires. J Alloys Compd 610:143–150
Kalambate PK, Dar RA, Karna SP, Srivastav AK (2015) High performance supercapacitor based on graphene-silver nanoparticles-polypyrrole nanocomposite coated on glassy carbon electrode. J Power Sources 276:262–270
Wang RY, Li Q, Cheng LL, Lia HL, Wang BY, Zhao XS, Guo PZ (2014) Electrochemical properties of manganese ferrite-based supercapacitors in aqueous electrolyte: the effect of ionic radius. Colloids and Surfaces A: Physicochem Eng Aspects 457:94–99
Wang XW, Zhu QQ, Wang XE, Zhang HC, Zhang JJ, Wang LF (2016) Structural and electrochemical properties of La0.85Sr0.15MnO3 powder as an electrode material for supercapacitor. J Alloys Compd 675:195–200
Acknowledgements
This work was financially supported by the Natural Science Foundation of China (no. 51062015) and Science and Technology Program of Jiangxi Education Department, China (no. GJJ14535).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Huang, L., Li, Q., Zhang, G. et al. The preparation of LaSr3Fe3O10 − δ and its electrochemical performance. J Solid State Electrochem 21, 1343–1348 (2017). https://doi.org/10.1007/s10008-016-3493-z
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10008-016-3493-z