Skip to main content

Anodic deposition of lead dioxide at Nafion® covered gold electrode

Journal of Solid State Electrochemistry volume 20, pages 3053–3059 (2016)Cite this article

Abstract

Anodic electrodeposition of lead dioxide at the bare and Nafion® covered gold electrode was studied by cyclic voltammetry and chronoamperometry. The results showed that Nafion® layer has a favourable effect on the efficiency of the deposition process which was caused by both thermodynamic and kinetic reasons. Electrodeposition process at Nafion® covered gold electrode goes via Pb(III) intermediate species which are stabilized within Nafion® membrane. The final PbO2 deposit crystallizes in tetragonal β-PbO2 form.

This is a preview of subscription content, access via your institution.

Access options

Buy single article

Instant access to the full article PDF.

USD 39.95

Price includes VAT (USA)
Tax calculation will be finalised during checkout.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Figure 7

References

  1. Fleischmann M, Mansfield JR, Thirsk HR, Wilson HG (1967) Electrochim Acta 12:967–982

    CAS  Article  Google Scholar 

  2. Fleischmann M, Liler M (1958) Trans Faraday Soc 54:1370–1381

    CAS  Article  Google Scholar 

  3. Fleischmann M, Thirsk HR (1955) Trans Faraday Soc 51:71–95

    CAS  Article  Google Scholar 

  4. Bewick A, Fleischmann M, Thirsk HR (1962) Trans Faraday Soc 58:2200–2216

    CAS  Article  Google Scholar 

  5. Armstrong RD, Fleischmann F, Thirsk HR (1966) J Electroanal Chem 11:208–223

    CAS  Google Scholar 

  6. Fleishmann M, Thirsk HR (1963) In: Delahay P (Ed) advances in electrochemistry and chemical engineering, vol 3, Chap. 3. Wiley Interscience, New York

    Google Scholar 

  7. Abyaneh MY (1982) Electrochim Acta 27:1329–1334

    CAS  Article  Google Scholar 

  8. Abyaneh MY (1986) J Electroanal Chem 209:1–10

    CAS  Article  Google Scholar 

  9. Abyaneh MY (1991) Electrochim Acta 36:727–732

    CAS  Article  Google Scholar 

  10. Abyaneh MY, Saez V, Gonzalez-Garcia J, Mason TJ (2010) Electrochim Acta 55:3572–3579

    CAS  Article  Google Scholar 

  11. Bosco E, Rangarajan SK (1982) J Electroanal Chem 134:225–241

    CAS  Article  Google Scholar 

  12. Gunawardena GA, Hills GJ, Montenegro I, Scharifker BR (1982) J Electroanal Chem 138:225–239

    CAS  Article  Google Scholar 

  13. Scharifker BR, Mostany J (1984) J Electroanal Chem 177:13–23

    CAS  Article  Google Scholar 

  14. Sluyters-Rehbach M, Wijenberg JHOJ, Bosco E, Sluyters JH (1987) J Electroanal Chem 236(1987):1–20

    CAS  Article  Google Scholar 

  15. Mirkin MV, Nilov AP (1990) J Electroanal Chem 283:35–51

    CAS  Article  Google Scholar 

  16. Harrinson JA, Thirsk HA (1972) In: A guide to the study of the electrode kinetics, chap. 3, Academic Press, New York.

    Google Scholar 

  17. Pavlov D, Balkanov I, Halachev T, Rachev P (1989) J Electrochem Soc 136:3189–3197

    CAS  Article  Google Scholar 

  18. Ruetschi P (1992) J Electrochem Soc 139:1347–1351

    CAS  Article  Google Scholar 

  19. Rand DAJ (1987) J Power Sources 21:B1

    Article  Google Scholar 

  20. Hui BS, Huber CO (1982) Anal Chim Acta 134:211–218

    CAS  Article  Google Scholar 

  21. Yeo IH, Kim S, Jacobson RA, Johnson DC (1989) J Electrochem Soc 136:1395–1401

    CAS  Article  Google Scholar 

  22. Polcaro AM, Palmas S, Renoldi F, Mascia M (1999) J Appl Electrochem 29:147–151

    CAS  Article  Google Scholar 

  23. Tahar NB, Savall A (1999) J New Mater Electrochem Syst 2:19–26

    CAS  Google Scholar 

  24. Wang F, Xiao S, Hou Y, Hu C, Liu L, Wu Y (2013) RSC Adv 3:13059–13084

    CAS  Article  Google Scholar 

  25. Simon P, Gogotsi Y (2008) Nat Mater 7:845–854

    CAS  Article  Google Scholar 

  26. Kriston Á, Inzelt G (2007) J Appl Electrochem 38:415–424

    Article  Google Scholar 

  27. Ul Hassan N, Kilic M, Okumus E, Tunaboylu B, Soydan AM (2016) J Electrochem Sci Eng 6:9–16

    Article  Google Scholar 

  28. Sopčić S, Kraljić Roković M, Mandić Z (2012) J Electrochem Sci Eng 2:41–52

    Google Scholar 

  29. Sopčić S, Mandić Z, Kraljić Roković M (2014) Acta Chim Slov 61:272–279

    Google Scholar 

  30. Eladeb B, Bonnet C, Favre E, Lapicque F (2012) J Electrochem Sci Eng 2:211–221

    CAS  Google Scholar 

  31. Veseli A, Hajrizi A, Arbneshi T, Kalcher K (2012) J Electrochem Sci Eng 2:199–210

    CAS  Google Scholar 

  32. Velichenko AB, Luk’yanenko TV, Nikolenko NV, Amadelli R, Danilov FI (2007) Russ J Electrochem 43:118–120

    CAS  Article  Google Scholar 

  33. Velichenko AB, Devilliers D (2007) J Fluor Chem 128:269–276

    CAS  Article  Google Scholar 

  34. Velichenko AB, Girenko DV, Danilov FI (1995) Electrochim Acta 40:2803–2807

    CAS  Article  Google Scholar 

  35. Chang H, Johnson DC (1989) J Electrochem Soc 136:23–27

    CAS  Article  Google Scholar 

  36. Gilroy D, Stevens R (1980) J Appl Electrochem 10:511–525

    CAS  Article  Google Scholar 

  37. Li LJ, Fleischmann F, Peter LM (1989) Electrochim Acta 34:459–474

    CAS  Article  Google Scholar 

  38. Ramamurthy AC, Kuwana T (1982) J Electroanal Chem 135:243–255

    CAS  Article  Google Scholar 

  39. Laitnen HA, Watkins NH (1976) J Electrochem Soc 123:804–809

    Article  Google Scholar 

  40. Gonzalez-Garcia J, Gallud F, Iniesta J, Montiel V, Aldaz A, Lasia A (2000) J Electrochem Soc 147:2969–2974

    CAS  Article  Google Scholar 

Download references

Acknowledgments

The authors are indebted to Professor György Inzelt for many valuable and fruitful discussions led during our cooperation in recent years. The support of Croatian Science Foundation under the project ESUP-CAP (IP-11-2013-8825) is greatly acknowledged.

Author information

Authors and Affiliations

  1. Rudjer Bošković Institute, Bijenička cesta 54, 10000, Zagreb, Croatia

    Sanja Burazer

  2. Faculty of Chemical Engineering and Technology, University of Zagreb, Marulićev trg 19, -10000, Zagreb, HR, Croatia

    Suzana Sopčić & Zoran Mandić

Authors
  1. Sanja Burazer
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Suzana Sopčić
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Zoran Mandić
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Zoran Mandić.

Rights and permissions

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Burazer, S., Sopčić, S. & Mandić, Z. Anodic deposition of lead dioxide at Nafion® covered gold electrode. J Solid State Electrochem 20, 3053–3059 (2016). https://doi.org/10.1007/s10008-016-3261-0

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10008-016-3261-0

Keywords

  • Gold Electrode
  • PbO2
  • Rotate Disk Electrode
  • Oxygen Evolution Reaction
  • Electrodeposition Process