Abstract
The electrical properties of bulk and grain boundaries of donor-doped barium titanate ceramics have been characterized as a function of temperature (50–350 °C) and voltage load (up to 140 V) by application of impedance spectroscopy. Both the grain boundary resistivities and the steepness of the R-T characteristics are diminished significantly with increasing voltage load. While the grain boundary resistances are strongly affected by the applied electric field, the grain boundary capacitance is almost independent of the dc-bias. The non-linearity of the resistivity of n-conducting BaTiO3 has been investigated in detail by impedance spectroscopy as a function of dc-bias and a small ac-voltage signal as well as impedance measurements with high ac-voltage amplitudes (zero bias). The non-linear current response to high ac-voltage amplitudes at low frequencies (0.01 Hz) has been determined experimentally and analyzed by means of fast Fourier transform (FFT) as well as Lissajous analyses. Moreover, a finite element model (FEM) has been developed for the simulation of the ac-current response. The FEM calculations are in close agreement with the experimentally determined data for the variation of the grain boundary resistance with ac-voltage amplitude.
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References
Preis W, Sitte W (2015) Electrical properties of grain boundaries in interfacially controlled functional ceramics. J Electroceram. doi:10.1007/s10832-014-9972-7
Heywang W (1964) J Am Ceram Soc 47:484–490
Jonker GH (1964) Solid State Electron 7:895–903
Kulwicki BM, Purdes AJ (1970) Ferroelectrics 1:253–263
Preis W, Bürgermeister A, Sitte W, Supancic P (2004) Solid State Ionics 173:69–75
Preis W, Sitte W (2006) Solid State Ionics 177:2549–2553
Preis W, Sitte W (2011) J Electroceram 27:83–88
Daniels J, Wernicke R (1976) Philips Res Rep 31:544–559
Preis W (2009) Monatsh Chem 140:1059–1068
Frömling T, Hou J, Preis W, Sitte W, Hutter H, Fleig J (2011) J Appl Phys 110:043531
Morrison FD, Coates AM, Sinclair DC, West AR (2001) J Electroceram 6:219–232
Ting C-J, Peng C-J, Lu H-Y, Wu S-T (1990) J Am Ceram Soc 73:329–334
Waser R, Hagenbeck R (2000) Acta Mater 48:797–825
Vollmann M, Waser R (1997) J Electroceram 1:51–64
Preis W, Sitte W (2014) Solid State Ionics 262:486–489
Barsoukov E, Macdonald JR (2005) Impedance spectroscopy, 2nd edn. Wiley, Hoboken
Orazem ME, Tribollet B (2008) Electrochemical impedance spectroscopy. Wiley, Hoboken
Boukamp BA (2004) Solid State Ionics 169:65–73
Preis W, Sitte W (2006) Solid State Ionics 177:3093–3098
Kirstein K, Reichmann K, Preis W, Mitsche S (2011) J Eur Ceram Soc 31:2339–2349
Heinen B, Waser R (1998) J Mater Sci 33:4603–4608
Fleig J, Maier J (1999) J Am Ceram Soc 82:3485–3493
Adler SB (2002) J Electrochem Soc 149:E166–E172
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Financial support by the Austrian Federal Government (in particular from Bundesministerium für Verkehr, Innovation und Technologie and Bundesministerium für Wissenschaft, Forschung und Wirtschaft) represented by Österreichische Forschungsförderungsgesellschaft mbH and the Styrian and the Tyrolean Provincial Government, represented by Steirische Wirtschaftsförderungsgesellschaft mbH and Standortagentur Tirol, within the framework of the COMET Funding Programme is gratefully acknowledged.
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Preis, W., Hofer, J. & Sitte, W. Characterization of electrical properties of n-conducting barium titanate as a function of dc-bias and ac-voltage amplitude by application of impedance spectroscopy. J Solid State Electrochem 19, 2439–2444 (2015). https://doi.org/10.1007/s10008-015-2896-6
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DOI: https://doi.org/10.1007/s10008-015-2896-6