Abstract
This paper reports the formation of hybrid polyoxometalate-porphyrin copolymeric films obtained by the electro-oxidation of zinc-β-octaethylporphyrin (ZnOEP) in the presence of a functionalized Dawson-type polyoxometalate bearing two pyridyl groups (POMdbme3,3, Py-POM-Py) which will be compared to the copolymer obtained from ZnOEP and a dipyridyl compound without POM (ibme3,3). The resulting film has been characterized by UV-visible absorption spectroscopy, X-ray photoelectron spectroscopy, and atomic force microscopy. Electrochemical quartz crystal microbalance was employed to investigate the poly-porphyrin-POMs deposition mass.
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Acknowledgments
We thank CNRS, the University of Strasbourg (France), Université Paris-Descartes (Paris, France), Université Pierre et Marie Curie (Paris, France), Institut de Chimie des Substances Naturelles (Gif sur Yvette, France), ECE Paris Ecole d’Ingénieurs (France), and Fudan University (Shanghai, China) for funding of this work. We also thank the Université de Strasbourg for the projet “Idex Attractivité 2012” for supporting one part of this research, as well as the Oversea Study Program of Guangzhou Elite Project (GEP) for the Ph.D. grant to Zhaohui Huo. This work was also supported by Fund of senior visiting professor of Fudan University.
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Huo, Z., Azcarate, I., Farha, R. et al. Copolymeric films obtained by electropolymerization of porphyrins and dipyridyl-spacers including Dawson-type polyoxometalates. J Solid State Electrochem 19, 2611–2621 (2015). https://doi.org/10.1007/s10008-015-2828-5
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DOI: https://doi.org/10.1007/s10008-015-2828-5