Abstract
The cathodic processes of cobalt ion in ionic liquids consisting in binary mixtures of choline chloride (ChCl) with urea, ethylene glycol, malonic acid or oxalic acid were investigated using cyclic voltammetry and electrochemical impedance spectroscopy. The as-received hexahydrate cobalt chloride has been the precursor of cobalt ionic species. It was found that the reduction mechanism of Co2+ in ChCl-urea and ChCl-ethylene glycol is a quasi-reversible (or with high degree of irreversibility at high scan rate) and diffusion controlled process, whereas in ChCl-carboxilic acid solvents the cathodic process of Co2+ is overlapped with reduction of protons. By using Pt and vitreous carbon electrodes, one has computed the value for the Co2+ diffusion coefficient in ChCl-urea at 80 °C; in comparison with values obtained in aqueous solutions, this is up to two orders of magnitude lower. The paper also describes preliminary experiments concerning electrodeposition of cobalt thin films on copper substrate from the four ionic liquid analogue solvents containing choline chloride. The crystalline morphology and structural constitution of Co deposits were examined by scanning electron microscopy, energy dispersive X-ray spectroscopy, and X-ray diffraction. Good results regarding the quality and cobalt content in films were obtained for Co deposits using ChCl-urea or ChCl-ethylene glycol mixtures as solvents. The behaviour of Co films grown from these media was typical for a ferromagnetic material.
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Mendoza-Huizar LH, Rios-Reyes CH (2011) J Solid State Electrochem 15(4):737–745
Mendoza-Huizar LH, Rios-Reyes CH (2012) J Solid State Electrochem 16(9):2899–2906
Mendoza-Huizar LH, Rios-Reyes CH (2013) Cent Eur J Chem 11(8):1381–1392
Rios-Reyes CH, Mendoza-Huizar LH, Reyes-Cruz VE, Rodriguez MAV (2013) Quim Nova 36(7):978–983
Prasad KA, Giridhar P, Ravidran V, Muralidharan VS (2001) J Solid State Electrochem 6:63–68
Krastev I, Dobrovolska T, Lacnjevac U, Nineva S (2012) J Solid State Electrochem 16:3449–3456
Zhou QF, Lu LY, Yu LN, Xu XG, Jiang Y (2013) Electrochim Acta 106:258–263
Cui CQ, Jiang SP, Tseung ACC (1991) J Electrochem Soc 138:94–100
Suzaki A, Watanabe T (2000) J Jpn Inst Metals 64(10):869–877
Yamamoto H, Morishita M, Mizuta Y, Masubuchi A (2012) Surf Coat Technol 206:3415–3420
Carlin RT, De Long HC, Fuller J, Trulove PC (1998) J Electrochem Soc 145:1598–1607
Chen P-Y, Sun I-W (2001) Electrochim Acta 46:1169–1177
An MZ, Yang PX, Su CN, Nishikata A, Tsuru T (2008) Chin J Chem 26(7):1219–1224
Freyland W, Zell CA, El Abedin SZ, Endres F (2003) Electrochim Acta 48(20–22):3053–3061
Lin LG, Yan JW, Wang Y, Fu YC, Mao BW (2006) J Exp Nanosci 1(3):269–278
Schaltin S, Nockeman P, Thijs B, Binnemans K, Fransaer J (2007) Electrochem Solid State Lett 10:D104–D107
Yang PX, An MZ, Su CN, Wang FP (2008) Electrochim Acta 54:763–767
Su CN, An MZ, Yang PX, Gu HW, Guo XH (2010) Appl Surf Sci 256:4888–4893
Ali MR, Nishikata A, Tsuru T (2005) Indian J Chem Technol 12:648–653
Katayama Y, Fukui R, Miura T (2007) J Electrochem Soc 154(10):D534–D537
Katayama Y, Fukui R, Miura T (2007) ECS Trans 3:287–295
Fukui R, Katayama Y, Miura T (2011) Electrochim Acta 56:1190–1196
Ispas A, Buschbeck M, Pitula S, Mudring A, Uhlemann M, Bund A, Endres F (2009) ECS Trans 16(45):119–127
Abbott AP, Davies DL, Capper G, Rasheed RK, Tambyrajah V (2004) Ionic liquids and their use as solvents, US Patent 2004/0097755 A1 (May 20, 2004)
Yue D, Jia Y, Yao Y, Sun J, Jing Y (2012) Electrochim Acta 65:30–36
Gomez E, Cojocaru P, Magagnin L, Valles E (2011) J Electroanal Chem 658:18–24
Cojocaru P, Magagnin L, Gomez E, Valles E (2011) Mater Lett 65:3597–3600
Guillamat P, Cortes M, Valles E, Gomez E (2012) Surf Coat Technol 206:4439–4448
Li M, Wang Z, Reddy RG (2014) Electrochim Acta 123(20):325–331
Abbott AP, Capper G, Davies DL, Rasheed R (2004) Chem Eur J 10:3769–3774
Abbott AP, Davies GL, Capper G, Rasheed RK, Tambyrajah V (2007) Ionic liquids and their use, US Patent No. 7,196,22 (March 27, 2007)
Srivastava M, Yoganandan G, William Grips VK (2012) Surf Eng 28(6):424–429
You YH, Gu CD, Wang XL, Tu JP (2012) Surf Coat Technol 206:3632–3638
Ciocirlan O, Iulian O, Croitoru O (2010) Rev Chim (Bucharest) 61(8):721–723
Mares (Badea) ML, PhD Thesis, Univ. POLITEHNICA of Bucharest, 2013
Bard AJ, Faulkner LR (2001) Electrochemical methods: fundamentals and applications, 2nd edn. John Wiley, New York
Fukui R, Katayama Y, Miura T (2005) Electrochemistry 73:567–569
Cui CQ, Jiang SP, Tseung ACC (1990) J Electrochem Soc 137(11):3418–3423
Ribeiro ACF, Lobo VMM, Natividade JJS (2002) J Chem Eng Data 47:539–541
Ribeiro ACF, Valente AJM, Costa DO, Simoes SMN, Pereira RFP, Lobo VMM, Esteso MA (2010) Electrochim Acta 55(15):4483–4487
Kaye & Laby Tables of physical and chemical constants, chapter 2.6.6 Magnetic properties of materials, NPL (National Physical Laboratory USA), 19th edition, 1995
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One of the authors (M.L. Mares) recognizes the financial support from the European Social Fund through POSDRU/107/1.5/S/76813 Romanian Research Project. Part of this work was financially supported under M ERA Net Program, NANOCOATIL 7-082/2013 Research Project.
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Cojocaru, A., Mares, M.L., Prioteasa, P. et al. Study of electrode processes and deposition of cobalt thin films from ionic liquid analogues based on choline chloride. J Solid State Electrochem 19, 1001–1014 (2015). https://doi.org/10.1007/s10008-014-2711-9
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DOI: https://doi.org/10.1007/s10008-014-2711-9