Abstract
A hollow carbon microsphere (HC) material was synthesized by hydrothermal method, which could be used as a potential hard template. Active sulfur is encapsulated into the hollow carbon microspheres via simple impregnation and heat treatments to design a sulfur−hollow carbon microsphere (S−HC) composite with the novel yolk−shell structure. The hollow carbon shell, acts as a conductor to provide a highly conductivity and short Li+ diffusion distance, as well as absorbs polysulfides to improve the cycle ability of the S−HC composite in lithium sulfur (Li−S) batteries. The internal void space inside the shell can accommodate the volumetric expansion of sulfur during lithiation. The initial discharge capacity of S−HC cathode is as high as 1420 mA h g−1 at 0.1 C. After a 100 cycle stability test, the S−HC cathode exhibits still as high as 710 mA h g−1 at 0.2 C. Test results indicate that the S−HC composite is a promising host material for the sulfur cathode in the Li−S battery applications.
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Acknowledgments
This work was supported by the financial supports of the National Natural Science Foundation of China (Nos. 21,301,140 and 21,061,130,551), the Natural Science Foundation of Shaanxi Province (Nos. 2012JQ6019 and 2013JM2009), and the Xi’an Industrial Technology Innovation Project-technology transfer promoting program (No. CXY1438-7).
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Yuan, G., Wang, G., Wang, H. et al. A novel sulfur/carbon hollow microsphere yolk−shell composite as a high-performance cathode for lithium sulfur batteries. J Solid State Electrochem 19, 1143–1149 (2015). https://doi.org/10.1007/s10008-014-2710-x
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DOI: https://doi.org/10.1007/s10008-014-2710-x