Abstract
We prepared LiNi0.4Co0.6O2 nanofibers by electrospinning at the calcination temperature of 450 °C for 6 h. The prepared LiNi0.4Co0.6O2 nanofibers was characterized by thermal, X-ray diffraction, and Fourier transform infrared (FTIR) studies. The morphology of LiNi0.4Co0.6O2 nanofibers was characterized by scanning electron microscopy studies. The asymmetric supercapacitor was fabricated using LiNi0.4Co0.6O2 nanofibers as positive electrode and activated carbon (AC) as negative electrode and a porous polypropylene separator in 1 M LiPF6–ethylene carbonate/dimethyl carbonate (LiPF6–EC:DMC) (1:1 v/v) as electrolyte. Cyclic voltammetry studies were then carried out in the potential range of 0 to 3.0 V at different scan rates which exhibited the highest specific capacitance of 72.9 F g−1. The electrochemical impedance measurements were carried out to find the charge transfer resistance and specific capacitance of the cell, and they were found to be 5.05 Ω and 67.4 F g−1, respectively. Finally, the charge–discharge studies were carried out at a current density of 1 mA cm−2 to find out the discharge-specific capacitance, energy density, and power density of the capacitor cell, and they were found to be 70.9 F g−1, 180.2 Wh kg−1, and 248.0 W kg−1, respectively.
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Zhao G, Wen T, Chen C, Wang X (2012) RSC Adv 2:9286–9303
Zeng J, Zhang Q, Chen J, Xia Y (2010) Nano Lett 10:30–35
Cericola D, Ruch PW, Kotz R, Novak P, Wokaun A (2010) J Power Sources 195:2731–2736
Xu W, Afriyanti S, Eugene K, Chaoyi Y, Pooi See L (2012) J Phys Chem C 116:4930–4935
Tang W, Hou YY, Wang XJ, Bai Y, Zhu YS, Sun H, Yue YB, Wu YP, Zhub K, Holzec R (2012) J Power Sources 197:330–333
Yan Jing H, Qiong Yu L, Xiao Yun X, Ling W (2011) Mater Chem Phys 126:432–436
Xue Y, Chen Y, Zhang M-l, Yan Y-d (2009) Metall Mater 16:112–118
Zhao Y, Wang YY, Lai QY, Chen LM, Hao YJ, Ji XY (2009) Synth Met 159:331–337
Hong Soo C, TaeHoon K, Ji Hyuk I, Chong Rae P (2011) Nanotechnology 22:405402–406411
Amaresh S, Kim GJ, Karthikeyan K, Aravindan V, Chung KY, Cho BW, Lee YS (2012) Phys Chem Chem Phys 14:11904–11909
Zhao D, Wang Y, Zhang Y (2011) Nano-Micro Lett 3:62–71
Desai AV, Haque MA (2007) Appl Phys Lett 90:033102–033104
Bhardwaj N, Kundu SC (2010) Biotechnol Adv 28:325–347
Ramesh Babu B, Periasamy P, Thirunakaran R, Kalaiselvi N, Prem Kumar T, Raghavan M, Renganathan NG, Muniyandi N (2001) Int J Inorg Mater 3:401–404
Sathiya Priya AR, Subramania A, Young-Sam Y, Kang-Jin K (2008) Langmuir 24:9816–9819
Chen F, Li R, Hou M, Liu L, Wang R, Deng Z (2005) Electrochim Acta 51:61–65
Richard Prabhu Gnanakan S, Murugananthem N, Subramania A (2011) Polym Adv Technol 22:788–793
Shao C, Na Y, Liu Y, Rixiang M (2006) J Phys Chem Solids 67:1423–1431
Joint Commission on Power Diffraction Standards (JCPDS), Card No. 44-145, International Center for Diffraction Data, 1995.
Yang S, Yue H, Yin Y, Yang J, Yang W (2006) Electrochim Acta 51:4971–4976
Saradha T, Muzhumathi S, Subramania A (2008) J Solid State Electrochem 12:143–148
Miaomiao Y, Bin C, Huaihe S, Xiaohong C (2010) Electrochim Acta 55:7021–7027
Periasamy P, Ramesh Babu B, Thirunakaran R, Kalaiselvi N, Prem Kumar T, Renganathan NG, Raghavan M, Muniyandi N (2000) Bull Mater Sci 23:345–348
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The authors gratefully acknowledge the DST-Nano Mission, New Delhi and UGC, New Delhi for their financial support.
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Bhuvanalogini, G., Murugananthem, N., Shobana, V. et al. Preparation, characterization, and evaluation of LiNi0.4Co0.6O2 nanofibers for supercapacitor applications. J Solid State Electrochem 18, 2387–2392 (2014). https://doi.org/10.1007/s10008-014-2460-9
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DOI: https://doi.org/10.1007/s10008-014-2460-9