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Reversible phase transformation-type electrolyte based on Dawson-type POM and simple quaternary ammonium salt

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Abstract

A novel kind of organic–inorganic material, (TOAMe)7[In(H2O)P2W17O61] (TOAMe = trioctylmethylammonium), is synthesized as white oily product from polyoxometalate-type ionic liquid with Dawson structure and simple quaternary ammonium ionic liquid. It was characterized by IR, UV, X-ray diffraction, and thermogravimetric–differential thermal analysis. The determination of (TOAMe)7[In(H2O)P2W17O61] shows that it has a high conductivity with 1.25 × 10−4 S cm−1 at 24 °C. In addition, its electrochemical properties were also investigated by the cyclic voltammetric studies. And then we released that the indium in the complexes can undergo reduction in dimethylformamide, which is unlikely in the water solution as a simple hydrated ion.

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Acknowledgments

This work was funded by the National Nature Science Foundation of China (21071124, 21173189), the Foundation of NSFC-RFBR (21211120160), and the Foundation of State Key Laboratory of Inorganic Synthesis and Preparative Chemistry of Jilin University (2013–06).

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Authors and Affiliations

  1. Department of Chemistry, Zhejiang University, Hangzhou, 310027, People’s Republic of China

    Xuefei Wu, Xia Tong, Yunyan Li & Qingyin Wu

  2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130012, People’s Republic of China

    Wenfu Yan

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  1. Xuefei Wu
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  2. Xia Tong
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  3. Yunyan Li
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  4. Qingyin Wu
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Correspondence to Qingyin Wu.

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Wu, X., Tong, X., Li, Y. et al. Reversible phase transformation-type electrolyte based on Dawson-type POM and simple quaternary ammonium salt. J Solid State Electrochem 18, 279–283 (2014). https://doi.org/10.1007/s10008-013-2275-0

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  • DOI: https://doi.org/10.1007/s10008-013-2275-0

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