Skip to main content

Advertisement

Log in

Performance of planar electrode-supported high-temperature solid oxide fuel cell using syngas

  • Original Paper
  • Published:
Journal of Solid State Electrochemistry Aims and scope Submit manuscript

Abstract

In China, coal is a dominant energy source. In order to ensure China’s energy security, coal should be used efficiently and cleanly. Integrated gasification fuel cell hybrid power generation system is a promising system for coal utilization. It combines clean coal gasification technology with high efficient fuel cell technology. In this work, the performance of solid oxide fuel cell using syngas as fuel was investigated, based on the commercial computational fluid dynamic software and the developed program used to analyze chemical, electrochemical, heat/mass transfer, current, and electric potential. The results show that the temperature difference is about 300 K in the cell under all calculation conditions. Along the cell length, hydrogen concentration rapidly reduces, and its decrement is larger than that of carbon monoxide. The variation of current density in electrolyte layer is relatively small along the direction of gas flow, but it is obvious along the direction vertical to gas flow.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Li M, Rao AD, Brouwer J, Samuelsen GS (2010) Design of highly efficient coal-based integrated gasification fuel cell power plants. J Power Sources 195:5707–5718

    Article  CAS  Google Scholar 

  2. Hepworth MT, Bender FN (1996) Recovery of lime and sulfur products from utility coal wastes. J resource management and technology 23:1–7

    CAS  Google Scholar 

  3. Eric G (2009) Technical assessment of an integrated gasification fuel cell combined cycle with carbon capture. Energy Procedia 1:4307–4334

    Article  Google Scholar 

  4. Sasaki K, Hori Y, Kikuchi R, Eguchi K, Ueno A, Takeuchi H, Aizawa M, Tsujimoto K, Tajiri H, Nishikawa H, Uchidad Y (2002) Current–voltage characteristics and impedance analysis of solid oxide fuel cells for mixed H2 and CO gases. J The Electrochemical Society 149:A227–A233

    Article  CAS  Google Scholar 

  5. Robert JK, Zhu HY, David G (2005) Solid-oxide fuel cells with hydrocarbon fuels. Proc the Combustion Institute 30:2379–2404

    Article  Google Scholar 

  6. Yu JG, Wang YZ, Xu L, Weng SL (2009) Development and investigation on the steady state of Solid oxide fuel cell and hybrid power system. In: Proceedings of the 1st International Conference on Sustainable Power Generation and Supply, China

  7. Peters R, Dahl R, Klüttgen U, Palm C, Stolten D (2002) Internal reforming of methane in solid oxide fuel cell systems. J Power Sources 106:238–244

    Article  CAS  Google Scholar 

  8. Marina OA, Coyle CA, Thomsen EC, Edwards DJ, Coffey GW, Pederson LR (2010) Degradation mechanisms of SOFC anodes in coal gas containing phosphorus. Solid State Ionics 181:430–440

    Article  CAS  Google Scholar 

  9. Trembly JP, Gemmen RS, Bayless DJ (2007) The effect of IGFC warm gas cleanup system conditions on the gas–solid partitioning and form of trace species in coal syngas and their interactions with SOFC anodes. J Power Sources 163:986–996

    Article  CAS  Google Scholar 

  10. Wang YZ, Yoshiba F, Kawase M, Watanabe T (2009) Performance and effective kinetic models of methane steam reforming over Ni/YSZ anode of planar SOFC. Int J Hydrogen Energy 34:3885–3893

    Article  CAS  Google Scholar 

  11. Yu JG, Wang YZ, Hui Y, Weng SL (2009) The effect of anode porosity on the performance of planar electrode supported solid oxide fuel cell. In: Proceedings of ASME 2009 2nd Micro/Nanoscale Heat & Mass Transfer International Conference, China

  12. Wang YZ, Yoshiba F, Watanabe T, Weng SL (2007) Numerical analysis of electrochemical characteristics and heat/species transport for planar porous-electrode-supported SOFC. J of Power Sources 170:101–110

    Article  CAS  Google Scholar 

  13. Wang YZ, Yoshiba F, Watanabe T (2006) Performance analysis of planar porous-electrode-supported SOFC. In: Proceedings of the International Conference on Clean Coal Technology and Fuel Cells, Yokosuka, Japan

  14. Xu L, Wang YZ, Weng YW, Weng SL (2009) Simulation and optimization on gasifier in the poly-generation system with IGCC. In: Proceedings of the International Conference on Clean Coal Technology and Fuel Cells, Daejoen, Korea

  15. Todd B, Young JB (2002) Thermodynamic and transport properties of gases for use in solid oxide fuel modeling. J Power Sources 110:186–200

    Article  CAS  Google Scholar 

  16. Wang YZ, Li YX, Weng SL, Wang Y (2007) Numerical simulation of counter-flow spray saturator for humid air turbine cycle. Energy 32:852–860

    Article  CAS  Google Scholar 

  17. Chan SH, Khor KA, Xia ZT (2001) A complete polarization model of a solid oxide fuel cell and its sensitivity of the change of cell component thickness. J Power Sources 93:130–140

    Article  CAS  Google Scholar 

  18. Hwang JJ, Chen CK, Lai DY (2005) Computational analysis of species transport and electrochemical characteristics of a MOLB-type SOFC. J Power Sources 140:235–242

    Article  CAS  Google Scholar 

  19. Bessette N (1994) Modeling and simulation for solid oxide fuel cell power systems. Doctorial thesis, Georgia Institute of Technology, Atlanta

  20. Weber A, Sauer B, Müller AC, Herbstritt D, Ivers-Tiffée E (2002) Oxidation of H2, CO and methane in SOFCs with Ni/YSZ-cermet anodes. Solid State Ionics 152:543–550

    Article  Google Scholar 

  21. Costamagna P, Selimovic A, Del Borghi M, Agnew G (2004) Electrochemical model of the integrated planar solid oxide fuel cell (IP-SOFC). Chem Eng J 102:61–69

    Article  CAS  Google Scholar 

  22. Hou K, Hughes R (2001) The kinetics of methane steam reforming over a Ni/α-Al2O catalyst. Chem Eng J 82:311–328

    Article  CAS  Google Scholar 

  23. Simbeck DR, Korens N (1993) Coal gasification guidebook: status, applications and technologies. Electric Power Research Institute, USA

    Google Scholar 

Download references

Acknowledgments

This work was supported by the Scientific Research Foundation for Returned Scholars, Ministry of Education of China, Shanghai Jiao Tong University Innovation Fund For Postgraduates, National Basic Research Program of China (2007CB210102), and Key Technologies R & D Program of Shanghai (08DZ1200102).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yuzhang Wang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yu, J., Cao, X. & Wang, Y. Performance of planar electrode-supported high-temperature solid oxide fuel cell using syngas. J Solid State Electrochem 16, 1509–1517 (2012). https://doi.org/10.1007/s10008-011-1554-x

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10008-011-1554-x

Keywords

Navigation