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Sustainable energy: a review of formic acid electrochemical fuel cells

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An Erratum to this article was published on 08 December 2011

Abstract

Of the many candidate fuels for low-temperature fuel cells, one of the most promising is formic acid. Although it has been investigated as such for nearly 50 years, rapid advances in recent times have begun to release the potential for formic acid fuel cells as high-performance, portable fuel cells with some products about to reach the market. In this review, we briefly summarise the recent advances in formic acid fuel cells.

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References

  1. Synnogy Ltd (2005) UK fuel cell development and deployment roadmap. Synnogy, Thorpe Waterville

    Google Scholar 

  2. Mikkelsen M, Jorgensen M, Krebs FC (2010) Energy Environ Sci 3:43

    Article  CAS  Google Scholar 

  3. Wilson EJ, Gerrard D (eds) (2007) Carbon capture and sequestration. Blackwell, Ames

    Google Scholar 

  4. Rees NV, Compton RG (2011) Energy Environ Sci 4:403

    Article  CAS  Google Scholar 

  5. MacDowell N, Florin N, Buchard A, Hallett J, Galindo A, Jackson G, Adjiman CS, Williams CK, Shah N, Fennell P (2010) Energy Environ Sci 3:1645

    Article  CAS  Google Scholar 

  6. Serov A, Kwak C (2010) Appl Catal B 98:1

    Article  CAS  Google Scholar 

  7. Lan R, Tao S (2010) Electrochem Solid State Lett 13:B83

    Article  CAS  Google Scholar 

  8. Rees NV, Compton RG (2011) Energy Environ Sci 4:1255–1260

    Article  CAS  Google Scholar 

  9. Kundu A, Jang JH, Gil JH, Jung CR, Lee HR, Kim SH, Ku B, Oh YS (2007) J Power Sources 170:67

    Article  CAS  Google Scholar 

  10. Uhm S, Lee HJ (2009) PhysChemChemPhys 11:9326

    CAS  Google Scholar 

  11. Yu X, Pickup PG (2008) J Power Sources 182:124

    Article  CAS  Google Scholar 

  12. Lipkowski J, Ross PN (1998) Electrocatalysis. Wiley-VCH, New York

    Google Scholar 

  13. Vielstich W, Lamm A, Gasteiger HA (2003) Handbook of fuel cells. Wiley, New York

    Google Scholar 

  14. Lide DR (ed) (2008) CRC handbook of chemistry and physics, 89th edn. CRC, Boca Raton

  15. Capon A, Parsons R (1973) J Electroanal Chem 44:1

    Article  CAS  Google Scholar 

  16. Xia XH, Iwasita T (1993) J Electrochem Soc 140:2559

    Article  CAS  Google Scholar 

  17. Willsau J, Heitbaum J (1985) J Electroanal Chem 194:27

    Article  CAS  Google Scholar 

  18. Chen YX, Heinen M, Jusys Z, Behm RJ (2007) Chemphyschem 8:380

    Article  CAS  Google Scholar 

  19. Chen YX, Heinen M, Jusys Z, Behm RJ (2006) Angew Chem Int Ed 45:981

    Article  CAS  Google Scholar 

  20. Gao W, Keith JA, Anton J, Jacob T (2010) J Am Chem Soc 132:18377

    Article  Google Scholar 

  21. Arenz M, Stamenkovic V, Schmidt TJ, Wandelt K, Ross PN, Markovic NM (2003) PhysChemChemPhys 5:4242

    CAS  Google Scholar 

  22. Larsen R, Ha S, Zakzeski J, Masel RI (2006) J Power Sources 157:78

    Article  CAS  Google Scholar 

  23. Ha S, Larsen R, Masel RI (2005) J Power Sources 144:28

    Article  CAS  Google Scholar 

  24. Zhou WP, Lewara A, Larsen R, Masel RI, Bagus PS, Wieckowski A (2006) J Phys Chem B 110:13393

    Article  CAS  Google Scholar 

  25. Zhu Y, Khan Z, Masel RI (2005) J Power Sources 139:15

    Article  CAS  Google Scholar 

  26. Ha S, Larsen R, Zhu Y, Masel RI (2004) Fuel Cells 4:337

    Article  CAS  Google Scholar 

  27. Llorca MJ, Feliu JM, Aldaz A, Clavilier JM (1994) J Electroanal Chem 376:151

    Article  CAS  Google Scholar 

  28. Baldauf M, Kolb DM (1996) J Phys Chem 100:11375

    Article  CAS  Google Scholar 

  29. Babu PK, Kim HS, Chung JH, Oldfield E, Wieckowski A (2004) J Phys Chem B 108:20228

    Article  CAS  Google Scholar 

  30. Sollon J, Montiel V, Aldaz A, Clavilier JM (2002) Electrochem Commun 4:716

    Article  Google Scholar 

  31. Kristian N, Yanb Y, Wang X (2008) Chem Commun 353

  32. Markovic NM, Ross PN (2002) Surf Sci Rep 45:117

    Article  CAS  Google Scholar 

  33. Petrii OA (2008) J Solid State Electrochem 12:609

    Article  CAS  Google Scholar 

  34. Zhu Y, Ha S, Masel RI (2004) J Power Sources 130:8

    Article  CAS  Google Scholar 

  35. Rice C, Ha S, Masel RI, Wieckowski A (2003) J Power Sources 115:229

    Article  CAS  Google Scholar 

  36. Choi JH, Jeong KJ, Dong Y, Han J, Lim TH, Lee JS, Sung YE (2006) J Power Sources 163:71

    Article  CAS  Google Scholar 

  37. Waszczuk P, Barnard TM, Masel RI, Wieckowski A (2002) Electrochem Commun 4:599

    Article  CAS  Google Scholar 

  38. Larsen R, Zakzeski J, Masel RI (2005) Electrochem Solid State Lett 8:A291

    Article  CAS  Google Scholar 

  39. Beltramo GL, Shubina TE, Koper MTM (2005) Chemphyschem 6:2597

    Article  CAS  Google Scholar 

  40. Wang X, Tang Y, Gao Y, Lu T (2008) J Power Sources 175:784

    Article  CAS  Google Scholar 

  41. Qi Y, Chen A, Huang W, Zhang J, Liu X, Xu G, Zhou Z (2007) Electrochem Commun 9:1513

    Article  Google Scholar 

  42. Brandt K, Steinhausen M, Wandelt K (2008) J Electroanal Chem 616:27

    Article  CAS  Google Scholar 

  43. Chen W, Kim J, Sun S, Chen S (2007) Langmuir 23:11303

    Article  CAS  Google Scholar 

  44. Abe H, Matsumoto F, Alden LR, Warren SC, Abruna HD, DiSalvo FJ (2008) J Am Chem Soc 130:5452

    Article  CAS  Google Scholar 

  45. Gojkovic GL, Tripkovic AV, Stevanovic RM, Krstajic NV (2007) Langmuir 23:12760

    Article  CAS  Google Scholar 

  46. Adžić RR, Simić DN, Despić AR, Dražić DM (1977) J Electroanal Chem 80:81

    Article  Google Scholar 

  47. Watanabe M, Horiuchi M, Motoo S (1988) J Electroanal Chem 250:117

    Article  CAS  Google Scholar 

  48. Clavilier J, Fernandez-Vega A, Feliu JM, Aldaz A (1989) J Electroanal Chem 258:89

    Article  CAS  Google Scholar 

  49. Uhm S, Lee HJ, Kwon Y, Lee J (2008) Angew Chem Int Ed 47:10163

    Article  CAS  Google Scholar 

  50. Kang S, Lee J, Lee JK, Chung SY, Tak Y (2006) J Phys Chem B 110:7270

    Article  CAS  Google Scholar 

  51. Casado-Rivera E, Gal Z, Angelo ACD, Lind C, DiSalvo FJ, Abruna HD (2003) Chemphyschem 4:193

    Article  CAS  Google Scholar 

  52. Haan JL, Masel RI (2008) ECS Trans 16:627

    Article  CAS  Google Scholar 

  53. Uhm S, Chung ST, Lee J (2007) Electrochem Commun 9:2027

    Article  CAS  Google Scholar 

  54. Lee JK, Jeon H, Uhm S, Lee J (2008) Electrochim Acta 53:6089

    Article  CAS  Google Scholar 

  55. Gonzalez MJ, Hable CT, Wrighton MS (1998) J Phys Chem B 102:9881

    Article  CAS  Google Scholar 

  56. Casado-Rivera E, Volpe DJ, Alden L, Lind C, Downie C, Vazquez-Alvarez T, Angelo ACD, DiSalvo FJ, Abruna HD (2004) J Am Chem Soc 126:4043

    Article  CAS  Google Scholar 

  57. Zhang LJ, Wang ZY, Xia DG (2006) J Alloys Compd 426:268

    Article  CAS  Google Scholar 

  58. Matsumoto F, Roychowdhury C, DiSalvo FJ, Abruna HD (2008) J Electrochem Soc 155:B148

    Article  CAS  Google Scholar 

  59. Lee J, Strasser P, Eiswirth M, Ertl G (2001) Electrochim Acta 47:501

    Article  CAS  Google Scholar 

  60. Uhm S, Yun Y, Tak Y, Lee J (2005) Electrochem Commun 7:1375

    Article  CAS  Google Scholar 

  61. Pautienienė V, Tamašauskaitė-Tamašiūnaitė L, Sudavičius A, Stalnionis G, Jusys Z (2010) J Solid State Electrochem 14:1675

    Article  Google Scholar 

  62. Lovic JD, Tripkovic AV, Gojkovic SLJ, Popovic KD, Tripkovic DV, Olszewski P, Kowal A (2005) J Electroanal Chem 581:294

    Article  CAS  Google Scholar 

  63. Liu ZL, Hong L, Tham MP, Lim TH, Jiang HX (2006) J Power Sources 161:831

    Article  CAS  Google Scholar 

  64. Zhang LL, Lu TH, Bao JC, Tang YW, Li C (2006) Electrochem Commun 8:1625

    Article  CAS  Google Scholar 

  65. Zhang LL, Tang YW, Bao JC, Lu TH, Li C (2006) J Power Sources 162:177

    Article  CAS  Google Scholar 

  66. Li XG, Hsing IM (2006) Electrochim Acta 51:3477

    Article  CAS  Google Scholar 

  67. Heinzel A, Barragan VM (1999) J Power Sources 84:70

    Article  CAS  Google Scholar 

  68. McGrath KM, Prakash GKS, Olah GA (2004) J Ind Eng Chem 10:1063

    CAS  Google Scholar 

  69. Wang X, Hu JM, Hsing IM (2004) J Electroanal Chem 562:73

    Article  CAS  Google Scholar 

  70. Jeong KJ, Miesse CA, Choi JH, Lee J, Han J, Yoon SP, Nam SW, Lim TH, Lee TG (2007) J Power Sources 168:119

    Article  CAS  Google Scholar 

  71. Song C, Khanfar M, Pickup PG (2006) J Appl Electrochem 36:339

    Article  CAS  Google Scholar 

  72. Uhm S, Kwon Y, Chung ST, Lee J (2008) Electrochim Acta 53:5162

    Article  CAS  Google Scholar 

  73. Rhee YW, Ha SY, Masel RI (2003) J Power Sources 117:35

    Article  CAS  Google Scholar 

  74. Jaime Ferrer JS, Couallier E, Rakib M, Durand G (2007) Electrochim Acta 52:5773

    Article  Google Scholar 

  75. Chen W, Tang Y, Bao J, Gao Y, Liu C, Xing W, Lu T (2007) J Power Sources 167:315

    Article  CAS  Google Scholar 

  76. Arriaga LG, Gochi Y, Alonso-Vante N (2006) ECS Trans 3:1333

    Article  CAS  Google Scholar 

  77. Niessen J, Harnisch F, Rosenbaum M, Schroder U, Scholz F (2006) Electrochem Commun 8:869

    Article  CAS  Google Scholar 

  78. Niessen J, Schroder U, Rosenbaum M, Scholz F (2004) Electrochem Commun 6:571

    Article  CAS  Google Scholar 

  79. Wildgoose GG, Abiman P, Compton RG (2009) J Mater Chem 19:4875

    Article  CAS  Google Scholar 

  80. Widlgoose GG, Banks CE, Compton RG (2006) Small 2:182

    Article  Google Scholar 

  81. Tang S, Sun G, Sun S, Qi J, Xin Q, Haarberg GM (2010) J Electrochem Soc 157:B1321

    Article  CAS  Google Scholar 

  82. Reddy A, Leela M, Shaijumon MM, Rajalakshmi N, Ramaprabhu S (2006) Proc Int Conf Fuel Cell Sci 4:B951

    Google Scholar 

  83. Li L, Xing Y (2006) J Electrochem Soc 153:A1823

    Article  CAS  Google Scholar 

  84. Wang X, Li W, Chen Z, Waje M, Yan Y (2006) J Power Sources 158:154

    Article  CAS  Google Scholar 

  85. Pan D, Chen J, Tao W, Nie L, Yao S (2006) Langmuir 22:5872

    Article  CAS  Google Scholar 

  86. Wu G, Li L, Li J-H, Xu B-Q (2006) J Power Sources 155:118

    Article  CAS  Google Scholar 

  87. Kamat PV (2010) J Phys Chem Lett 1:520

    Article  CAS  Google Scholar 

  88. Dong L, Gar RRS, Li Z, Craig MM, Hou S (2010) Carbon 48:781

    Article  CAS  Google Scholar 

  89. Li Y, Gao W, Ci L, Wang C, Ajayan PM (2010) Carbon 48:1124

    Article  CAS  Google Scholar 

  90. Yoo E-J, Okada T, Akita T, Kohyama M, Honma I, Nakamura J (2011) J Power Sources 196:110

    Article  CAS  Google Scholar 

  91. Gotoh K, Kinumoto T, Fujii E, Yamamoto A, Hashimoto H, Ohkubo T, Itadani A, Kuroda Y, Ishida H (2011) Carbon 49:1118

    Article  CAS  Google Scholar 

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Correspondence to Richard G. Compton.

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An erratum to this article can be found at http://dx.doi.org/10.1007/s10008-011-1614-2

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Rees, N.V., Compton, R.G. Sustainable energy: a review of formic acid electrochemical fuel cells. J Solid State Electrochem 15, 2095–2100 (2011). https://doi.org/10.1007/s10008-011-1398-4

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  • DOI: https://doi.org/10.1007/s10008-011-1398-4

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