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Stannum film electrode for square wave voltammetric determination of trace copper(II)

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Abstract

An anodic stripping voltammetric procedure for the determination of Cu(II) at an in situ-plated stannum film electrode (SnFE) was described. The results indicated that the SnFE had an attractive electroanalytical performance, with two distinct voltammetric stripping signals for copper and stannum, and showed the superior advantage for the determination of copper compared with the bismuth film electrode. Several experimental parameters were optimized. The SnFE exhibited highly linear behavior in the concentration range from 1.0 to 100.0 μg L−1 of Cu(II) (r = 0.994) with the detection limit of 0.61 μg L−1 (S/N = 3), and the relative standard deviation for a solution containing 40.0 μg L−1 Cu(II) was 2.2% (n = 8). The procedure has been successfully applied for the determination of Cu(II) in lake water sample.

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Acknowledgments

This project is supported by the Municipal Science Foundation of Chongqing City (No. CSTC–2008BB4012; No. CSTC–2008BB4013) and the 211 Project of Southwest University (the Third Term).

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Authors and Affiliations

  1. Key Laboratory of Eco-environments in Three Gorges Reservoir Region (Ministry of Education), School of Chemistry and Chemical Engineering, Southwest University, Chongqing, 400715, People’s Republic of China

    Yun Qing Tian, Hong Qun Luo & Nian Bing Li

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  1. Yun Qing Tian
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  2. Hong Qun Luo
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  3. Nian Bing Li
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Correspondence to Nian Bing Li.

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Tian, Y.Q., Luo, H.Q. & Li, N.B. Stannum film electrode for square wave voltammetric determination of trace copper(II). J Solid State Electrochem 16, 529–533 (2012). https://doi.org/10.1007/s10008-011-1363-2

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  • DOI: https://doi.org/10.1007/s10008-011-1363-2

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