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Improved properties of polymer electrolyte by ionic liquid PP1.3TFSI for secondary lithium ion battery

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Abstract

A new kind of polymer electrolyte is prepared from N-methyl-N-propylpiperidinium bis (trifluoromethanesulfonyl) imide (PP1.3TFSI), polyethylene oxide (PEO), and lithium bis (trifluoromethanesulfonyl) imide (LiTFSI). IR and X-ray diffraction results demonstrate that the addition of ionic liquid decreases the crystallization of PEO. Thermal and electrochemical properties have been tested for the solid polymer electrolytes, the addition of the room temperature molten salt PP1.3TFSI to the conventional P(EO)20LiTFSI polymer electrolyte leads to the improvement of the thermal stability and the ionic conductivity (x = 1.27, 2.06 × 10−4 S cm−1 at room temperature), and the reasonable lithium transference number is also obtained. The Li/LiFePO4 cell using this polymer electrolyte shows promising reversible capacity, 120 mAh g−1 at room temperature and 164 mAh g−1 at 55 °C.

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References

  1. Ding MS, Xu K, Zhang SS, Jow TR (2000) J Electrochem Soc 147:1688

    Article  CAS  Google Scholar 

  2. Beaton SP, Bishop GA, Zhang Y, Ashbaugh LL, Lawson DR, Stedman DH (1995) Science 268:991

    Article  CAS  Google Scholar 

  3. Kim GT, Appetecchi GB, Alessandrini F (2007) J Power Sources 171:861

    Article  CAS  Google Scholar 

  4. Nishimoto A, Agehara K, Furuya N, Watanabe T, Watanabe M (1999) Macromolecules 32:1541

    Article  CAS  Google Scholar 

  5. Croce F, Serraino-Fiory F, Persi L, Scrosati B (2000) Electrochem Solid-State Lett 4(8):A121

    Article  Google Scholar 

  6. Saito Y, Stephan-Manuel A, Kataoka H (2003) Solid State Ionics 16:149

    Article  Google Scholar 

  7. Stephan AM, Kumar SG, Renganathan NG, Kulandainathan MA (2005) J Eur Polym 41:15

    Article  CAS  Google Scholar 

  8. Sakaebe H, Matsumoto H (2003) Electrochem Commun 5:594

    Article  CAS  Google Scholar 

  9. Chagnes A, Carre MB (2005) J Power Sources 145:82

    Article  CAS  Google Scholar 

  10. Galinski M, Lewandowski A, Stepniak I (2006) Electrochim Acta 51:5567

    Article  CAS  Google Scholar 

  11. Tsunashima K, Sugiya M (2007) Electrochem Commun 9:2353

    Article  CAS  Google Scholar 

  12. Seki S, Ohno Y, Kobayashi Y, Miyashiro H, Usami A, Mita Y, Tokuda H, Watanabe M, Hayamizu K, Tsuzuki S, Hattori M, Terada N (2007) J Electrochem Soc 154(3):A173

    Article  CAS  Google Scholar 

  13. Kim S, Jung Y, Park S (2007) Electrochim Acta 52:2116

    Article  CAS  Google Scholar 

  14. Matsumoto H, Sakaebe H, Tatsumi K (2005) J Power Sources 146:45

    Article  CAS  Google Scholar 

  15. Shin JH, Henderson W, Passerini S (2005) Electrochem Solid-State Lett 8:A125

    Article  CAS  Google Scholar 

  16. Kim KS, Park SY, Choi S, Lee H (2006) J Power Sources 155(2):385

    Article  CAS  Google Scholar 

  17. Evans J, Vincent CA, Bruce PG (1987) Polymer 28(13):2324

    Article  CAS  Google Scholar 

  18. Fernicola A, Croce F, Scrosati B (2007) J Power Sources 174:342

    Article  CAS  Google Scholar 

  19. Ramesh S, Yuen TF, Shen CJ (2008) Electrochim Acta 69:670

    CAS  Google Scholar 

  20. Cheng H, Zhu CB, Huang B (2007) Electrochim Acta 52:5789

    Article  CAS  Google Scholar 

  21. Castriota M, Caruso T, Agostino RG, Cazzaneli E, Henderson WA, Passerini S (2005) J Phys Chem 109(1):92

    Article  CAS  Google Scholar 

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Acknowledgments

The authors would like to thank the anonymous reviewers and the finance support from the 863Foundation of China (no. 2009AA11A105).

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Authors and Affiliations

  1. School of Chemical Engineering and Technology, Harbin Institute of Technology, No. 92, West Da-Zhi Street, Harbin, 150001, China

    An Yongxin, Cheng Xinqun, Zuo Pengjian, Liao Lixia & Yin Geping

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  1. An Yongxin
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  2. Cheng Xinqun
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  3. Zuo Pengjian
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  4. Liao Lixia
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  5. Yin Geping
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Correspondence to Yin Geping.

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Yongxin, A., Xinqun, C., Pengjian, Z. et al. Improved properties of polymer electrolyte by ionic liquid PP1.3TFSI for secondary lithium ion battery. J Solid State Electrochem 16, 383–389 (2012). https://doi.org/10.1007/s10008-011-1340-9

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  • DOI: https://doi.org/10.1007/s10008-011-1340-9

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