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Electrochemical oxidation behavior of 2,4-dinitrophenol at hydroxylapatite film-modified glassy carbon electrode and its determination in water samples

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Abstract

Hydroxylapatite (HAP)-modified glassy carbon electrode (GCE) was fabricated and used to investigate the electrochemical oxidation behavior of 2,4-dinitrophenol (2,4-DNP) by cyclic voltammetry, differential pulse voltammetry, and chronocoulometry. The oxidation peak current of 2,4-DNP at the modified electrode was obviously increased compared with the bare GCE, indicating that HAP exhibits a remarkable enhancement effect on the electrochemical oxidation of 2,4-DNP. Based on this, a sensitive and simple electrochemical method was proposed for the determination of 2,4-DNP. The effects of HAP concentration, accumulation time, accumulation potential, pH, and scan rate were examined. Under optimal conditions, the oxidation peak current of 2,4-DNP was proportional to its concentration in the range from 2.0 × 10−6 to 6.0 × 10−4 M with a correlation coefficient of 0.9987. The detection limit was 7.5 × 10−7 M (S/N = 3). The proposed method was further applied to determine 2,4-DNP in water samples with recoveries from 96.75% to 106.50%.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (No. 20775044) and the Natural Science Foundation of Shandong Province, China (Y2006B20).

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Authors and Affiliations

  1. College of Chemistry and Material Science, Shandong Agricultural University, Taian, 271018, Shandong, China

    Huanshun Yin, Ruixia Han, Yanyan Qiu & Shiyun Ai

  2. College of Resources and Environment, Shandong Agricultural University, Taian, 271018, Shandong, China

    Huanshun Yin & Lusheng Zhu

  3. College of Life Science, Beijing Normal University, 100875, Beijing, China

    Yunlei Zhou

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  1. Huanshun Yin
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  2. Yunlei Zhou
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  3. Ruixia Han
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  4. Yanyan Qiu
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Correspondence to Shiyun Ai or Lusheng Zhu.

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Yin, H., Zhou, Y., Han, R. et al. Electrochemical oxidation behavior of 2,4-dinitrophenol at hydroxylapatite film-modified glassy carbon electrode and its determination in water samples. J Solid State Electrochem 16, 75–82 (2012). https://doi.org/10.1007/s10008-010-1280-9

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  • DOI: https://doi.org/10.1007/s10008-010-1280-9

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