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Preparation and properties of manganese dioxide studied by QCM

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Abstract

Electrodeposition and cycling of MnO2 was tested by cyclic voltammetry and electrochemical quartz crystal microbalance (QCM). The electrodeposition from manganese sulfate and the material cycling are accompanied by strong and almost reversible water sorption close to the stoichiometric ratio 3:1. Similar reversible sorption of water was observed also on solid MnO2 deposited as an “ink” (slurry) with PTFE as a binder on the QCM probe.

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Acknowledgment

This paper was supported by the Ministry of Education of Czech Republic, Project MSM002130516 and Academy of Sciences, Research Plan AV/0Z403 0502. Moreover, it was presented on the ABAF-10 Conference co-sponsored by The Electrochemical Society, Inc., USA.

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Authors and Affiliations

  1. Department of Electrical and Electronic Technology, Brno University of Technology, 602 00, Brno, Czech Republic

    Petr Špičák, Marie Sedlaříková, Miroslav Zatloukal, V. Novák, Jiri Kazelle & Jiri Vondrák

  2. Institute of Inorganic Chemistry of the AS CR, v.v.i., 250 68 Řež near Prague, Prague, Czech Republic

    Jiri Vondrák

Authors
  1. Petr Špičák
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  2. Marie Sedlaříková
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  3. Miroslav Zatloukal
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  4. V. Novák
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  5. Jiri Kazelle
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  6. Jiri Vondrák
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Correspondence to Jiri Vondrák.

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Špičák, P., Sedlaříková, M., Zatloukal, M. et al. Preparation and properties of manganese dioxide studied by QCM. J Solid State Electrochem 14, 2139–2144 (2010). https://doi.org/10.1007/s10008-010-1198-2

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  • DOI: https://doi.org/10.1007/s10008-010-1198-2

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