Abstract
Pd nanoparticle/Ti electrodes are prepared by electroless plating of palladium on titanium plates. The morphology and surface analysis of Pd nanoparticle/Ti electrodes are investigated using scanning electron microscopy and energy-dispersive X-ray spectroscopy, respectively. The results indicate that palladium nanoparticles are homogeneously deposited on the surface of titanium plates. The electro-catalytic activity of Pd nanoparticle/Ti electrodes in the methanol electro-oxidation is studied by cyclic voltammetry and chronoamperometry methods. The results show that the electro-catalytic oxidation of methanol on the Pd nanoparticle/Ti electrode improved compare to pure palladium electrode and confirmed the better electro-catalytic activity and stability of these new electrodes.
Similar content being viewed by others
References
Carrette L, Friedrich KA, Stimming U (2001) Fuel Cells 1:5
Steele BCH, Heinzel A (2001) Nature 414:345
Schlapbach L, Zuettel A (2001) Nature 414:353
McNicol BD, Rand DAJ, Williams KR (1999) J Power Sources 83:15
Beer HB (1980) J Electrochem Soc 127:303c
Gilroy D, Stevem SR (1980) J Appl Electrochem 10:511
Comnnellis CH, Platiner E (1982) J Appl Electrochem 12:399
Freitas RG, Santos MC, Oliveira RTS, Bulhoes LOS, Pereira EC (2006) J Power Sources 158:164
Cheng H, Scott K (2003) J Power Sources 123:137
de Oliveira MB, Profeti LPR, Olivi P (2005) Electrochem Commun 7:703
Yu EH, Scott K, Reeve RW, Yang LX, Allen RG (2004) Electrochim Acta 49:2443
Shao ZG, Lin WF, Zhu FY, Christensen PA, Zhang HM, Yi BL (2006) J Power Sources 160:1003
Yu EH, Scott K (2004) Electrochem Commun 6:361
Yang CC, Chiu SJ, Chien WC (2006) J Power Sources 162:21
Shao ZG, Lin WF, Zhu FY, Christensen PA, Li MQ, Zhang HM (2006) Electrochem Commun 8:5
Shao ZG, Zhu FY, Lin WF, Christensen PA, Zhang HM, Yi BL (2006) J Electrochem Soc 153:A1575
Yi Q, Huang W, Zhang J, Liu X, Li L (2008) Catal Commun 9:2053
Abdel Rahim MA, Hassan HB (2009) Thin Solid Films 517:3362
Hosseini MG, Sajjadi SAS, Momeni MM (2007) Surf Eng 23:419
Bard AJ, Faulkner LR (2004) Elecrochemical methods fundamentals and applications, 2nd edn. Wiley, New York
Acknowledgment
The authors would like to acknowledge the financial support of Iranian Nanotechnology Society.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Hosseini, J., Bodaghi, A. Preparation of palladium nanoparticles–titanium electrodes as a new anode for direct methanol fuel cells. J Solid State Electrochem 15, 795–800 (2011). https://doi.org/10.1007/s10008-010-1152-3
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10008-010-1152-3