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Thiomorpholine-functionalized nanoporous mesopore as a sensing material for Cd2+ carbon paste electrode

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Abstract

A new thiomorpholine-functionalized nanoporous mesopore Mobil Composition of Matter No. 41 (MCM-41), abbreviated as TMMCM-41, was synthesized and applied as a sensing material in construction of a cadmium carbon paste electrode. The electrode composition of 20.1%wt TMMCM-41, 54.0% graphite powder, 25.9% paraffin oil showed the stable potential response to Cd2+ ions with the Nernstian slope of 28.6 mV decade−1 (±1.8 mV decade−1) over a wide linear concentration range of 10−6 to 10−2 mol L−1 with a detection limit of 6 × 10−7 mol L−1. The electrode has fast response time and long-term stability (more than 4 months). The proposed electrode was used to determine the concentration of cadmium in tap water contaminated by this metal and cadmium electroplating waste water samples.

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References

  1. Walcarius A (2001) Electroanalysis 13:701–718

    Article  CAS  Google Scholar 

  2. Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS (1992) Nature 359:710–712

    Article  CAS  Google Scholar 

  3. Beck JA, Vartuli JC (1996) Curr Opin Solid State Mater Sci 1:76–87

    Article  CAS  Google Scholar 

  4. Feng X, Fryxell GE, Wang LQ, Kim AY, Liu J, Kemner KM (1997) Science 27:923–926

    Article  Google Scholar 

  5. Mercier L, Pinnavaia TJ (1997) Adv Mater 9:500–503

    Article  CAS  Google Scholar 

  6. Brown J, Richer R, Mercier L (2000) Micropor Mesopor Mater 37:41–48

    Article  CAS  Google Scholar 

  7. Yantasee W, Lin Y, Fryxell GE, Busche BJ, Birnbaum JC (2003) Separ Sci Technol 38:3809–3825

    Article  CAS  Google Scholar 

  8. Bibby A, Mercier L (2002) Chem Mater 14:1591–1597

    Article  CAS  Google Scholar 

  9. Walcarius A, Etienne M, Bessiere J (2002) Chem Mater 14:2757–2766

    Article  CAS  Google Scholar 

  10. Moller K, Bein T (1998) Chem Mater 10:2950–2963

    Article  CAS  Google Scholar 

  11. Sayari A, Hamoudi S (2001) Chem Mater 13:3151–3168

    Article  CAS  Google Scholar 

  12. Stein A, Melde BJ, Schroden RC (2000) Adv Mater 12:1403–1419

    Article  CAS  Google Scholar 

  13. Mercier L, Pinnavaia TJ (2000) Chem Mater 12:188–196

    Article  CAS  Google Scholar 

  14. Corriu RJP, Lancelle-Beltran E, Mehdi A, Reye C, Brandes S, Guilard R (2002) J Mater Chem 12:1355–1362

    Article  CAS  Google Scholar 

  15. Lim MH, Stein A (1999) Chem Mater 11:3285–3295

    Article  CAS  Google Scholar 

  16. Sanchez C, Ribot F (1994) New J Chem 18:1007–1047

    CAS  Google Scholar 

  17. Walcarius A (2004) Electrochim Acta 49:3775–3783

    Article  CAS  Google Scholar 

  18. Corriu RJP, Leclercq D (1996) Angew Chem Int Ed Engl 35:1420–1436

    Article  Google Scholar 

  19. Javanbakht M, Badiei A, Ganjali MR, Norouzi P, Hasheminasab A, Abdouss M (2007) Anal Chim Acta 601:172–182

    Article  CAS  Google Scholar 

  20. Javanbakht M, Fard SE, Abdouss M, Mohammadi A, Ganjali MR, Norouzi P, Safaraliee L (2008) Electroanalysis 20:2023–2030

    Article  CAS  Google Scholar 

  21. Javanbakht M, Ganjali MR, Norouzi P, Badiei A, Hasheminasab A, Abdouss M (2007) Electroanalysis 19:1307–1314

    Article  CAS  Google Scholar 

  22. Badiei A, Norouzi P, Tousi F (2005) Europ J Sci Res 12:39–45

    Google Scholar 

  23. Badiei A, Bonneviot L, Crowther N, Mohammadi Ziarani G (2006) J Organomet Chem 691:5923–5931

    Article  Google Scholar 

  24. Lawrence NS, Deo RP, Wang J (2004) Anal Chem 76:3735–3739

    Article  CAS  Google Scholar 

  25. Department of Health and Human Services and US Environmental Protection Agency (1987) Federal Register 52:12866

    Google Scholar 

  26. Keith LH, Telliard WA (1979) Environ Sci Toxicol 13:416–423

    Google Scholar 

  27. US Environmental Protection Agency (1991) Water quality criteria summary list. USEPA, Washington, DC

    Google Scholar 

  28. US Environmental Protection Agency (1996) EPA integrated risk information system (IRIS). USEPA, Washington, DC

    Google Scholar 

  29. Green M. Chapter on Pollutants, Chemical. Grolier Electronic Publishing Ink, (1988) Danbury, CT

  30. National Library of Medicine (1996) Hazardous substances data bank (HSDB)

  31. Friberg L, Nordberg GF, Kessler E, Vouk VB (1986) Handbook of toxicology of metals, 2nd Edn. 1:11

  32. Faridbod F, Ganjali MR, Dinarvand R, Norouzi P, Riahi S (2008) Sensors 8:1645–1703

    Article  CAS  Google Scholar 

  33. Bakker E, Buhlmann P, Pretsch E (1997) Chem Rev 97:3083–3132

    Article  CAS  Google Scholar 

  34. Faridbod F, Ganjali MR, Dinarvand R, Norouzi P (2007) African J Biotechnol 6:2960–2987

    CAS  Google Scholar 

  35. Granzhan AV, Charykov AK (1993) Pharm Chem J 27:517–523

    Google Scholar 

  36. Faridbod F, Ganjali MR, Dinarvand R, Norouzi P (2008) Sensors 8:2331–2412

    Article  Google Scholar 

  37. Mashhadizadeh MH, Mostafavi A, Allah-Abedi H, Sheikhshoai I (2006) Sens Actuators B 113:930–936

    Article  Google Scholar 

  38. Reddy KM, Song C (1996) Catal Lett 36:103–109

    Article  CAS  Google Scholar 

  39. Badiei A, Bonneviot L (1998) Inorg Chem 37:4142–4145

    Article  CAS  Google Scholar 

  40. Lorencetti LL, Gushikem Y, Kubota LT, Oliveria Neto G, Fernandes JR (1995) Microchim Acta 117:239–244

    Article  CAS  Google Scholar 

  41. IUPAC Analytical Chemistry Division, Commission on Analytical Nomenclature. Recommendations for nomenclature of ion-selective electrodes (1976) Pure Appl Chem 48:127

    Article  Google Scholar 

  42. Ganjali MR, Memari Z, Faridbod F, Dinarvand R, Norouzi P (2008) Electroanalysis 20:2663–2670

    Article  CAS  Google Scholar 

  43. Gupta VK, Al Hayat M, Singh AK, Pal MK (2009) Anal Chim Acta 634:36–43

    Article  CAS  Google Scholar 

  44. Ganjali MR, Norouzi P, Faridbod F, Yousefi M, Naji L, Salavati-Niasari M (2007) Sens Actuators B 120:494–499

    Article  Google Scholar 

  45. Ganjali MR, Norouzi P, Faridbod F, Riahi S, Ravanshad J, Tashkhourian J, Salavati-Niasari M, Javaheri M (2007) IEEE Sensor J 7:544–550

    Article  CAS  Google Scholar 

  46. Gupta VK, Jain S, Chandra S (2003) Anal Chim Acta 486:199–207

    Article  CAS  Google Scholar 

  47. Gupta VK, Singh AK, Gupta B (2006) Anal Chim Acta 575:198–204

    Article  CAS  Google Scholar 

  48. Ganjali MR, Norouzi P, Mirnaghi FS, Riahi S, Faridbod F (2007) IEEE Sens J 7:544–550

    Article  CAS  Google Scholar 

  49. Faridbod F, Ganjali MR, Larijani B, Norouzi P, Riahi S, Mirnaghi FS (2007) Sensors 7:3119–3135

    Article  CAS  Google Scholar 

  50. Buck PR, Lindner E (1994) Pure Appl Chem 66:2527–2532

    Article  CAS  Google Scholar 

  51. Umezawa Y, Umezawa K, Sato H (1995) Pure Appl Chem 67:507–518

    Article  Google Scholar 

  52. Riahi S, Faridbod F, Ganjali MR (2009) Sensor Lett 7:42–49

    Article  CAS  Google Scholar 

  53. Ganjali MR, Norouzi P, Faridbod F, Sepehrifard A, Ghandi M, Moghimi A (2007) Can J Anal Sci Spec 52:46–56

    CAS  Google Scholar 

  54. Ganjali MR, Norouzi P, Dinarvand R, Faridbod F, Moghlimi M (2008) J Anal Chem 63:684–689

    Article  CAS  Google Scholar 

  55. Gupta VK, Goyal RN, Sharma RA (2009) Int J Electrochem Sci 4:156–172

    CAS  Google Scholar 

  56. Gupta VK, Chandra S, Agarwal S, Lang H (2005) Sens Actuators B 107:762–767

    Article  Google Scholar 

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Acknowledgements

The authors are grateful to the Research Council of University of Tehran for the financial support of this work.

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Authors and Affiliations

  1. Center of Excellence in Electrochemistry, Faculty of Chemistry, University of Tehran, Tehran, Iran

    Mohammad Reza Ganjali, Mehdi Asgari, Farnoush Faridbod & Parviz Norouzi

  2. Endocrinology and Metabolism Research Center, University of Tehran Medical Sciences, Tehran, Iran

    Mohammad Reza Ganjali, Farnoush Faridbod & Parviz Norouzi

  3. School of Chemistry, College of Science, University of Tehran, Tehran, Iran

    Alireza Badiei & Javad Gholami

Authors
  1. Mohammad Reza Ganjali
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  2. Mehdi Asgari
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  3. Farnoush Faridbod
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  4. Parviz Norouzi
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  5. Alireza Badiei
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  6. Javad Gholami
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Correspondence to Mohammad Reza Ganjali.

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Ganjali, M.R., Asgari, M., Faridbod, F. et al. Thiomorpholine-functionalized nanoporous mesopore as a sensing material for Cd2+ carbon paste electrode. J Solid State Electrochem 14, 1359–1366 (2010). https://doi.org/10.1007/s10008-009-0937-8

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  • DOI: https://doi.org/10.1007/s10008-009-0937-8

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