Abstract
Nanosized carbon-coated Li1−3x La x FePO4 composites were synthesized using a fast, easy, microwave assisted, room-temperature, solid-state method. A lanthanum precursor was used to improve the electronic conductivity of LiFePO4. The particle structure of the as-synthesized samples was observed using transmission electron microscopy. The results indicated that a uniform and continuous carbon layer was formed on the surface of Li1−3x La x FePO4 particles. Electrochemical techniques, such as cyclic voltammetry, charge/discharge test, and electrochemical impedance spectroscopy were used to investigate the electrochemical performance of the samples. The results of electrochemical measurements revealed that the carbon coating and lanthanum doping provided an initial discharge capacity of 145 mA h/g with excellent rate capacity and long cycling stability. These advantages, coupled with the low cost, the high thermal stability, and the environmental friendliness of the raw materials, render Li1−3x La x FePO4/C composites attractive for practical and large-scale applications.
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Padhi AK, Nanjundaswamy KS, Goodenough JB (1997) J Electrochem Soc 144:1188
Song M-S, Kang Y-M, Kim J-H, Kim H-S, Kim D-Y, Kwon H-S, Lee J-Y (2007) J Power Sources 166:260
Giorgetti M, Berrettoni M, Scaccia S, Passerini S (2006) Inorg Chem 45:2750
Wang Y, Wang Y, Hosono E, Wang K, Zhou H (2008) Angew Chem Int Ed 47:7461
Shin HC, Cho WI, Jang H (2006) Electrochim Acta 52:1472
Chung S-Y, Bloking JT, Chiang Y-M (2002) Nat Mater 1:123
Wang Y, Wang J, Yang J, Nuli Y (2006) Adv Funct Mater 16:2135
Liu H, Cao Q, Fu LJ, Li C, Wu YP, Wu HQ (2006) Electrochem Commun 8:1553
Jayaprakash N, Kalaiselvi N (2007) Electrochem Commun 9:620
Herle PS, Ellis B, Coombs N, Nazar LF (2004) Nat Mater 3:147
Wang GX, Bewlay SL, Konstantinov K, Liu HK, Dou SX, Ahn JH (2004) Electrochim Acta 50:443
Wang D, Li H, Shi S, Huang X, Chen L (2005) Electrochim Acta 50:2955
Liao X-Z, He Y-S, Ma Z-F, Zhang X-M, Wang L (2007) J Power Sources 174:720
Li X, Kang F, Bai X, Shen W (2007) Electrochem Commun 9:663
Dominko R, Bele M, Gaberscek M, Remskar M, Hanzel D, Goupil JM, Pejovnik S, Jamnik J (2006) J Power Sources 153:274
Sanchez MAE, Brito GES, Fantini MCA, Goya GF, Matos JR (2006) Solid State Ionics 177:497
Gaberscek M, Dominko R, Bele M, Remskar M, Hanzel D, Jamnik J (2005) Solid State Ionics 176:1801
Yang S, Song Y, Zavalij PY, Stanley Whittingham M (2002) Electrochem Commun 4:239
Yamada A, Chung SC, Hinokuma K (2001) J Electrochem Soc 148:A224
Prosini PP, Zane D, Pasquali M (2001) Electrochim Acta 46:3517
Arnold G, Garche J, Hemmer R, Ströbele S, Vogler C, Wohlfahrt-Mehrens M (2003) J Power Sources 119–121:247
Ye XR, Jia DZ, Yu JQ, Xin XQ, Xue Z (1999) Adv Mater 11:941
Wang R-Y, Jia D-Z, Zhang L, Liu L, Guo Z-P, Li B-Q, Wang J-X (2006) Adv Funct Mater 16:687
Gerbec JA, Magana D, Washington A, Strouse GF (2005) J Am Chem Soc 127:15791
Wang L, Huang Y, Jiang R, Jia D (2007) J Electrochem Soc 154:A1015
Wang L, Huang Y, Jiang R, Jia D (2007) Electrochim Acta 52:6778
Zhuang D, Zhao X, Xie J, Tu J, Zhu T, Cao G (2006) Acta Phys-Chim Sin 22:840
Morgan D, Van der Ven A, Ceder G (2004) Electrochem Solid-State Lett 7:A30
Guo ZP, Liu H, Bewlay S, Liu HK, Dou SX (2005) Synth Met 153:113
Hu YS, Guo YG, Dominko R, Gaberscek M, Jamnik J (2007) Adv Mater 19:1963
Cho Y-D, Fey G, Kao H-M (2008) J Solid State Electrochem 12:815
Yang R, Song X, Zhao M, Wang F (2009) J Alloys Compd 468:365
Ying J, Lei M, Jiang C, Wan C, He X, Li J, Wang L, Ren J (2006) J Power Sources 158:543
Zhou Y-K, He B-L, Zhou W-J, Li H-L (2004) J Electrochem Soc 151:A1052
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This work was supported by grants from the Natural Science Foundation of Xinjiang Province (Nos. 200821121 and 200721102) and the National Natural Science Foundation of China (Nos. 20666005 and 20661003).
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Li, D., Huang, Y., Jia, D. et al. Synthesis and electrochemical properties of nanosized carbon-coated Li1−3x La x FePO4 composites. J Solid State Electrochem 14, 889–895 (2010). https://doi.org/10.1007/s10008-009-0875-5
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DOI: https://doi.org/10.1007/s10008-009-0875-5