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Synthesis and characteristics of nanostructured Li(Co1/3Ni1/3Mn1/3)O2 cathode material prepared at 0 °C

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Abstract

Special synthetic conditions at 0 °C were used to prepare nanostructured Li[Ni1/3Co1/3Mn1/3]O2 via chemical coprecipitation synthesis. The precursor preparation shows platelet shape with thickness of 10 nm and width of 100 nm. After calcination, the particles change to spherical or rectangle shape with a size of 100~200 nm. The nanostructured Li[Ni1/3Co1/3Mn1/3]O2 shows a well-ordered layered hexagonal lattice with low cation mixing. Galvanostatic testing showed good electrochemical properties and high rate capability, which may be due to its unique morphological and structural characteristics. Synthesis at 0 °C effectively prevented growth of the precursor particles and produced nanosize Li[Ni1/3Co1/3Mn1/3]O2, which gave improvement in high rate performance and favoring the future use of this cathode material for high power applications.

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Acknowledgment

This work was supported by the Development Program for Outstanding Young Teachers in Harbin Normal University (KGB200805) and Postdoctoral Foundation of Heilongjiang Province, China.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Provincial Key Lab for Nano-functionalized Materials and Excitated State, Harbin Normal University, Harbin, Heilongjiang, 150025, China

    C. Deng, B. Wu & H. Q. Li

  2. College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin, Heilongjiang, 150001, China

    S. Zhang & S. Y. Yang

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  1. C. Deng
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  2. S. Zhang
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  3. B. Wu
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  4. S. Y. Yang
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  5. H. Q. Li
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Correspondence to C. Deng or S. Zhang.

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Deng, C., Zhang, S., Wu, B. et al. Synthesis and characteristics of nanostructured Li(Co1/3Ni1/3Mn1/3)O2 cathode material prepared at 0 °C. J Solid State Electrochem 14, 871–875 (2010). https://doi.org/10.1007/s10008-009-0874-6

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  • DOI: https://doi.org/10.1007/s10008-009-0874-6

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