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A new strategy for fabrication Fe2O3/SiO2 composite coatings on the Ti substrate

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Abstract

We report here on the synthesis of homogenous, well-adherent composite film of Fe2O3/SiO2, up to 7 μm thick, on the titanium substrate by anodic treatment optimized for an aqueous suspension of K2O·SiO2 and Fe2O3 powder under galvanostatic conditions. The end products were characterized by scanning electron microscopy, energy-dispersive X-ray, X-ray powder diffractometry, X-ray photoelectron spectroscopy, and Mössbauer spectroscopy, concluding that the formation of composite coating at the SiO2 to Fe2O3 ratio of approximately 1:1 proceeds just after formation of a thin TiO2 layer with Fe2O3 particle inclusions without transformations via an electrophoresis deposition of negatively charged Fe2O3 species enveloped by silica ions.

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Acknowledgments

This research was in part supported by a grant from the Lithuanian State Science and Studies Foundation (C-07035). The authors are grateful to Remigijus Juškėnas from the Institute of Chemistry for assistance in XRD spectroscopy.

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Authors and Affiliations

  1. Institute of Chemistry, A. Goštauto 9, 01108, Vilnius, Lithuania

    Arūnas Jagminas, Rimas Ragalevičius, Vitalija Jasulaitienė & Algis Selskis

  2. Institute of Physics, Savanorių 231, 02300, Vilnius, Lithuania

    Kestutis Mažeika, Jonas Reklaitis & Dalis Baltrūnas

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  1. Arūnas Jagminas
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  2. Rimas Ragalevičius
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  3. Kestutis Mažeika
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  6. Algis Selskis
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Correspondence to Arūnas Jagminas.

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Jagminas, A., Ragalevičius, R., Mažeika, K. et al. A new strategy for fabrication Fe2O3/SiO2 composite coatings on the Ti substrate. J Solid State Electrochem 14, 271–277 (2010). https://doi.org/10.1007/s10008-009-0820-7

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  • DOI: https://doi.org/10.1007/s10008-009-0820-7

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