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Facile fabrication of porous NiO films for lithium-ion batteries with high reversibility and rate capability

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Abstract

We report the high-rate capability and good cyclability of three-dimension nanoporous NiO films as the anodes of lithium-ion batteries. The NiO films are fabricated by immersing foam nickel substrates in an 80 °C aqueous solution containing ammonia and potassium peroxydisulfate, and subsequent heat treatment at 500 °C. At a rate of 1.0 C, the film electrodes maintain a capacity of 560 mAh g−1 as well as capacity retention of 97% after 100 discharge/charge cycles. When the current density is increased to 14C, 42% of the capacity can be retained. Owing to the ease of large-scale fabrication and superior electrochemical performance, these NiO films will be promising anodes for high-energy-density lithium-ion batteries.

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Acknowledgement

The work was supported by program of excellent team in Harbin Institute of Technology.

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Authors and Affiliations

  1. School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin, 150001, People’s Republic of China

    Qinmin Pan & Jia Liu

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  1. Qinmin Pan
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  2. Jia Liu
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Correspondence to Qinmin Pan.

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Pan, Q., Liu, J. Facile fabrication of porous NiO films for lithium-ion batteries with high reversibility and rate capability. J Solid State Electrochem 13, 1591–1597 (2009). https://doi.org/10.1007/s10008-008-0740-y

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  • DOI: https://doi.org/10.1007/s10008-008-0740-y

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