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Chemical diffusion of electroactive species in ionic compounds: a focus on chemical equilibrium constraint

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Abstract

This work aims at considering the theoretical basis of chemical diffusion of electroactive species in ionic compounds, in particular from the perspective of the chemical equilibrium constraint. For this purpose, first a variety of descriptions on diffusivity are briefly summarised from the viewpoint of driving forces. Then, the equations to stand for the chemical diffusion behaviour are theoretically derived with and without the chemical equilibrium constraint. Finally, the two different situations above are critically compared to explore the origin of chemical diffusion in ionic compounds.

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Acknowledgements

This work supported by a grant-in-aid for the National Core Research Center Program from MOST and KOSEF (No. R15-2006-022-01001-0). Furthermore, this work was partly supported by the Brain Korea 21 project.

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Authors and Affiliations

  1. Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology, #373-1, Guseong-dong, Yuseong-gu, Daejeon, 305-701, Republic of Korea

    Sung-Jai Lee & Su-Il Pyun

  2. School of Materials Science & Engineering, Pusan National University, San 30, Jangjeon-dong, Geumjeong-gu, Busan, 609-735, Repubic of Korea

    Heon-Cheol Shin

Authors
  1. Sung-Jai Lee
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  2. Su-Il Pyun
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  3. Heon-Cheol Shin
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Correspondence to Su-Il Pyun.

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Lee, SJ., Pyun, SI. & Shin, HC. Chemical diffusion of electroactive species in ionic compounds: a focus on chemical equilibrium constraint. J Solid State Electrochem 13, 829–836 (2009). https://doi.org/10.1007/s10008-008-0617-0

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  • DOI: https://doi.org/10.1007/s10008-008-0617-0

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