Abstract
The electrophoretic deposition combined with common pressure hydrothermal treatment was employed to prepare nanocrystalline TiO2 thin film from suspension of tetra-n-butyl titanate and P25 at low temperature. The tetra-n-butyl titanate was hydrolyzed and crystallized into anatase to interconnect nanocrystalline TiO2 particles and to stick them to a conductive substrate by common pressure hydrothermal treatment to improve the electron transport properties of the deposited thin film. A dye-sensitized solar cell based on TiO2 thin film prepared by the low temperature method yielded the conversion efficiency of 6.12%. Due to the relative slower electron transport rate in the deposited film, its conversion efficiency was slightly lower than that of the cell with TiO2 thin film prepared by the conventional high temperature sintering method. Since it is free of high temperature sintering step, this method can be used to prepare nanocrystalline TiO2 thin film on plastic polymer conductive substrate for fabrication of flexible dye-sensitized solar cell.
Similar content being viewed by others
References
Regan BO, Gratzel M (1991) Nature 353:737
Boschloo G, Lindstrom J, Magnusson E, Holmberg A, Hagfeldt A (2002) J Photochem Photobiol A 148:11
Lindstrom H, Holmberg A, Magnusson E, Lindquist SE, Malmqvist L, Hagfeldt A (2001) Nano Lett 1:97
Lindstrom H, Magnusson E, Holmberg A, Sodergren S, Lindquist SE, Hagfeldt A (2002) Sol Energy Mater Sol Cells 73:91
De Paoli MA, Nogueira AF, Machado DA, Longo C (2001) Electrochim Acta 46:4243
Miyasaka T, Kijitori Y, Murakami TN, Kimura M, Uegusa S (2002) Chem Lett 12:1250
Miyasaka T, Kijitori Y (2004) J Electrochem Soc 151A:1767
Kim GS, Seo HK, Godble VP, Kim YS, Yang OB, Shin HS (2006) Electrochem Commun 8:961
Yoshida T, Oekermann T, Okabe K, Schlettwein D, Funabiki K, Minoura H (2002) Electrochemistry 70:470
Matsumoto Y, Noguchi M, Matsunaga T, Kamada K, Koinuma M, Yamada S (2001) Electrochemistry 69:314
Karuppuchamy S, Nonomura K, Yoshida T, Sugiura T, Minoura H (2002) Solid State Ionics 151:19
Zhang DS, Yoshida T, Minoura H (2002) Chem Lett 9:874
Zhang DS, Yoshida T, Furuta K, Minoura H (2004) J Photochem Photobiol A 164:159
Longo C, Nogueira AF, De Paoli MA, Cachet H (2002) J Phys Chem B 106:5925
Park NG, Schlichthorl G, van de Lagemaat J, Cheong HM, Mascarenhas A, Frank AJ (1999) J Phys Chem B 103:3308
Nakade S, Matsuda M, Kambe S, Saito Y, Kitamura T, Sakata T, Wada Y, Mori H, Yanagida S (2002) J Phys Chem B 106:10004
Murakami TN, Kijitori Y, Kawashima N, Miyasaka T (2004) J Photochem Photobiol A 164:187
Murakami TN, Kijitori Y, Kawashima N, Miyasaka T (2003) Chem Lett 32:1076
Lee S, Jun Y, Kim KJ, Kim D (2001) Sol Energy Mater Sol Cells 65:193
Menzies DB, Dai Q, Bourgeois L, Caruso RA, Cheng YB, Simon GP, Spiccia L (2007) Nanotechnology 18:25608
Xagas AP, Bernard MC, Hugot-Le Goff A, Spyrellis N, Loizos Z, Falaras P (2000) J Photochem Photobiol A 132:115
Li CY, Lin Y, Li XP, Wang ZP, Ma YT, Zhou XW, Feng SJ, Xiao XR (2005) Chin Sci Bull 501:1449
Zhang DS, Yoshida T, Oekermann T, Furuta K, Minoura H (2006) Adv Funct Mater 16:1228
Acknowledgments
We gratefully acknowledge the financial support from the Major State Basic Research Development Program (2006CB202605), High-Tech Research and Development of China Program (2007AA05Z439), the National Nature Science Foundation of China (50221201), and the Innovative Foundation of the Center for Molecular Science, Chinese Academy of Science (CMS-CX200718).
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Tan, W., Chen, J., Zhou, X. et al. Preparation of nanocrystalline TiO2 thin film at low temperature and its application in dye-sensitized solar cell. J Solid State Electrochem 13, 651–656 (2009). https://doi.org/10.1007/s10008-008-0605-4
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10008-008-0605-4