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Investigation on cell impedance for high-power lithium-ion batteries

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Abstract

Variation of the dc polarization with time has been successfully calculated semiempirically for the lithium-ion battery at a variety of discharging rates. In particular, with the help of circuit analysis, the contribution of the uncompensated ohmic resistance, interfacial impedance, and diffusion impedance to total cathodic polarization has been satisfactorily differentiated as a function of discharging time. In the present work, a simple and practical method has been suggested to help one design effectively the high-power lithium-ion batteries.

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Acknowledgments

This work was supported by the Korea Research Foundation Grant funded by the Korean Government (MOEHRD; KRF-2006-331-D00713). Incidentally, this work was partially supported by a grant-in-aid for the National Core Research Center Program from the Ministry of Science and Technology and the Korea Science and Engineering Foundation (no. R15-2006-022-01001-0).

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Correspondence to Heon-Cheol Shin.

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Dedicated to Professor Su-II Pyun on the occasion of his 65th birthday.

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Kang, DK., Shin, HC. Investigation on cell impedance for high-power lithium-ion batteries. J Solid State Electrochem 11, 1405–1410 (2007). https://doi.org/10.1007/s10008-007-0371-8

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  • DOI: https://doi.org/10.1007/s10008-007-0371-8

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