Abstract
The simultaneous electrodeposition of the system Cu–In–Se was investigated. The study was carried out at pH 8.5 using diethylentriamine as complexing agent for the Cu+2 ion. The synthesis of CuInSe2 semiconductor thin films was carried out by electrodeposition on different substrates [indium–tin oxide (ITO) on glass, aluminum and type 304 steel]. The simultaneous codeposition of the Cu, In, and Se was achieved by constant potential electrolysis technique in aqueous solutions containing the elements that conform this material. The deposits of CuInSe2 were about 4 μm thick, which is thick enough for the photovoltaic effect to take place. The as-deposited films were characterized by atomic emission spectroscopy with inductive coupling plasm (AES-ICP) and scanning electronic microscopy (SEM). Annealed films were characterized X-ray diffraction, optical NIR spectroscopy, and photoelectrochemical studies The films were obtained with a well-defined composition, very close to the expected one. Homogeneous deposit with chalcopyrite structure was produced. A In2O3 phase was also observed. Annealing of the film improved the crystallinity of the films. Good photo response, an appropriate absorption coefficient, and a band gap of 1.09 eV were obtained.
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References
Bhattacharga RN (1983) J Electrochem Soc 130:2040
Shay JL, Tell B, Kasper HM, Schiavone LM (1973) Phys Rev B7:4485
Daniel Lincot (2005) Thin Solid Films 487:40–48
Moorthy S, Babu AE, Lux-Steiner M Ch (2005) Journal of Crystal Growth 275:e1241
Bereznev S, Kois J, Golovtsov I, Öpik A, Mellikov E (2006) Thin Solid Films (in press)
Kois J, Bereznev S, Mellikov E, Öpik A (2006) Thin Solid Films (in press)
Lincot D, Guillemoles JF, Taunier S, Guimard D, Sicx-Kurdi J, Chaumont A, 8 Roussel O, Ramdani O, Hubert C, Fauvarque JP, (2004) Solar Energy 77:725
Chraibi F, Fahoume M, Ennaoui A, Delplancke JLM(2004) J Condensed Matter 5:188
Menezes S (2002) Electrochemical and Solid-State Letter 5(9):C79–C81
Chakraborty H, Rahman ML (1993) Transition Metal Chemistry 18(6):545
Pourbaix M (1966) Atlas of Electrochemical Equilibria, Pergamon , New York
Al-Bassam AAI (1999) Physica B:Condensed Matter 266:192–197
Delgado G, Mora A J, Pineda C, Tinoco T (2001) Materials Research Bulletin 36:2507
PDF-ICDD-Powder Diffraction File (2001) International Centre for Diffraction Data, USA
De Silva KTL, Priyantha WAA, Jayanetti JKDS, Chithrani BD, Siripala W, Blake K, Dharmadasa IM (2001) Thin Solid Films 382:158–163
Huang CJ, Meen TH, Lai MY, Chen WR (2002) Solar Energy Materials & Solar Cells 82:553–565
Kemell M, Ritala M, Saloniemi H, Leskelä M, Sajavaara T, Rauala E (2000) J Electrochem Soc 147 (3):1080–1087
J Tauc (Ed.) (1974) Amorphous and Liquid Semiconductors, Plenum, New York
Pattabi M, Sebastian PJ, Mathew X, Bhattacharya RN (2000) Solar Energy Materials & Solar Cells 63:315–323
Acknowledgement
The authors wish to gratefully acknowledge the financial support from FONACIT (Project S1 2001001163) and CDCHT-ULA (Project C-1327-05-08-B).
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Araujo, J., Ortíz, R., López-Rivera, A. et al. Electrochemical growth of CuInSe2 thin film on different substrates from alkaline medium. Characterization of the films. J Solid State Electrochem 11, 407–412 (2007). https://doi.org/10.1007/s10008-006-0162-7
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DOI: https://doi.org/10.1007/s10008-006-0162-7