Abstract
Measurements of oxygen permeation through dense \({\hbox{Sr}}_{{1 - x}} {\left( {{\hbox{Fe,Al}}} \right)}{\hbox{O}}_{{3 - \delta }} - {\hbox{SrAl}}_{{\text{2}}} {\hbox{O}}_{4}\) composite membranes showed a considerable influence of processing conditions on the surface exchange kinetics, while the bulk ambipolar conductivity is almost unaffected by microstructural factors. Compared to the materials prepared via the glycine–nitrate process (GNP), the surface limitations to oxygen transport are significantly higher for dual-phase \({\left( {{\hbox{SrFe}}} \right)}_{{0.7}} {\left( {{\hbox{SrAl}}_{{{2}}} } \right)}_{{0.3}} {\hbox{O}}_{{3.3 - \delta }}\) made of a commercial powder synthesized by spray pyrolysis. This difference in behavior may be related to compositional inhomogeneities in the grains of A-site deficient perovskite phase and an enhanced surface concentration of grain boundaries in the case of GNP-synthesized composite, which has also smaller grain size, slightly higher thermal expansion and lower total conductivity. No essential effects on Vickers hardness, varying in the range 6.3–6.5 GPa, were found. The deposition of porous catalyst layers onto the composite surface exposed to reducing environment leads to membrane decomposition. For the fabrication of tubular membranes, the cold isostatic pressing technique was, hence, combined with mechanical treatment to increase the specific surface area without incorporation of catalytically active components.
Similar content being viewed by others
References
Dyer PN, Richards RE, Russek SL, Taylor DM (2000) Solid State Ionics 134:21
Diethelm S, Sfeir J, Clemens F, Van herle J, Favrat D (2004) J Solid State Electrochem 8:611
Pei S, Kleefisch MS, Kobylinski TP, Faber J, Udovich CA, Zhang-McCoy V, Dabrowski B, Balachandran U, Mieville RL, Poeppel RB (1995) Catal Letters 30:201
Bahteeva JA, Leonidov IA, Patrakeev MV, Mitberg EB, Kozhevnikov VL, Poeppelmeier KR (2004) J Solid State Electrochem 8:578
Mazanec TJ, Cable TL, Frye JG, Kliewer WR (1997) US Patent 5591315
Kharton VV, Shaula AL, Snijkers FMM, Cooymans JFC, Luyten JJ, Yaremchenko AA, Valente AA, Tsipis EV, Frade JR, Marques FMB, Rocha J (2005) J Membr Sci 252:215
Kharton VV, Yaremchenko AA, Shaula AL, Viskup AP, Marques FMB, Frade JR, Naumovich EN, Casanova JR, Marozau IP (2004) Defect Diffus Forum 226–228:141
Yaremchenko AA, Kharton VV, Valente AA, Shaula AL, Marques FMB, Rocha J (2005) Solid State Ionics (in press)
Christie GM, van Berkel FPF (1996) Solid State Ionics 83:17
Kharton VV, Marques FMB (2002) Curr Opin Solid State Mater Sci 6:261
Zhang K, Yang YL, Ponnusamy D, Jacobson AJ, Salama K (1999) J Mater Sci 34:1367
Kharton VV, Naumovich EN, Kovalevsky AV, Viskup AP, Figueiredo FM, Bashmakov IA Marques FMB (2000) Solid State Ionics 138–135
Diethelm S, Van herle J, Sfeir J, Buffat P (2005) J Eur Ceram Soc 25:2191
Shaula AL, Viskup AP, Kharton VV, Logvinovich DI, Naumovich EN, Frade JR, Marques FMB (2003) Mater Res Bull 38:353
Kharton VV, Kovalevsky AV, Yaremchenko AA, Figueiredo FM, Naumovich EN, Shaula AL, Marques FMB (2002) J Membr Sci 195:277
Steele BCH (1995) Solid State Ionics 75:157
Murphy MW, Armstrong TR, Smith PA (1997) J Am Ceram Soc 80:165
Kharton VV, Yaremchenko AA, Naumovich EN (1999) J Solid State Electrochem 3:303
West AR (1984) Solid state chemistry and its applications. Wiley, Chichester NY Brisbane
Hayashi H, Kanoh M, Quan CJ, Inaba H, Wang S, Dokiya M, Tagawa H (2000) Solid State Ionics 132:227
Kharton VV, Kovalevsky AV, Tsipis EV, Viskup AP, Naumovich EN, Jurado JR, Frade JR (2002) J Solid State Electrochem 7:30
Kharton VV, Waerenborgh JC, Viskup AP, Yakovlev SO, Patrakeev MV, Gaczyñski P, Marozau IP, Yaremchenko AA, Shaula AL, Samakhval VV (2006) J Solid State Chem (in press)
Isupova LA, Yakovleva IS, Rogov VA, Alikina GM, Sadykov VA (2004) Kinet Catal 45:446
Kharton VV, Yaremchenko AA, Tsipis EV, Valente AA, Patrakeev MV, Shaula AL, Frade JR, Rocha J (2004) Appl Catal A 261:25
Bouwmeester HJM, Burggraaf AJ (1996) Dense ceramic membranes for oxygen separation. In: Burggraaf AJ, Cot L (eds) Fundamentals of inorganic membrane science and technology. Elsevier, Amsterdam, pp 435–528
Hendriksen PV, Larsen PH, Mogensen M, Poulsen FW, Wiik K (2000) Catal Today 56:283
Kharton VV, Yaremchenko AA, Valente AA, Sobyanin VA, Belyaev VD, Semin GL, Veniaminov SA, Tsipis EV, Shaula AL, Frade JR, Rocha J (2005) Solid State Ionics 176:781
Acknowledgements
This work was partially supported by the FCT, Portugal (projects POCI/CTM/58570/2004, SFRH/BPD/15003/2004 and SFRH/BPD/11606/2002), and by the NATO Science for Peace program (project 978002). Experimental assistance of A. Shaula and I. Marozau is gratefully acknowledged.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Kharton, V.V., Kovalevsky, A.V., Yaremchenko, A.A. et al. Oxygen transport and thermomechanical properties of SrFe(Al)O3-δ –SrAl2O4 composites: microstructural effects. J Solid State Electrochem 10, 663–673 (2006). https://doi.org/10.1007/s10008-006-0141-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10008-006-0141-z