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Electrochemical study of copper and bismuth compounds in the solid state by using voltammetry of immobilized microparticles: application to YBa2Cu3O7– x (s) and Bi2Sr2CaCu2O8– x (s) high transition temperature superconductors

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Abstract.

In this paper, an electrochemical study was carried out of different solid samples, such as Cu2O(s), CuO(s), Bi2O3(s) and NaBiO3(s) and their binary mixtures, in order to characterize the high transition temperature superconductors YBa2Cu3O7– x (s) and Bi2Sr2CaCu2O8– x (s). These studies were carried out by using an electrode with a glassy tube and a plastic piston, containing a mass of carbon paste bound with liquid paraffin. The technique employed in our paper is similar to that developed by others.

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Authors and Affiliations

  1. Department of Analytical Chemistry, Faculty of Sciences, University of Valladolid, C/Prado de la Magdalena s/n, 47005 Valladolid, Spain, , , , ,

    Ana Alonso Sedano, Luz M. Tascón García, Dolores M. Vázquez Barbado & Pedro Sánchez Batanero

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  1. Ana Alonso Sedano
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  2. Luz M. Tascón García
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  3. Dolores M. Vázquez Barbado
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  4. Pedro Sánchez Batanero
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Alonso Sedano, A., Tascón García, L.M., Vázquez Barbado, D.M. et al. Electrochemical study of copper and bismuth compounds in the solid state by using voltammetry of immobilized microparticles: application to YBa2Cu3O7– x (s) and Bi2Sr2CaCu2O8– x (s) high transition temperature superconductors. J Solid State Electrochem 7, 301–308 (2003). https://doi.org/10.1007/s10008-002-0334-z

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  • DOI: https://doi.org/10.1007/s10008-002-0334-z

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