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Investigations towards nano-hybrid resin-based composites

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Abstract

Objective

Clinical data indicate an increased trend in material fracture as reason for failure in composite restorations, questioning whether modern resin-based composites (RBCs) are able to fulfil the rising aesthetical demands and to provide at the same time a sufficient mechanical stability also in larger cavities. Nano-hybrid RBCs are promoted as materials with improved mechanical properties. The aim of this study was to analyse differences in mechanical properties within and between modern flowable and non-flowable nano-hybrid and micro-hybrid RBCs by measuring mechanical properties at macro- and micro-scale.

Methods

Thirty-four RBCs with traditional and new monomer formulation or photo-polymerization initiator technology—15 nano-hybrid, nine micro-hybrid and ten flowable—were therefore considered. Flexural strength, flexural modulus (Eflexural), indentation modulus, Vickers hardness (HV) and creep were measured after the samples had been stored in water for 24 h at 37°C. Differences within the materials as well as within material categories were statistically analysed using one-way ANOVA with Tukey HSD post hoc test (α = 0.05) as well as partial eta-square statistics.

Results

The category of micro- and nano-hybrid RBCs performed in all properties superior compared to the flowable RBCs. The former two categories differ significantly only with regard to three parameters, with nano-hybrid RBCs showing higher HV respectively lower Eflexural and filler weight. The micro-mechanical parameters proved to be more sensitive to differences in filler amount and RBCs type than the macro-mechanical properties.

Clinical relevance

Only few differences were found between nano-hybrid and micro-hybrid RBCs as a material category and thus, from laboratory tests, no clear advantages in the mechanical stability in stress-bearing areas of nano-hybrid RBCs are expected clinically. Similar is valid for materials with new monomer formulation or photo-polymerization initiator technology. However, several of the measured nano-hybrid RBCs showed consistently higher mechanical properties than the mean values of the micro-hybrid RBCs.

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References

  1. Sarrett DC (2005) Clinical challenges and the relevance of materials testing for posterior composite restorations. Dent Mater 21:9–20

    Article  PubMed  Google Scholar 

  2. Brunthaler A, Konig F, Lucas T, Sperr W, Schedle A (2003) Longevity of direct resin composite restorations in posterior teeth. Clin Oral Investig 7:63–70

    Article  PubMed  Google Scholar 

  3. van Dijken JW (2000) Direct resin composite inlays/onlays: an 11 year follow-up. J Dent 28:299–306

    Article  PubMed  Google Scholar 

  4. Van Nieuwenhuysen JP, D'Hoore W, Carvalho J, Qvist V (2003) Long-term evaluation of extensive restorations in permanent teeth. J Dent 31:395–405

    Article  PubMed  Google Scholar 

  5. Trujillo-Lemon M, Ge J, Lu H, Tanaka J, Stansbury J (2006) Dimethacrylate derivates of dimer acid. J Polymer Sci 44:3921–3929

    Google Scholar 

  6. Reiners J, Podszun W, Winkel J (1990) (Meth)acrylic acid derivates of tricyclo(5.2.1.02.6)decanes containing urethane groups Europe: BAYER AG

  7. Kurokawa R, Finger WJ, Hoffmann M, Endo T, Kanehira M, Komatsu M, Manabe A (2007) Interactions of self-etch adhesives with resin composites. J Dent 35:923–929

    Article  PubMed  Google Scholar 

  8. Marchesi G, Breschi L, Antoniolli F, Di Lenarda R, Ferracane J, Cadenaro M (2010) Contraction stress of low-shrinkage composite materials assessed with different testing systems. Dent Mater 26:947–953

    Article  PubMed  Google Scholar 

  9. Utterodt A (2008) Dental composites with Tricyclo[5.2.02.6]decane derivatives Europe: Heraeus Kulzer GmbH (Hanau, DE)

  10. Utterodt A (2008) Compositions for dental composites with tricyclo[5.2.1.02.6]decane derivates. United States: Heraeus Kulzer GmbH (Hanau, DE)

  11. Koo JH (2006) Processing of Nanomaterials. In: Polymer nanocomposites: processing, characterization, and applications, McGraw-Hill, New York, pp 61–75

  12. Wagner D, Vaia R (2004) Nanocomposites: issues at the interface. Mater Today 7:38–42. doi:10.1016/S1369-7021(04)00507-3

    Google Scholar 

  13. Ilie N, Hickel R (2009) Investigations on mechanical behaviour of dental composites. Clin Oral Investig 13:427–438

    Article  PubMed  Google Scholar 

  14. Ilie N, Hickel R (2009) Macro-, micro- and nano-mechanical investigations on silorane and methacrylate-based composites. Dent Mater 25:810–819

    Article  PubMed  Google Scholar 

  15. Curtis AR, Palin WM, Fleming GJ, Shortall AC, Marquis PM (2009) The mechanical properties of nanofilled resin-based composites: characterizing discrete filler particles and agglomerates using a micromanipulation technique. Dent Mater 25:180–187

    Article  PubMed  Google Scholar 

  16. Curtis AR, Palin WM, Fleming GJ, Shortall AC, Marquis PM (2009) The mechanical properties of nanofilled resin-based composites: the impact of dry and wet cyclic pre-loading on bi-axial flexure strength. Dent Mater 25:188–197

    Article  PubMed  Google Scholar 

  17. Lohbauer U, von der Horst T, Frankenberger R, Kramer N, Petschelt A (2003) Flexural fatigue behavior of resin composite dental restoratives. Dent Mater 19:435–440

    Article  PubMed  Google Scholar 

  18. Maseki T, Nitta T, Yamase M, Yamada T, Ogawa S, Kimishima T, Nara Y, Dogon IL (2010) Characteristics in polymerization shrinkage of latest low-shrinkage resin composite restoratives. J Dent Res 89:457

    Google Scholar 

  19. Platt J, Macpherson M, Rhodes B (2010) Polymerization shrinkage and contraction stress of an experimental composite. J Dent Res 89:1024

    Google Scholar 

  20. Wei Y, Silikas N, Zhang ZT, Watts DC (2011) Hygroscopic dimensional changes of self-adhering and new resin-matrix composites during water sorption/desorption cycles. Dent Mater 27:259–266

    Google Scholar 

  21. Weinmann W, Thalacker C, Guggenberger R (2005) Siloranes in dental composites. Dent Mater 21:68–74

    Article  PubMed  Google Scholar 

  22. Bettencourt AF, Neves CB, de Almeida MS, Pinheiro LM, Oliveira SA, Lopes LP, Castro MF (2010) Biodegradation of acrylic based resins: A review. Dent Mater 26:e171–e180

    Article  PubMed  Google Scholar 

  23. Palin WM, Fleming GJ, Burke FJ, Marquis PM, Randall RC (2005) The influence of short and medium-term water immersion on the hydrolytic stability of novel low-shrink dental composites. Dent Mater 21:852–863

    Article  PubMed  Google Scholar 

  24. Bayne SC, Heymann HO, Swift EJ Jr (1994) Update on dental composite restorations. J Am Dent Assoc 125:687–701

    PubMed  Google Scholar 

  25. Suzuki S, Leinfelder KF, Kawai K, Tsuchitani Y (1995) Effect of particle variation on wear rates of posterior composites. Am J Dent 8:173–178

    PubMed  Google Scholar 

  26. Jin XB, Bertrand, S, Hammesfahr P (2009) New radically polymerizable resins with remarkably low curing stress. J Dent Res 88:1651

    Google Scholar 

  27. Ilie N, Hickel R (2011) Investigations on a methacrylate-based flowable composite based on the SDR technology. Dent Mater 27:348–355

    Article  PubMed  Google Scholar 

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The authors declare that they have no conflict of interest.

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Correspondence to Nicoleta Ilie.

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Ilie, N., Rencz, A. & Hickel, R. Investigations towards nano-hybrid resin-based composites. Clin Oral Invest 17, 185–193 (2013). https://doi.org/10.1007/s00784-012-0689-1

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