JBIC Journal of Biological Inorganic Chemistry

, Volume 22, Issue 6, pp 969–975 | Cite as

Comparative studies of reaction of cobalamin (II) and cobinamide (II) with sulfur dioxide

  • Ilia A. Dereven’kov
  • Pavel A. Ivlev
  • Cristina Bischin
  • Denis S. Salnikov
  • Radu Silaghi-Dumitrescu
  • Sergei V. Makarov
  • Oscar I. Koifman
Original Paper

Abstract

The kinetics of reactions of cobalamin (II) and cobinamide (II) with sulfur dioxide was studied by UV–visible (UV–vis) spectroscopy. Reaction results in oxidation of Co(II) center and involves two aquated SO2 moieties. The final product is suggested to be complex Co(III)–S2O4•–. The absence of corrin ring modifications during the reactions was proved.

Keywords

Cobalamin Cobinamide Sulfur dioxide Redox reactions Kinetics 

Abbreviations

Cbl

Cobalamin

Cbi

Cobinamide

DMBI

5,6-dimethylbenzimidazole

S(IV)

Sulfite species

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Copyright information

© SBIC 2017

Authors and Affiliations

  • Ilia A. Dereven’kov
    • 1
  • Pavel A. Ivlev
    • 1
  • Cristina Bischin
    • 2
  • Denis S. Salnikov
    • 1
  • Radu Silaghi-Dumitrescu
    • 2
  • Sergei V. Makarov
    • 1
  • Oscar I. Koifman
    • 1
  1. 1.Institute of Macroheterocyclic CompoundsIvanovo State University of Chemistry and TechnologyIvanovoRussia
  2. 2.Department of Chemistry and Chemical Engineering“Babes-Bolyai” UniversityCluj-NapocaRomania

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