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Dynamics of Guest Water Molecules in Pillared Mordenite Studied by 1H NMR Relaxation

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Abstract

The dynamics of H2O molecules confined in mesopores of about 3.4 nm in size, formed by amorphous SiO2 pillars separating 2D mordenite nanolayers, was probed by 1H nuclear magnetic relaxation. 1H nuclear magnetic resonance (NMR) spectra evidence the presence of water with different local surroundings and mobility. The temperature dependence of 1H spin–lattice relaxation T1 and relaxation in rotating frame T1ρ indicate the complex behavior of nanoconfined water that can be characterized by different activation energies: freezing (29 kJ/mol), fast rotation (12 kJ/mol), and translational motion (23.6 kJ/mol).

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Data Availability

The data that support the findings of this study are available from the corresponding author, [M.G.S], upon reasonable request.

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Acknowledgements

The samples were synthesized at the Center for Nanoscience and Nanotechnology, National Autonomous University of Mexico (CNYN-UNAM), and studied at the Research Park of Saint Petersburg State University: Thermogravimetric and Calorimetric Research Centre, Centre for Diagnostics of Functional Materials for Medicine, Pharmacology and Nanoelectronics. H’Linh Hmok acknowledges the support of Van Lang University.

Funding

This study was supported by the Russian Science Foundation within the framework of project No. 23-23-00448.

Author information

Authors and Affiliations

  1. Saint Petersburg State University, 7/9 Universitetskaya Nab., Saint Petersburg, 199034, Russia

    Marina G. Shelyapina, Denis Yu. Nefedov, Anastasiia O. Antonenko, Andrei V. Egorov, Maria I. Egorova & Alexandr V. Ievlev

  2. Simulation in Materials Science Research Group, Science and Technology Advanced Institute, Van Lang University, Ho Chi Minh City, Vietnam

    H’Linh Hmok

  3. Faculty of Applied Technology, School of Technology, Van Lang University, Ho Chi Minh City, Vietnam

    H’Linh Hmok

  4. Tecnológico Nacional de México/Instituto Tecnológico Superior de Guasave, Carretera a Brecha Sin Número, Ejido Burrioncito, 81149, Guasave, Sinaloa, México

    Rosario Yocupicio-Gaxiola

  5. Centro de Nanociencias y Nanotecnología, Universidad Nacional Autónoma de México, 22860, Ensenada, México

    Vitalii Petranovskii, Joel Antúnez-García & Sergio Fuentes

Authors
  1. Marina G. Shelyapina
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Contributions

MGS: Conceptualization, Validation, Writing—original draft, Writing—review and editing, Supervision, Project administration, Funding acquisition. DYuN, AON, AVI: Data curation, Investigation. H’LH: Investigation. AVE: Investigation, Formal analysis, Writing—review and editing. MIE: Visualization, Formal analysis. RYG: Methodology, VP, JAG, SF: Conceptualization, Writing—review and editing.

Corresponding authors

Correspondence to Marina G. Shelyapina or H’Linh Hmok.

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Shelyapina, M.G., Nefedov, D.Y., Antonenko, A.O. et al. Dynamics of Guest Water Molecules in Pillared Mordenite Studied by 1H NMR Relaxation. Appl Magn Reson 54, 915–928 (2023). https://doi.org/10.1007/s00723-023-01589-w

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