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Magnetic Phase Separation in Double Perovskite Sr2TiMnO5.87

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Abstract

The double perovskite Sr2TiMnO5.87 was synthesized via the solution combustion precursor method using Sr(NO3)2, MnO2, i-Ti(OC3H7)4, and disubstituted ammonium citrate as a complexing agent. The crystal structure and unit cell parameters are refined by the Rietveld method using powder X-ray diffraction. The magnetic properties of double perovskites Sr2TiMnO5.87 were studied using the ESR spectroscopy, specific heat measurements in the temperature range ~ 5–300 K, and magnetometry under cooling in zero- (ZFC) and nonzero-fields (FC). The four ESR line were observed in ESR spectra, three ESR lines with g ~ 2 and fourth ESR at Bres = 50 mT in both X-and Q-bands measurements in the temperature range 37.5–42 K in Sr2TiMnO5.87. The peaks obtained in real and imaginary parts of AC magnetization measurements confirm phase separation at the same temperatures. The antiferromagnetic ordering was found out below the temperature TN ≈ 12 K. The fitting Debye and Einstein temperatures, obtained from the specific heat measurements, are equal to θD = 217 K, θE1 = 275 K, θE2 = 615 K, and θE3 = 2000 K.

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Acknowledgements

This research was supported by the Russian Science Foundation (Project No. 22-42-02014) and DST Project number DST/INT/RUS/RSF/P-55/2021.

Funding

This research was supported by the Russian Science Foundation (Project No. 22–42-02014) and DST Project number DST/INT/RUS/RSF/P-55/2021.

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Authors and Affiliations

  1. Zavoisky Physical-Technical Institute, Federal Research Center ‘‘Kazan Scientific Center of RAS’’, Sibirsky Tract, 10/7, 420029, Kazan, Russia

    D. V. Popov, I. V. Yatsyk, I. A. Faizrakhmanov, I. I. Fazlizhanov & R. M. Eremina

  2. Kazan (Volga Region) Federal University, Kremlevskaya St., 18, 420008, Kazan, Russia

    R. G. Batulin, M. A. Cherosov, I. R. Vakhitov & R. V. Yusupov

  3. Institute of Solid State Chemistry of the Russian Academy of Sciences (UB), Pervomaiskaya St., 91, Ekaterinburg, 620990, Russia

    T. I. Chupakhina & Yu. A. Deeva

  4. Department of Materials Science and Engineering, Indian Institute of Technology Kanpur, Kanpur, 208016, UP, India

    T. Maiti

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Contributions

DVP—acquired data visualization, writing an article (review and editing). IVY—ESR measurement in X-band. RGB—magnetization measurements. MAC—specific heat data measurements. IRV—XPS measurements. RVY—interpretation of XPS. IAF—SEM experiment. TIC—fit of X-ray data and synthesis of the sample. YAD—synthesis of the sample. IIF—ESR measurement in Q-band. TM—conceptualization, writing an article (review and editing). RME—writing an article (original draft), supervision.

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Correspondence to D. V. Popov.

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Popov, D.V., Yatsyk, I.V., Batulin, R.G. et al. Magnetic Phase Separation in Double Perovskite Sr2TiMnO5.87. Appl Magn Reson 54, 561–580 (2023). https://doi.org/10.1007/s00723-023-01541-y

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