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Magnetic Properties of La0.81Sr0.19Mn0.9Fe0.1−xZnxO3 (x = 0, x = 0.05)

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Abstract

Magnetic properties of polycrystalline La0.81Sr0.19Mn0.9Fe0.1−xZnxO3 (x = 0, 0.05) have been investigated by means of electron spin resonance, magnetic susceptibility, and Mössbauer measurements. Both samples show a clear ferromagnetic transition. The Curie temperature TC decreases on increasing Fe content (x = 0.05—TC = 222 K; x = 0—TC = 148 K). Mössbauer studies indicate that Fe in these compounds is in the trivalent high-spin state. The temperature evolution of the Mössbauer spectra at low temperatures (T < TC) is typical for ferromagnetic clusters with a wide distribution in size and magnetic correlation length. The inverse susceptibility of all the samples deviates from the Curie–Weiss law above TC, indicating the presence of fluctuations on approaching magnetic order. An anomalous downturn of the inverse susceptibility for x = 0.05 significantly above TC and the concomitant observation of ferromagnetic resonance signals coexisting with the paramagnetic resonance up to approximately room temperature, is caused by a Griffiths-like behavior. This regime is characterized by the coexistence of ferromagnetic entities within the globally paramagnetic phase.

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The data that were used and analyzed are presented in the article.

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Acknowledgements

The authors thank Dana Vieweg for SQUID measurements.

Funding

This work was partially supported by the Deutsche Forschungsgemeinschaft (DFG) within the Transregional Collaborative Research Center TRR 80 "From Electronic Correlations to Functionality", project no. 107745057 (Augsburg, Munich, Stuttgart). The work of Z.Y. Seidov, M.M. Tagiev and D.S. Abdinov was supported by the Science Development Foundation under the President of the Republic Azerbaijan Grant EIF-BGM-4-RFTF-1/2017–21/03/1-M-03. Electron spin resonance measurements (I.V. Yatsyk, V.A. Shustov, R.M. Eremina) were performed with the financial support from the government assignment for FRC Kazan Scientific Center of RAS.

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Authors and Affiliations

  1. Zavoisky Physical-Technical Institute, Federal Research “Kazan Scientific Center of RAS”, Kazan, 420029, Russia

    R. M. Eremina, I. V. Yatsyk & V. A. Shustov

  2. Institute of Physics, Azerbaijan National Academy of Sciences, Baku, AZ1143, Azerbaijan

    Z. Y. Seidov & D. S. Abdinov

  3. Institute of Physics, Kazan Federal University, Kazan, 420008, Russia

    F. G. Vagizov

  4. Astrakhan State University, Astrakhan, 414056, Russia

    A. G. Badelin & V. K. Karpasyuk

  5. Azerbaijan State University of Economics, Baku, AZ1001, Azerbaijan

    M. M. Tagiev

  6. Institute for Metallurgy, Ural Division of RAS, Yekaterinburg, 620016, Russia

    S. Kh. Estemirova

  7. Experimental Physics V, EKM, Institute of Physics, University of Augsburg, 6135, Augsburg, Germany

    H.-A. Krug von Nidda

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  1. R. M. Eremina
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Contributions

RE and ZS: conceptualization, methodology, formal analysis, original draft preparation, writing—review and editing, supervision; FV: investigation by Mössbauer method, methodology, formal analysis, writing—original draft; IY: Investigation by ESR method, methodology, formal analysis; VS: investigation by X-ray method, methodology, formal analysis; AB, VK, and SE: sample synthesis, methodology, characterization; DA and MT: Resources, visualization; H-A KvN: project administration, investigation of the magnetization, writing—reviewing and editing. All authors have read and agreed to the published version of the manuscript.

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Correspondence to Z. Y. Seidov.

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Eremina, R.M., Yatsyk, I.V., Seidov, Z.Y. et al. Magnetic Properties of La0.81Sr0.19Mn0.9Fe0.1−xZnxO3 (x = 0, x = 0.05). Appl Magn Reson 54, 449–461 (2023). https://doi.org/10.1007/s00723-022-01510-x

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