Abstract
Seven binary mixed oxides of V2O5, MoO3, TiO2, B2O3, Bi2O3, In2O3, and Tm2O3, in which V2O5 is a permanent component, were prepared by the method of mechanochemical activation (MCA). All composites have been investigated using EPR spectroscopy, X-ray diffraction, BET analysis and EPR spectra calculations. The results obtained were compared with those for individual V2O5 powder. The kinetic of structural transformations occurring in these binary mixtures under MCA were quantitatively characterized using a developed program of EPR spectra analysis. These structural rearrangements are fitted well by the first-order rate constants. Influence of the oxide nature mixed with vanadium pentoxide, the ratio of the components and time of milling on these transformations are discussed.
Similar content being viewed by others
References
I. Georgiadou, S. Slavov, C.H. Papadopoulou, H.K. Matralis, C.H. Kordulis, Vanadium-Titanium Oxide Catalysts (Wiley-VCH Verlag, Weinheim, Influence of the Preparation Method on the O-Xylene Selective Oxidation, 1995).
O.V. Krylov, Heterogeneous Catalysis (Akademkniga, Moscow, 2004). (in Russian)
J. Haber, Catal. Today 142, 100 (2009)
X. Liu, J. Zeng, H. Yang, K. Zhou, D. Pan, RSC Adv. 8, 4014 (2018)
L.T. Denisova, L.A. Irtyugo, Yu.F. Kargin, L.G. Chumilina, N.V. Belousova, V.M. Denisov, N.A. Galiakhmetova, Inorg. Mater. 53, 300 (2017)
B. Deroide, R. Backov, J.R. Zanchetta, J. Phys. Chem. Solids 61, 819 (2000)
T.V. Andrushkevich, Yu.A. Chesalov, Russ. Chem. Rev. 87, 586 (2018)
M. Sutradhar, L.M.D.R.S. Martins, M.F.C.G. da Silva, A.J.L. Pombeiro, Coord. Chem. Rev. 301–302, 200 (2015)
A.G.J. Ligtenbarg, R. Hage, B.L. Feringa, Coord. Chem. Rev. 237, 89 (2003)
W.E. Slink, P.B. De Groot, J. Catal. 68, 423 (1981)
P.A. Vakhrushin, T.V. Sviridova, M.V. Vishnetskaya, D.V. Sviridov, A.I. Kokorin, Russ. J. Phys. Chem. B 6, 711 (2012)
I.E. Wachs, Dalton Trans. 42, 11762 (2013)
K.-T. Li, N.-S. Shyu, Ind. Eng. Chem. Res. 36, 1480 (1997)
S. Beg, S. Haneef, N.A.S. Al-Areqi, Phase Trans. 83, 1114 (2010)
B.M. Wanklyn, J. Crystal Growth 56, 368 (1970)
A. Ghosh, B.K. Chaudhuri, J. Mater. Sci. 22, 2369 (1987)
Yu.V. Emelianova, PhD Thesis, Ural Federal University, Ekaterinburg, (2006)
T. Tojo, Q.W. Zhang, F. Saiyo, Chem. Sustain. Develop. 15, 243 (2007)
A.H. Shah, Y. Liu, V.T. Nguyen, G.S. Zakharova, I. Mehmood, W. Chen, RSC Adv. 5, 54412 (2015)
B.K. Sharma, D.C. Dube, A. Mansingh, J. Non-Cryst, Solids 65, 39 (1984)
R. Iordanova, Y. Dimitriev, E. Kashcheva, D. Klissurski, RSC Adv. 5, 54412 (2015)
H.A. Kuska, M.T. Rogers, ESR of First Row Transition Metal Complex Ions (Interscience, New York, 1968 (Mir, Moscow, 1970).
S.A. Al’tshuler, B.M. Kozyrev, Electron Paramagnetic Resonance of the Compounds of Intermediate Groups (Nauka, Moscow, 1972). (in Russian)
A.I. Kokorin, in Chemical physics of nanostructured semicontuctors, A.I. Kokorin, D.W. Bahnemann (eds.) (VSP−Brill Acad. Publ., Utrecht, Boston) 203−263 (2003)
F. Wang, R. Büchel, A. Savitsky, M. Zalibera, D. Widmann, S.E. Pratsinis, W. Lubitz, F. Schüth, ACS. Catal. 6, 3520 (2016)
D. Gamarra, A.L. Camara, M. Monte, S.B. Rasmussen, L.E. Chinchilla, A.B. Hungria, G. Munuera, N. Gyorffy, Z. Schay, V.C. Corberan, J.C. Conesa, A. Martinez-Arias, Appl. Catal. B. Environ. 130–131, 224 (2013)
A. Martı´nez-Arias, A.B. Hungrı´a, M. Ferna´ndez-Garcı´a, J.C. Conesa, G. Munuera, J. Phys. Chem. B. 108, 17983 (2004)
M.A.A. Issa, A.M. Hassib, Z.H. Dughaish, J. Phys. D: Appl. Phys. 17, 2037 (1984)
T.V. Sviridova, A.A. Antonova, A.I. Kokorin, E.N. Degtyarev, D.V. Sviridov, Russ. J. Phys. Chem. B 9, 22 (2015)
A.I. Kokorin, A.I. Kulak, I.S. Tomskii, Yu.N. Rufov, Russ. J. Phys. Chem. B 7, 255 (2013)
I.V. Kolbanev, E.N. Degtyarev, A.N. Streletskii, A.I. Kokorin, Appl. Magn. Reson. 47, 575 (2016)
A.I. Kokorin, T.V. Sviridova, I.V. Kolbanev, LYu. Sadovskaya, E.N. Degtyarev, G.A. Vorobieva, A.N. Streletskii, D.V. Sviridov, Russ. J. Phys. Chem. B 12, 330 (2018)
E.A. Konstantinova, A.I. Kokorin, A.A. Minnekhanov, T.V. Sviridova, D.V. Sviridov, Catal. Lett. 149, 2256 (2019)
E.A. Konstantinova, A.A. Minnekhanov, A.I. Kokorin, T.V. Sviridova, D.V. Sviridov, J. Phys. Chem. C 122, 10248 (2018)
E.V. Shelekhov, T.A. Sviridova, Met. Sci. Heat Treat. 42, 309 (2000)
A.Kh. Vorobiev, N.A. Chumakova, in: Nitroxides: theory, experiment and applications. A.I. Kokorin (ed) (InTech Publ, Riecka) 57–112 (2012)
M. Abou Fadel, A. de Juan, N. Touati, H. Vezin, L. Duponchel, J. Magn. Reson. 248, 27 (2014)
M. Vosough, C. Mason, R. Tauler, M. Jalali-Heravi, M. Maeder, J. Chemometrics 20, 302 (2006)
H. Parastar, M. Jalali-Heravi, R. Tauler, Trends Anal. Chem. 31, 134 (2012)
R. Zdunek, A. Cichocki, Neurocomputing 71, 2309 (2008)
Y.B. Monakhova, S.A. Astakhov, A. Kraskov, S. Mushtakova, Chemometr. Intell. Lab. Systems 103, 108 (2010)
A. Baikadi, N. Bhatt, S. Narasimhan, Ind. Eng. Chem. Res. 58, 13437 (2019)
A.I. Kulak, S.O. Travin, A.I. Kokorin, Appl. Magn. Reson. 51, 1005 (2020)
A.N. Streletskii, I.V. Kolbanev, G.A. Vorob’eva, A.V. Leonov, A.B. Borunova, A.A. Dubinskii, Colloid. J. 81, 567 (2019)
A.I. Kokorin, A.N. Streletskii, I.V. Kolbanev, A.B. Borunova, N. Ye, A.V. Degtyarev, D.G. Leonov, E.A.K. Permenov, J. Phys. Chem. C. 123, 19991 (2019)
A.I. Kokorin, V.I. Pergushov, A.I. Kulak, Catal. Lett. 150, 263 (2020)
G.R. Eaton, S.S. Eaton, D.P. Barr, R.T. Weber, Quantitative EPR (Springer, Wien, 2010).
D.R. Lide, Handbook of Chemistry and Physics (CRC Press, New York, 2004), pp. 1536–1538
Acknowledgements
This work was supported by the State assignment of RF No AAAA-A20-120021390044-2 and partially by Russian Foundation for Basic Research (Grant No. 19-03-00358-a). We are thankful to Prof. A. Kh. Vorob’ev (Department of Chemistry, M. V. Lomonosov Moscow State University) provided us his computer Program package and to Dr. Y. N. Kozlov (N. Semenov Federal Research Center for Chemical Physics RAS) for helpful discussions.
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Kokorin, A.I., Travin, S.O., Kolbanev, I.V. et al. Quantitative EPR Investigation of Binary Mixed Oxides Containing V2O5 Prepared by Mechanochemical Activation. Appl Magn Reson 52, 927–944 (2021). https://doi.org/10.1007/s00723-021-01314-5
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00723-021-01314-5