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Exchange Interactions in Heteronuclear Clusters Containing Dysprosium Ions: EPR Spectroscopy Possibility

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Abstract

The exchange interaction in two isostructural compounds [M2Dy2 (μ3–OH)2(L)2(O2CPh–Me–p)6] (M = Al, Cr) is studied by electron paramagnetic resonance (EPR). Studies have been performed on polycrystalline samples in different frequency ranges. The features of the shape of the spectra of clusters containing dysprosium ions are analyzed and experimental spectra are described using calculated spectra for tetranuclear clusters. The value Jzz = − 0.86 cm−1 of the spin–spin interaction of the Ising form JzzS1zS2z between dysprosium ions in the Al2Dy2 cluster, which exhibits single-molecule magnet properties, was experimentally determined. The study of the heteronuclear Cr2Dy2 cluster has demonstrated a number of features of the EPR spectra due to the Cr–Dy interaction. It is shown that this interaction has a predominantly Ising form with the parameter JCrDyzz = − 1 cm−1. However, the Cr–Dy pair fragment does not have a center of symmetry, and this suggests the presence of an antisymmetric term in the spin–spin interaction tensor, the manifestation of which is observed in the X-band EPR spectrum.

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References

  1. N. Ishikawa, M. Sugita, T. Ishikawa, S.-Y. Koshihara, Y. Kaizu, J. Am. Chem. Soc. 125, 8694–8695 (2003)

    Article  Google Scholar 

  2. R.J. Blagg, C.A. Muryn, E.J.L. McInnes, F. Tuna, R.E.P. Winpenny, Angew. Chem., Int. Ed. 50, 6530 (2011)

    Article  Google Scholar 

  3. V. Mereacre, A. Baniodeh, C.E. Anson, A.K. Powell, J. Am. Chem. Soc. 133, 15335–15337 (2011)

    Article  Google Scholar 

  4. A. Baniodeh, V. Mereacre, N. Magnani, Y. Lan, J.A. Wolny, V. Schenemann, C.E. Anson, A.K. Powell, Chem. Commun. 49, 9666–9668 (2013)

    Article  Google Scholar 

  5. A. Baniodeh, Y. Lan, G. Novitchi, V. Mereacre, A. Sukhanov, M. Ferbinteanu, V. Voronkova, C.E. Anson, A.K. Powell, Dalton Trans. 42, 8926–8938 (2013)

    Article  Google Scholar 

  6. A. Baniodeh, A. Mondal, R. Galeev, A. Sukhanov, R. Eremina, V. Voronkova, A. Powell, Appl. Magn. Reson. 48(1), 101–113 (2017)

    Article  Google Scholar 

  7. S.K. Langley, D.P. Wielechowski, V. Vieru, N.F. Chilton, B. Moubaraki, B.F. Abrahams, L.F. Chibotaru, K.S. Murray, Angew. Chem. Int. Ed. 52, 12014–12019 (2013); Angew. Chem. 125, 12236–12241 (2013)

    Article  Google Scholar 

  8. S.K. Langley, D.P. Wielechowski, V. Vieru, N.F. Chilton, B. Moubaraki, L.F. Chibotaru, K.S. Murray, Chem. Sci. 5, 3246 (2014)

    Article  Google Scholar 

  9. L. Ungur, M. Thewissen, J.-P. Costes, W. Wernsdorfer, L.F. Chibotaru, Inorg. Chem. 52, 6328–6337 (2013)

    Article  Google Scholar 

  10. S.T. Langley, D.P. Wielechowski, N.F. Chilton, B. Moubaraki, K.S. Murray, Inorg. Chem. 54, 10497–10503 (2015)

    Article  Google Scholar 

  11. S.K. Langley, D.P. Wielechowski, B. Moubaraki, K.S. Murray, Chem. Commun. 52, 10976–10979 (2016)

    Article  Google Scholar 

  12. Y. Peng, V. Mereacre, C.E. Anson, A.K. Powell, Phys. Chem. Chem. Phys. 18, 21469–21480 (2016)

    Article  Google Scholar 

  13. V. Vieru, L. Ungur, V. Cemortan, A. Sukhanov, A. Baniodeh, ChE Anson, A.K. Powell, V. Voronkova, L.F. Chibotaru, Chem. Eur. J. 24(62), 16652–16661 (2018)

    Article  Google Scholar 

  14. Y. Peng, M.K. Singh, V. Mereacre, C.E. Anson, G. Rajaraman, A.K. Powell, Chem. Sci. (2019). https://doi.org/10.1039/c8sc05362f

    Article  Google Scholar 

  15. Q.Y.M. Zheng, H.H. Zou, H.L. Wang, DCh. Liu, YCh. Liu, F.P. Liang, J. Clus. Sci. 30, 25–30 (2019)

    Article  ADS  Google Scholar 

  16. D. Gatteschi, R. Sessoli, J. Villain, Molecular Тanomagnetism (Oxford University Press, Oxford, 2007)

    Google Scholar 

  17. D. Gatteschi, R. Sessoli, Angew. Chem. Int. Ed. 42, 268–297 (2003)

    Article  Google Scholar 

  18. F.S. Guo, B.M. Day, Y.C. Chen, M.L. Tong, A. Mansikkamäki, R.A. Layfield, Science 362, 400–1403 (2018). https://doi.org/10.1126/science.aav0652

    Article  Google Scholar 

  19. V. Tangoulis, A. Figuerola, Chem. Phys. 140, 293–301 (2007)

    Article  Google Scholar 

  20. E.M. Pineda, N.F. Chilton, R. Marx, M. Dorfel, D.O. Sells, P. Neugebauer, S.D. Jiang, D. Collison, J. Slageren, E.J.L. McInnes, R.E.P. Winpenny, Nat. Commun. 5, 5243 (2014)

    Article  ADS  Google Scholar 

  21. A. Abragam, B. Bleaney, Electron Paramagnetic Resonance of Transition Ions (Clarendon, Oxford, 1970)

    Google Scholar 

  22. L.V. Mingalieva, R.T. Galeev, A.A. Sukhanov, V.K. Voronkova, I.K. Budnikova, G. Novitchi, Appl. Magn. Reson. 49, 61–69 (2018)

    Article  Google Scholar 

  23. K.M. Salikhov, R.T. Galeev, V.K. Voronkova, YuV Yablokov, J. Legendziewicz, Appl. Magn. Reson. 14, 457–472 (1998)

    Article  Google Scholar 

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Acknowledgements

This work was supported in part by the Presidium of the Russian Academy of Sciences Program No. 5: “Photonic technologies in probing inhomogeneous media and biological objects”.

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Authors and Affiliations

  1. Zavoisky Physical-Technical Institute, FRC Kazan Scientific Center of RAS, Kazan, Russian Federation

    R. T. Galeev, L. V. Mingalieva, A. A. Sukhanov & V. K. Voronkova

  2. Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Karlsruhe, Germany

    Y. Peng & A. K. Powell

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  1. R. T. Galeev
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  2. L. V. Mingalieva
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  3. A. A. Sukhanov
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  4. V. K. Voronkova
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Correspondence to R. T. Galeev.

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Galeev, R.T., Mingalieva, L.V., Sukhanov, A.A. et al. Exchange Interactions in Heteronuclear Clusters Containing Dysprosium Ions: EPR Spectroscopy Possibility. Appl Magn Reson 50, 1429–1441 (2019). https://doi.org/10.1007/s00723-019-01160-6

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  • DOI: https://doi.org/10.1007/s00723-019-01160-6

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