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Selective Hole-Burning in RIDME Experiment: Dead-Time Free Measurement of Dipolar Modulation

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Abstract

The most common technique used in pulse electron paramagnetic resonance spectroscopy to determine interspin distances in the nanometer range is pulse electron double resonance, while relaxation-induced dipolar modulation enhancement (RIDME) is a promising alternative to this method. In this article we introduced a selective hole-burning technique for RIDME experiment, which allows dead-time free measurement of dipolar modulation without the use of the second microwave frequency or a magnetic field jump. This technique was tested on a short, stable biradical in a frozen solution, and the optimal experimental conditions for the measurement of dipolar modulation were found. Interspin distances in the range of 13 Å ≤ r ≤ 25 Å can be measured by the proposed method.

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Acknowledgments

The work was supported by the program of the Presidium of the Russian Academy of Sciences no. 23/24.48 “Nanodynamics of disordered media” and the Ministry of Education and Science of the Russian Federation number 11.519.11.1006. We are grateful to Dr. K. L. Ivanov for helpful discussion.

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Authors and Affiliations

  1. Zavoisky Physical-Technical Institute, Russian Academy of Sciences, Kazan, Russia

    K. B. Konov

  2. Kazan National Research Technological University, Kazan, Russia

    A. A. Knyazev & Yu. G. Galyametdinov

  3. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch of Russian Academy of Sciences, Novosibirsk, Russia

    N. P. Isaev & L. V. Kulik

Authors
  1. K. B. Konov
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  2. A. A. Knyazev
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  3. Yu. G. Galyametdinov
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  4. N. P. Isaev
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  5. L. V. Kulik
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Correspondence to L. V. Kulik.

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Konov, K.B., Knyazev, A.A., Galyametdinov, Y.G. et al. Selective Hole-Burning in RIDME Experiment: Dead-Time Free Measurement of Dipolar Modulation. Appl Magn Reson 44, 949–966 (2013). https://doi.org/10.1007/s00723-013-0464-8

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  • DOI: https://doi.org/10.1007/s00723-013-0464-8

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