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Electron Spin Resonance and Ground State Wave Functions of Vanadyl Ion in LiNaSO4

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Abstract

Electron spin resonance (ESR) of VO2+ doped into LiNaSO4 has been studied at 300 K on an X-band spectrometer. The ESR powder spectra have been analyzed and spin Hamiltonian parameters have been evaluated. Using the crystal-field approach, a theoretical estimate of the ground state wave functions of VO2+ in LiMSO4 (M = Na, K) has been made from the ESR data. The dipolar hyperfine coupling constant P and Fermi contact parameter K have also been estimated.

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Authors and Affiliations

  1. Department of Physics and Astrophysics, University of Delhi, Delhi, India

    Manu Jain

  2. Research and Development Cell, Vidya College of Engineering, Vidya Knowledge Park, Baghpat Road, Meerut, 250002, India

    V. K. Jain

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  1. Manu Jain
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  2. V. K. Jain
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Correspondence to V. K. Jain.

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Jain, M., Jain, V.K. Electron Spin Resonance and Ground State Wave Functions of Vanadyl Ion in LiNaSO4 . Appl Magn Reson 40, 171–176 (2011). https://doi.org/10.1007/s00723-010-0190-4

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  • DOI: https://doi.org/10.1007/s00723-010-0190-4

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