Abstract
The scope of the electron paramagnetic resonance (EPR) technique in catalysis is often limited because of the presence of the ferromagnetic nanoparticles in many catalytic systems. The present work gives an effective method to discriminate solid-state EPR spectra in the microwave resonance absorption while investigating such systems. The approach is based on the different features of the EPR spectra and ferromagnetic resonance absorption that are simultaneously observed in the system.
Similar content being viewed by others
Notes
It is necessary to keep in mind that discussions about the statistical formation process of the unaveraged spectrum leave open the question about the physical nature of the individual lines.
References
G.A. Bykhtiyarova, V.I. Bykhtiyarov, N.S. Sakaeva, V.V. Kaichev, B.P. Zolotovskii, J. Mol. Catal. A Chem. 158, 251–255 (2000)
E.A. El-Katatnya, S.A. Halawyb, A.M. Mohamed, M.I. Zaki, Appl. Catal. A General 199, 83–92 (2000)
P.P. Bakare, S.K. Date, Y.B. Khollam, S.B. Deshpande, H.S. Potdar, S. Salunke-Gawali, F. Varret, E. Pereira, Hyperfine Interact. 168, 1127–1132 (2006)
D. Makovec, S. Campel, M. Bele, U. Maver, M. Zorko, M. Drofenik, J. Jamnik, M. Gaberˇsˇcek, Colloids Surf. A Physicochem. Eng. Asp. 334, 74–79 (2009)
S. Zeng, K. Tang, T. Li, J. Colloids Interface Sci. 312, 513–521 (2007)
R. Zboril, M. Mashlan, K. Barcova, M. Vujtek, Hyperfine Interact. 139/140, 597–606 (2002)
W. Low, M. Weger, Phys. Rev. 118, 1130–1136 (1960)
B.V. Nekrasov, Textbook of General Chemistry, vol. 2 (Chemistry Publications, Moscow, 1973)
O.N. Martyanov, R.N. Lee, V.F. Yudanov, J. Magn. Magn. Mater. 267, 13–18 (2003)
O.N. Matryanov, S.N. Trukhan, V.F. Yudanov, Appl. Magn. Reson. 33, 57–71 (2008)
S.N. Trukhan, O.N. Martyanov, V.F. Yudanov, Phys. Solid State 50, 456–462 (2008)
M.M. Yulikov, O.N. Matryanov, V.F. Yudanov, Appl. Magn. Reson. 23, 105–112 (2002)
O.N. Martyanov, V.F. Yudanov, J. Struct. Chem. 40, 878–882 (1999)
P.H. Kasai, J. Phys. Chem. 66, 674–680 (1961)
A.J. Shuskus, Phys. Rev. 127, 1529–1531 (1962)
Acknowledgments
The work has been performed with the financial support of the program nr. 27 of the Presidium of the Russian Academy of Sciences “Basic research in the nanotechnologies and nanomaterials”.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Yakushkin, S.S., Trukhan, S.N., Yudanov, V.F. et al. Features of EPR Application to Systems Containing Paramagnetic Centers and Ferromagnetic Nanoparticles. Appl Magn Reson 38, 495–500 (2010). https://doi.org/10.1007/s00723-010-0146-8
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00723-010-0146-8