Abstract
The formation of hydrogen bonds and molecular dynamics of alkenylphenol derivatives has been investigated in solution using nuclear magnetic resonance. The results confirm formation of an N···H, O···H-type intramolecular hydrogen bond. The spin–lattice relaxation times (T 1) and activation energy of molecular dynamics have been investigated confirming the importance of relaxation times as a very sensitive tool for studying molecular mobility.
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References
V.I. Bakhmutov, Practical NMR Relaxation for Chemists (Wiley, England, 2004), 202 p.
A.A. Vashman, I.S. Pronin, Nuclear Magnetic Relaxation and its Application in Chemical Physics (Nauka, Moscow, 1979), 234 p.
A.A. Vashman, I.S. Pronin, Nuclear Magnetic Relaxation Spectroscopy (Nauka, Moscow, 1986), 98 p.
T. Yamaguchi, N. Matubayasi, M. Nakahara, J. Mol. Liq. 119, 119A–123A (2005)
A. Szady-Chelmieniecka, E. Grech, Z. Rozwadowski, T. Dziembowska, W. Schilf, B. Kamienski, J. Mol. Struct. 565–566, 125–128 (2001)
A.J. Horsewill, A. Aibout, J. Phys. Condens. Matter. 1, 9609–9622 (1989)
A. Robert, H. Bernheim, H.S. Gutowsky, J. Lawrenson, J. Chem. Phys. 34, 565–569 (1961)
I.G. Mamedov, A.M. Maharramov, M.R. Bairamov, Rus. J. Phys. Chem. 82(7), 1382–1384 (2008)
I.G. Mamedov, A.M. Maharramov, M.R. Bairamov, Actual Problems of Magnetic Resonance and its Application (Kazan State University, Kazan, 2007), p. 165–167 (23–28 September)
I.G. Mamedov, A.M. Maharramov, M.R. Bairamov, IX International Seminar on Magnetic Resonance (Southern Federal University, Rostov-on-Don, 2008), p. 43 (15–20 September)
I.G. Mamedov, A.M. Maharramov, M.R. Bairamov, V Winter School-Conference, Magnetic Resonance and its Application (Saint-Petersburg State University, 2008), p. 148–149 (1–5 December)
G.C. Levi, G.L. Nelson, Carbon-13 NMR for Organic Chemists (Wiley, New York, 1972), 296 p. (Russian version, Mir, 1975)
E. Breitmeier, G. Bauer, 13 C-NMR Spectroscopie (Georg Thieme Verlag, Stutgart, 1977)
S. Braun, H.O. Kalinowski, S. Berger, 100 and More Basic NMR Experiments (VCH, Weinheim, FRG, 1996), 418 p.
S.S. Gitis, A.I. Glaz, A.V. Ivanov, Practicum on Organic Chemistry (Visshaya shkola, Moscow, 1991), 303 p.
L.F. Tietze, T. Eicher, Practicum und Synthesen in Organish-Chemischen (Georg Thieme Verlag, Stutgart, 1991), 704 p.
V.V. Shpanova, V.S. Volodina, Practicum on Organic Chemistry (Goschemlit, Moscow, 1959), 888 p.
A.M. Mageramov, M.R. Bairamov, G.M. Mekhtiyeva, M.A. Agayeva, P.Sh. Mamedova, D.M. Kuliyeva, I.G. Mamedov, Rus. J. Petrol. Chem. 48(1), 63–66 (2008)
A.M. Mageramov, M.R. Bairamov, G.M. Mekhtiyeva, M.A. Agayeva, P.Sh. Mamedova, D.M. Kuliyeva, I.G. Mamedov, Rus. J. Appl. Chem. 80(4), 681–686 (2007)
T. Schaefer, J. Phys. Chem. 79(17), 1888–1890 (1975)
V.V. Moscow, Soros Educat. J. 2, 58–64 (1999)
N.D. Sokolov, Hydrogen Bond (Nauka, Moscow, 1981), 288 p.
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Mamedov, I.G., Eichhoff, U., Maharramov, A.M. et al. Molecular Dynamics of Alkenylphenol Derivatives in Solution as Studied by NMR Spectroscopy. Appl Magn Reson 38, 257–269 (2010). https://doi.org/10.1007/s00723-010-0117-0
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DOI: https://doi.org/10.1007/s00723-010-0117-0