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Investigation of Paramagnetic Centers in Fullerides A2MC60 and AM2C60 (A = K, Rb, M = Mg, Be)

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Abstract.

Paramagnetic centers in heterofullerides with the composition A2MC60 and AM2C60 (A = K, Rb, M = Mg, Be) were investigated by the electron spin resonance (ESR) method. It was found that the ESR signal can be interpreted as a composition of two lines with different temperature dependence of ESR absorption magnitude. This gives an evidence of the presence of at least two different types of paramagnetic centers. Centers of the first type behave as localized spins, while the rest can be interpreted as conduction electrons.

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Authors and Affiliations

  1. Physical Faculty, M. V. Lomonosov Moscow State University, Moscow, Russian Federation

    V. G. Kytin, A. V. Krechetov, E. A. Konstantinova, V. A. Kulbachinskii & R. A. Lunin

  2. Chemical Faculty, M. V. Lomonosov Moscow State University, Moscow, Russian Federation

    B. M. Bulychev

Authors
  1. V. G. Kytin
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  2. B. M. Bulychev
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  3. A. V. Krechetov
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  4. E. A. Konstantinova
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  5. V. A. Kulbachinskii
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  6. R. A. Lunin
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Additional information

Authors' address: Vladimir A. Kulbachinskii, Physics Faculty, M. V. Lomonosov Moscow State University, Leninskie Gory, Moscow 119991, Russian Federation

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Kytin, V., Bulychev, B., Krechetov, A. et al. Investigation of Paramagnetic Centers in Fullerides A2MC60 and AM2C60 (A = K, Rb, M = Mg, Be). Appl Magn Reson 33, 177–184 (2008). https://doi.org/10.1007/s00723-008-0048-1

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  • DOI: https://doi.org/10.1007/s00723-008-0048-1

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