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EPR Study of the Orientation Distribution Function of HO2 • Radicals Ordered by Light Irradiation

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Abstract.

Partial orientational alignment of HO2 • radicals in the matrix of glassy hydrogen peroxide was created by light irradiation. The orientation distribution function of the radicals was found by analyzing the angular dependence of electron paramagnetic resonance spectra. The direction of the dipole transition moment of HO2 • in the molecular frame of reference was determined.

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Authors and Affiliations

  1. Chemistry Department, Moscow State University, Moscow, Russian Federation

    N. A. Chumakova, T. S. Yankova & A. Kh. Vorobiev

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  1. N. A. Chumakova
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  2. T. S. Yankova
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  3. A. Kh. Vorobiev
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Authors' address: Natalia A. Chumakova, Chemistry Department, Moscow State University, Leninskiye Gory 1/3, Moscow 119899, Russian Federation

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Chumakova, N., Yankova, T. & Vorobiev, A. EPR Study of the Orientation Distribution Function of HO2 • Radicals Ordered by Light Irradiation. Appl Magn Reson 33, 117–126 (2008). https://doi.org/10.1007/s00723-008-0047-2

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  • DOI: https://doi.org/10.1007/s00723-008-0047-2

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