Abstract.
The magic-angle turning technique is applied to amorphous natural-abundance silicate materials and high-resolution silicon-29 correlations between the isotropic and anisotropic chemical shifts are obtained. Very narrow tilted spinning sideband patterns are resolved in the two-dimensional spectra whose line width corresponds to the natural line width of the silicon nuclei. Various numerical approaches are implemented to extract the distribution of the chemical shift anisotropy tensors in these materials and their results are compared.
Similar content being viewed by others
References
Donald, I.W., Metcalfe, B.L., Taylor, R.N.J.: J. Mater. Sci. 32, 5851 (1997)
Méenard, O., Advocat, T., Ambrosi, J.P., Michard, A.: Appl. Geochem. 13, 105 (1998)
Charpentier, T., Ispas, S., Profeta, M., Mauri, F., Packard, C.J.: J. Phys. Chem. B 108, 4147 (2004)
Farnan, I., Cho, H., Weber, W.J.: Nature 445, 190 (2007)
Zhang, P., Grandinetti, P., Stebbins, J.F.: J. Phys. Chem. B 101, 4004 (1997)
Zhang, P., Dunlap, C., Florian, P., Grandinetti, P.J., Farnan, I., Stebbins, J.F.: J. Non-Cryst. Solids 204, 294 (1996)
Duer, M.J., Elliot, S.R., Gladden, L.F.: J. Non-Cryst. Solids 189, 107 (1995)
Gan, Z.: J. Am. Chem. Soc. 114, 8307 (1992)
Hu, J.Z., Wang, W., Liu, F., Solum, M.S., Alderman, D.W., Pugmire, R.J., Grant, D.M.: J. Magn. Reson. A 113, 210 (1995)
Sakellariou, D., Jacquinot, J.-F., Charpentier, T.: Chem. Phys. Lett. 411, 171 (2005)
Angeli, F., Gaillard, M., Jollivet, P., Charpentier, T.: Geochim. Cosmochim. Acta 70, 2577 (2006)
Hu, J.Z., Alderman, D.W., Ye, C., Pugmire, R.J., Grant, D.M.: J. Magn. Reson. A 105, 82 (1993)
Waugh, J.S.: J. Mol. Spectrosc. 35, 298 (1970)
Larsen, F.H., Farnan, I.: Chem. Phys. Lett. 357, 403 (2002)
Hu, J.Z., Wind, R.A.: J. Magn. Reson. 163, 149 (2003)
Emerson, J., Stallworth, P., Bray, P.J.: J. Non-Cryst. Solids 113, 253 (1989)
Zwanziger, J.W.: Solid State Nucl. Magn. Reson. 3, 219 (1994)
Angeli, F., Charpentier, T., Faucon, P., Petit, J.C.: J. Phys. Chem. B 103, 10356 (1999)
Sakellariou, D., Brown, S.P., Lesage, A., Hediger, S., Bardet, M., Meriles, A., Pines, A., Emsley, L.: J. Am. Chem. Soc. 125, 4376 (2003)
Wind, R., Hu, J.Z., Majors, P.D.: Magn. Reson. Med. 55, 41 (2006)
Sakellariou, D., Meriles, C.A., Martin, R.W., Pines, A.: Magn. Reson. Imaging 23, 295 (2005)
Author information
Authors and Affiliations
Additional information
Authors' address: Dimitris Sakellariou, Laboratoire Claude Fréjacques, Service de Chimie Moléculaire, Commissariat à l'Energie Atomique Saclay, 91191 Gif-sur-Yvette cedex, France
Rights and permissions
About this article
Cite this article
Sakellariou, D., Charpentier, T. Shift Anisotropy Tensors in Amorphous Natural-Abundance Solids: High-Resolution 29Si Chemical Shift Anisotropy Distributions under Very Slow Sample Rotation. Appl Magn Reson 32, 583–594 (2007). https://doi.org/10.1007/s00723-007-0039-7
Received:
Issue Date:
DOI: https://doi.org/10.1007/s00723-007-0039-7