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Mineralogy and Petrology

, Volume 110, Issue 4, pp 547–560 | Cite as

Trace element composition of rutile and Zr-in-rutile thermometry in meta-ophiolitic rocks from the Kazdağ Massif, NW Turkey

  • Fırat ŞengünEmail author
  • Thomas Zack
Original Paper

Abstract

In northwest Turkey, ophiolitic meta-gabbros are exposed on the Kazdağ Massif located in the southern part of the Biga Peninsula. Trace element composition of rutile and Zr-in-rutile temperatures were determined for meta-gabbros from the Kazdağ Massif. The Zr content of all rutiles range from 176 to 428 ppm and rutile grains usually have a homogeneous Zr distribution. The rutile grains from studied samples in the Kazdağ Massif are dominated by subchondritic Nb/Ta (11–19) and Zr/Hf ratios (20–33). Nb/Ta and Zr/Hf show positive correlation, which is probably produced by silicate fractionation. The Nb/Ta and Zr/Hf ratios increase with a decrease in Ta and Hf contents. The core of rutile grains are generally characterized by low Nb/Ta ratios of 17–18 whereas the rims exhibit relatively high Nb/Ta ratios of 19–23. Trace element analyses in rutile suggest that these rutile grains were grown from metamorphic fluids. The P-T conditions of meta-gabbros were estimated by both Fe–Mg exchange and Zr-in-rutile thermometers, as well as by the Grt-Hb-Plg-Q geothermobarometer. The temperature range of 639 to 662 °C calculated at 9 kbar using the Zr-in-rutile thermometer is comparable with temperature estimates of the Fe-Mg exchange thermometer, which records amphibolite-facies metamorphism of intermediate P-T conditions. The P-T conditions of meta-ophiolitic rocks suggest that they occur as a different separate higher-pressure tectonic slice in the Kazdağ metamorphic sequence. Amphibolite-facies metamorphism resulted from northward subduction of the İzmir-Ankara branch of the Neo-Tethyan Ocean under the Sakarya Zone. Metamorphism was followed by internal imbrication of the Kazdağ metamorphic sequence resulting from southerly directed compression during the collision.

Keywords

Rutile Metamorphic Fluid Tectonic Slice Sakarya Zone Biga Peninsula 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgments

This study was supported by National Postdoctoral Research Scholarship Programme and the Scientific and Technological Research Council of Turkey (TÜBİTAK) grant 114Y834. We thank David Cornell for helping with SEM analyses. We would like to thank two anonymous reviewers and Johann Raith for valuable suggestions and editorial handling of manuscript.

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© Springer-Verlag Wien 2016

Authors and Affiliations

  1. 1.Terzioğlu Campus, Faculty of Engineering, Department of Geological EngineeringÇanakkale Onsekiz Mart UniversityÇanakkaleTurkey
  2. 2.Department of Earth SciencesUniversity of GothenburgGothenburgSweden

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