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Mineralogy and Petrology

, Volume 110, Issue 2–3, pp 295–307 | Cite as

Origin of Ti-rich garnets in the groundmass of Wajrakarur field kimberlites, southern India: insights from EPMA and Raman spectroscopy

  • Ashish N. Dongre
  • K. S. Viljoen
  • N. V. Chalapathi Rao
  • A. Gucsik
Original Paper

Abstract

Although Ti-rich garnets are commonly encountered in the groundmass of many alkaline igneous rocks, they are comparatively rare in kimberlites. Here we report on the occurrence of Ti-rich garnets in the groundmass of the P-15 and KL-3 kimberlites from the diamondiferous Wajrakarur field in the Eastern Dharwar craton of southern India. These garnets contain considerable Ti (11.7–23.9 wt.% TiO2), Ca (31.3–35.8 wt.% CaO), Fe (6.8–15.5 wt.% FeOT) and Cr (0.04–9.7 wt.% Cr2O3), but have low Al (0.2–5.7 wt.% Al2O3). In the case of the P-15 kimberlite they display a range in compositions from andradite to schorlomite, with a low proportion of grossular (andradite(17.7–49.9)schorlomite(34.6–49.5)-grossular(3.7–22.8)-pyrope(1.9–10.4)). A few grains also contain significant chromium and represent a solid solution between schorlomite and uvarovite. The Ti-rich garnets in the KL-3 kimberlite, in contrast, are mostly schorlomitic (54.9─90.9 mol %) in composition. The Ti-rich garnets in the groundmass of these two kimberlites are intimately associated with chromian spinels, perhaps suggesting that the garnet formed through the replacement of spinel. From the textural evidence, it appears unlikely that the garnets could have originated through secondary alteration, but rather seem to have formed through a process in which early magmatic spinels have reacted with late circulating, residual fluids in the final stages of crystallization of the kimberlite magma. Raman spectroscopy provides evidence for low crystallinity in the spinels which is likely to be a result of their partial transformation into andradite during their reaction with a late-stage magmatic (kimberlitic) fluid. The close chemical association of these Ti-rich garnets in TiO2-FeO-CaO space with those reported from ultramafic lamprophyres (UML) is also consistent with results predicted by experimental studies, and possibly implies a genetic link between kimberlite and UML magmas. The occurrence of Ti-rich garnets of similar composition in the Swartruggens orangeite on the Kaapvaal craton in South Africa, as well as in other kimberlites with an orangeitic affinity (e.g. the P-15 kimberlite on the Eastern Dharwar craton in southern India), is inferred to be a reflection of the high Ca- and high Ti-, and the low Al-nature, of the parent magma (i.e. Group II kimberlites).

Keywords

Olivine Dharwar Craton Kaapvaal Craton Eastern Dharwar Craton Metasomatic Fluid 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgments

This study was supported with funding provided to K.S. Viljoen by the South African Department of Science and Technology through their Research Chairs initiative (Geometallurgy), as administered by the National Research Foundation. In addition, the Centre of Excellence for Integrated Mineral and Energy Resource Analysis (CIMERA) at the University of Johannesburg is thanked for general funding, relating to this, and other projects. We thank Christian Reinke of the University of Johannesburg Central Analytical Facility for his assistance with the electron microprobe analyses. A. Dongre would like to thank Sebastian Tappe and Tapabrato Sarkar for their helpful discussions that ensued during the course of this study. N.V. Chalapathi Rao would like to thank DST-SERB New Delhi and Head, Department of Geology, BHU for support. We thank the reviewers, A.L. Jaques and an anonymous reviewer, as well as the guest editor, Peter Downes, for their efforts at improving the paper.

Supplementary material

710_2016_428_MOESM1_ESM.doc (152 kb)
ESM 1 (DOC 169 kb)

References

  1. Antao SM, Mohib S, Zaman M, Marr R (2015) Ti rich andradites: chemistry, structure, multi phases, optical anisotropy and oscillatory zoning. Can Mineral. doi: 10.3749/canmin.1400042 Google Scholar
  2. Becker M, Le Roex AP (2006) Geochemistry of South African on and off craton Group I and II kimberlites: petrogenesis and source region evaluation. J Petrol 47:673–703CrossRefGoogle Scholar
  3. Boyd FR, Pearson DG, Hoal KO, Hoal BG, Nixon PH, Kingston MJ, Mertzman SA (2004) Garnet Iherzolites from Louwrensia, Namibia: bulk composition and P/T relations. Lithos 77:573–592CrossRefGoogle Scholar
  4. Brey GP, Bulatov VK, Girnis AV, Lahaye Y (2008) Experimental melting of carbonated peridotite at 6–10 GPa. J Petrol 49:797–821CrossRefGoogle Scholar
  5. Buse B, Schumacher JC, Sparks RSJ, Field M (2010) Growth of bultfonteinite and hydrogarnet in metasomatized basalt xenoliths in the B/K9 kimberlite, Damtshaa, Botswana: insights into hydrothermal metamorphism in kimberlite pipes. Contrib Mineral Petrol 160:533–550CrossRefGoogle Scholar
  6. Chakhmouradian AR, McCammon CA (2005) Schorlomite: a discussion of the crystal chemistry, formula and inter-species boundaries. Phys Chem Mineral 32:277–289CrossRefGoogle Scholar
  7. Chalapathi Rao NV, Dongre AN (2009) Mineralogy and geochemistry of kimberlites NK2 and KK6, Narayanpet kimberlite field, Eastern Dharwar craton, Southern India: evidence for a transitional kimberlite signature. Can Mineral 47:1117–1135CrossRefGoogle Scholar
  8. Chalapathi Rao NV, Srivastava RK (2009) Petrology and geochemistry of diamondiferous Mesoproterozoic kimberlites from Wajrakarur kimberlite field, Eastern Dharwar craton, Southern India: genesis and constrains on mantle source regions. Contrib Mineral Petrol 157:245–265CrossRefGoogle Scholar
  9. Chalapathi Rao NV, Gibson SA, Pyle D, Dickin AP (2004) Petrogenesis of Proterozoic lamproites and kimberlites from the Cuddapah basin and Dharwar cratons, southern India. J Petrol 45:907–948CrossRefGoogle Scholar
  10. Chalapathi Rao NV, Wu FY, Mitchell RH, Li QL, Lehmann B (2013) Mesoproterozoic U–Pb ages, trace element and Sr–Nd isotopic composition of perovskite from kimberlites of the Eastern Dharwar craton, southern India: distinct mantle sources and a widespread 1.1 Ga tectonomagmatic event. Chem Geol 353:48–64CrossRefGoogle Scholar
  11. Chalapathi Rao NV, Dongre AN, Wu FY, Lehmann B (2015) A Late Cretaceous (ca. 90 Ma) kimberlite event in southern India: Implication for sub-continental lithospheric mantle evolution and diamond exploration. Gond Res. doi: 10.1016/j.gr.2015.06.006 Google Scholar
  12. Cheng Z, Zhang Z, Santosh M, Hou T, Zhang D (2014) Carbonate and silicate rich globules in the kimberlitic rocks of northwestern Tarim large igneous province NW China: evidence for carbonated mantle source. J Asian Earth Sci 95:114–135CrossRefGoogle Scholar
  13. Choudary VS, Rau TK, Bhaskara Rao KS, Sridhar M, Sinha KK (2007) Timmasamudram kimberlite cluster, Wajrakarur kimberlite field, Anantapur district, Andhra Pradesh. J Geol Soc India 69:597–610Google Scholar
  14. Coe N, Le Roex A, Gurney J, Pearson G, Nowell G (2008) Petrogenesis of theSwartruggens and Star Group II kimberlite dyke swarms, South Africa: constraints from whole rock geochemistry. Contrib Mineral Petrol 156:627–652CrossRefGoogle Scholar
  15. Das JN, Korakoppa MM, Fareeduddin SS, Srivastava JK, Gera NL (2013) Tuffisitic kimberlite from Eastern Dharwar craton, Undraldoddi area, Raichur district, Karnataka, India. In: Pearson DG, Grutter HS, Harris JW, Kjarsgaard BA, O’Brien H, Chalapathi Rao NV, Sparks S (eds) Proceeding of 10th International kimberlite conference, vol 2. Geological Society of India, Bangalore, pp 109–128CrossRefGoogle Scholar
  16. Dasgupta R, Hirschman MM, McDonough WF, Spiegelman M, Withers AC (2009) Trace element partitioning between garnet lherzolite and carbonatite at 6.6 and 8.6 GPa with applications to the geochemistry of the mantle and of mantle-derived melts. Chem Geol 262:57–77CrossRefGoogle Scholar
  17. Deer WA, Howie RA, Zussman J (1982) Rock-forming minerals, vol1A: Orthosilicates. Longman, New YorkGoogle Scholar
  18. Dey S (2013) Evolution of Archean crust in Dharwar craton: the Nd isotope record. Precambr Res 227:227–246CrossRefGoogle Scholar
  19. Dingwell DB, Brearley M (1985) Mineral chemistry of igneous melanite garnets from analcite-bearing volcanic rocks, Alberta, Canada. Contrib Mineral Petrol 90:29–35CrossRefGoogle Scholar
  20. Dongre AN, Chalapathi Rao NV, Malandkar M (2014) Petrogenesis of macrocrystic and aphanitic intrusions in Mesoproterozoic diamondiferous pipe 2 kimberlite, Wajrakarur kimberlite field, eastern Dharwar craton, southern India. Geochem J 48:491–507CrossRefGoogle Scholar
  21. Dongre AN, Jacob DE, Stern RA (2015a) Subduction related origin of eclogite xenoliths from the Wajrakarur kimberlite field, Eastern Dharwar craton, southern India: constraints from petrology and geochemistry. Geochim Cosmochim Ac 166:165–188CrossRefGoogle Scholar
  22. Dongre AN, Viljoen KS, Malandkar M (2015b) The Pipe-15 kimberlite: a new addition to Wajrakarur cluster of the Wajrakarur kimberlite field, Eastern Dharwar craton, southern India. J Geol Soc India 86:71–79CrossRefGoogle Scholar
  23. Fielding DC, Jaques AL (1989) Geology, petrology and geochemistry of the Bow Hill lamprophyre dykes, Western Australia. In: Ross J et al. (eds) Kimberlites and related rocks, Volume 1. Proceedings of the Fourth International Kimberlite Conference. Geological Society of Australia Special Publication 14:206–219Google Scholar
  24. Flohr MJK, Ross M (1989) Alkaline igneous rocks of Magnet Cove, Arkansas: Metasomatised ijolite xenoliths from Diamond Jo quarry. Am Mineral 74:113–131Google Scholar
  25. Francis D, Patterson M (2009) Kimberlites and aillikites as probes of thecontinental lithospheric mantle. Lithos 109:72–80CrossRefGoogle Scholar
  26. Friend CRL, Nutman AP (1991) SHRIMP U–Pb geochronology of the Closepet granite and peninsular gneisses, Karnataka, South of India. J Geol Soc India 38:357–368Google Scholar
  27. Gillet P, Fiquet G, Malezieux JM, Charles AG (1992) High pressure and high temperature Raman spectroscopy of end member garnets: pyrope, grossular and andradite. Eur J Mineral 4:651–664CrossRefGoogle Scholar
  28. Gopalan K, Kumar A (2008) Phlogopite K–Ca dating of Narayanpet kimberlites, South India: implications to the discordance between their Rb–Sr, Ar/Ar ages. Precambr Res 67:377–382CrossRefGoogle Scholar
  29. Grew ES, Locock AJ, Mills SJ, Galuskina IO, Galuskin EV, Halenius U (2013) Nomenclature of the garnet supergroup. Am Mineral 98:785–811CrossRefGoogle Scholar
  30. Gudfinnsson GH, Presnall DC (2005) Continuous gradations among primary carbonatitic, kimberlitic, melilititic, basaltic, picritic, and komatiitic melts in equilibrium with garnet lherzolite at 3–8 GPa. J Petrol 46:1645–1659CrossRefGoogle Scholar
  31. Gudfinnsson GH, Presnall DC (2008) Continuous gradations among primary kimberlitic, carbonatitic, melilititic and komatitic melts in equilibrium with garnet lherzolite at 3-8 Gpa. In 8th International kimberlite conference, Victoria, (Long abstract)Google Scholar
  32. Gwalani LG, Rock NMS, Ramasamy R, Griffin BJ, Mulai BP (2000) Complexly zoned Ti-rich melanite-schorlomite garnets from Ambadungar carbonatite-alkalic complex, Deccan Igneous Province, Gujarat State, Western India. J Asian Earth Sci 18:163–176CrossRefGoogle Scholar
  33. Haggerty SE (1975) The chemistry and genesis of opaque minerals in kimberlites. Phys Chem Earth 9:295–307CrossRefGoogle Scholar
  34. Haggerty SE, Birkett T (2004) Geological setting and chemistry of kimberlite clan rocks in the Dharwar Craton, India. Lithos 76:535–549CrossRefGoogle Scholar
  35. Hammond AL, Mitchell RH (2002) Accessory mineralogy of orangeitefrom Swartruggens, South Africa. Mineral Petrol 76:1–19CrossRefGoogle Scholar
  36. Jayananda M, Chardon D, Peucat J-J, Capdevila R (2006) 2.61 Ga potassic granites and crustal reworking in the western Dharwar craton, southern India: tectonic, geochronologic and tectonic constraints. Precambr Res 150:1–26CrossRefGoogle Scholar
  37. Katerinopoulou A, Katerinopoulos A, Voudouris P, Bieniok A, Musso M, Amthauer G (2009) A multi analytical study of the crystal structure of unusual Ti-Zr-Cr rich andradite from the Maronia skarn, Rhodope massif, western Thrace, Greece. Miner Petrol 95:113–124CrossRefGoogle Scholar
  38. Kaur G, Mitchell RH (2013) Mineralogy of P2 west kimberlite, Wajrakarur kimberlite field, Andhra Pradesh, India: Kimberlite or lamproite? Mineral Mag 77:3175–3196CrossRefGoogle Scholar
  39. Kaur G, Mitchell RH (2015) Mineralogy of P-12 K-Ti richterite-diopside-olivine lamproite from Wajrakarur, Andhra Pradesh, India: Implications for subduction related magmatism in eastern India. Miner Petrol. doi: 10.1007/s00710-015-0402-6 Google Scholar
  40. Kaur G, Korakoppa M, Fareeduddin, Pruseth KL (2013) Petrology of P-5 and P-13 kimberlites from Lattavaram kimberlite cluster, Wajrakarur Kimberlite Field, Andhra Pradesh, India: reclassification as lamproites. Proc 10th Int Kimberlite Conf 1:183–194CrossRefGoogle Scholar
  41. Laverne C, Grauby O, Alt JC, Bohn M (2006) Hydroschorlomite in altered basalts from Hole 1256D, ODP Leg 206: the transition from low-temperature to hydrothermal alteration. Geochem Geophys Geosyst 7:Q10003CrossRefGoogle Scholar
  42. Lazarov M, Brey GP, Weyer S (2009) Time steps of depletion and enrichment in the Kaapvaal craton as recorded by subcalcic garnets from Finsch (SA). Earth Planet Sci Lett 279:1–10CrossRefGoogle Scholar
  43. Mitchell RH (1994) Accessory rare earth. strontium. barium and zirconium minerals in the Benfontein and Wesselton calcite kimberlites. South Africa. In Meyer and Leonardos q.v . 1:115–128Google Scholar
  44. Mitchell RH (1995) Kimberlites, orangeites and related rocks. Plenum Press, New York, 410pCrossRefGoogle Scholar
  45. Mitchell RH, Meyer HOA (1989) Mineralogy of micaceous kimberlites from the New Elands and Star Mines. Orange Free State. South Africa. In: Ross J et al. (eds) Kimberlites and related rocks, Volume 1. Proceedings of the Fourth International Kimberlite Conference. Geological Society of Australia Special Publication 14:83–96Google Scholar
  46. Muntener O, Hermann J (1994) Titanian andradite in a metapyroxenite layer from the Malenco ultramafics (Italy): implications for Ti-mobility and low oxygen fugacity. Contrib Mineral Petrol 116:156–168CrossRefGoogle Scholar
  47. Naqvi SM, Rogers JJW (1987) Precambrian geology of India. Oxford University Press, New York, 223pGoogle Scholar
  48. Nayak SS, Kudari SAD (1999) Discovery of diamond-bearing kimberlites in Kalyandurg area, Anantapur district, Andhra Pradesh. Curr Sci 76:1077–1079Google Scholar
  49. Paul DK, Nayak SS, Pant NC (2006) Indian kimberlites and related rocks: petrology and geochemistry. J Geol Soc India 67:328–355Google Scholar
  50. Paul DK, Crocket JH, Reddy TAK, Pant NC (2007) Petrology and geochemistry including platinum group element abundances of the Mesoproterozoic ultramafic (lamproite) rocks of Krishna district, southern India: implications for source rock characteristics and petrogenesis. J Geol Soc India 69:577–596Google Scholar
  51. Peucat JJ, Jayananda M, Chardon D, Capdevila R, Fanning CM, Paquette JL (2013) The lower crust of Dharwar craton, southern India: patchwork of Archean granulitic domains. Precambr Res 227:4–28CrossRefGoogle Scholar
  52. Platt RG, Mitchell RH (1979) The Marathon dikes I: Zirconium-rich titanian garnets and manganoan magnesian ulvöspinel-magnetite spinels. Am Mineral 64:546–550Google Scholar
  53. Ramakrishnan M, Vaidyanadhan R (2010) Geology of India, vol 1. Geological Society of India, BangaloreGoogle Scholar
  54. Ramasamy R (1986) Titanium-bearing garnets from alkaline rocks of carbonatite complex of Tiruppattur, Tamil Nadu. Curr Sci 55:1026–1029Google Scholar
  55. Rock NMS (1986) The nature and origin of ultramafic lamprophyres: alnöites and allied rocks. J Petrol 27:155–196CrossRefGoogle Scholar
  56. Rock NMS (1991) Lamprophyres. Blackie, Glasgow, 285pCrossRefGoogle Scholar
  57. Russell JK, Dipple GM, Lang JR, Lueck B (1999) Major-element discrimination of titanian andradite from magmatic and hydrothermal environments: an example from the Canadian Cordillera. Eur J Mineral 11:919–935CrossRefGoogle Scholar
  58. Schulze D (2003) A classification scheme for mantle-derived garnets in kimberlite: a tool for investigating the mantle and exploring for diamonds. Lithos 71:195–213CrossRefGoogle Scholar
  59. Shebanova ON, Lazor P (2003) Raman study of magnetite (Fe3O4): laser induced thermal effects and oxidation. J Raman Spectro 34:845–852CrossRefGoogle Scholar
  60. Smith CB, Haggerty SE, Chatterjee B, Beard A, Townend R (2013) Kimberlite, lamproite, ultramafic lamprophyre, and carbonatite relationships on the Dharwar Craton, India; an example from the Khaderpet pipe, a diamondiferous ultramafic with associated carbonatite intrusion. Lithos 182–183:102–113CrossRefGoogle Scholar
  61. Sorensen H (1974) The alkaline rocks. Wiley, LondonGoogle Scholar
  62. Stripp GR, Field M, Schumacher JC, Sparks RSJ, Cressey G (2006) Post-emplacement serpentinization and related hydrothermal metamorphism in a kimberlite from Venetia, South Africa. J Metamorph Geol 24:515–534CrossRefGoogle Scholar
  63. Tappe S, Jenner GA, Foley SF, Heaman LM, Besserer D, Kjarsgaard BA, Ryan AB (2004) Torngat ultramafic lamprophyres and their relation to the North Atlantic Alkaline Province. Lithos 76:491–518CrossRefGoogle Scholar
  64. Tappe S, Foley SF, Jenner GA, Kjarsgaard BA (2005) Integrating ultramafic lamprophyres into the IUGS classification of igneous rocks: rational and implications. J Petrol 46:1893–1900CrossRefGoogle Scholar
  65. Tappe S, Foley SF, Jenner GA, Heaman LM, Kjarsgaard BA, Romer RL, Stracke A, Joyce N, Hoefs J (2006) Genesis of ultramafic lamprophyres and carbonatites at Aillik Bay, Labrador: a consequence of incipient lithospheric thinning beneath the North Atlantic craton. J Petrol 47:1261–1315CrossRefGoogle Scholar
  66. Tappe S, Foley SF, Kjarsgaard BA, Romer RL, Heaman LM, Stracke A, Jenner GA (2008) Between carbonatite and lamproite—diamondiferous Torngat ultramafic lamprophyres formed by carbonate-fluxed melting of cratonic MARID-type metasomes. Geochim Cosmochim Ac 72:3258–3286CrossRefGoogle Scholar
  67. Tappe S, Steenfelt A, Heaman LM, Simonetti A (2009) The newly discovered Jurassic Tikiusaaq carbonatite-aillikite occurrence, West Greenland, and some remarks on carbonatite-kimberlite relationship. Lithos 112:385–399CrossRefGoogle Scholar
  68. Ulrych J, Povondra P, Rutsek J, Pivec E (1988) Melilitic and melilite bearing subvolcanic rocks from the Ploucnice river region. Czechoslovakia Acta Univ Caro Geol 195–231Google Scholar
  69. Ulrych J, Povondra P, Pivec E, Rutsek J, Sitek J (1994) Compositional evolution of metasomatic garnet in melilitic rocks of the O’secna complex, Bohemia. Can Mineral 32:637–647Google Scholar

Copyright information

© Springer-Verlag Wien 2016

Authors and Affiliations

  • Ashish N. Dongre
    • 1
  • K. S. Viljoen
    • 1
  • N. V. Chalapathi Rao
    • 2
  • A. Gucsik
    • 1
  1. 1.Department of GeologyUniversity of JohannesburgAuckland ParkSouth Africa
  2. 2.Department of Geology, Center of Advanced StudyBanaras Hindu UniversityVaranasiIndia

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