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Synthesis of New Functionalized Compounds Related to p-Extended Tetrathiafulvalenes with Quinonoidal Structures Bearing a Ferrocene Moiety

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Summary.

 A number of π-extended conjugated tetrathiafulvalene (TTF) analogues were synthesized as new π-donors, and their structures and physical properties were determined. UV/Vis spectra and cyclic voltammetry of the π-extended ferrocenyl donors were studied in comparison with ferrocene, ferrocenylquinone, and the parent donor. A three-electron redox behaviour was observed. The absorption spectrum of the new donor 16 showed a slight red-shift and a slight increase in intensity relative to the compared compounds.

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Authors and Affiliations

  1. Department of Chemistry and Chemical Engineering, Faculty of Engineering, Yamagata University, Yonezawa 992-8510, Japan, , , , , , JP

    Abd El-Wareth A. O. Sarhan, Makoto Murakami & Taeko Izumi

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  1. Abd El-Wareth A. O. Sarhan
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  2. Makoto Murakami
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  3. Taeko Izumi
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Received September 19, 2001. Accepted (revised) October 23, 2001

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Sarhan, AW., Murakami, M. & Izumi, T. Synthesis of New Functionalized Compounds Related to p-Extended Tetrathiafulvalenes with Quinonoidal Structures Bearing a Ferrocene Moiety. Monatshefte fuer Chemie 133, 1055–1066 (2002). https://doi.org/10.1007/s007060200074

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  • DOI: https://doi.org/10.1007/s007060200074

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