Summary.
Anhydrous 1,6-hexanediammonium dihydrogendecavanadate ((HdaH2)2H2V10O28, 1) was prepared by reaction of V2O5 with 1,6-hexanediamine in aqueous solution. The crystal structure of 1 was determined, and the proton positions in the H2V10O28 4− anion were calculated by the bond length/bond number method. The protons are bound to the centrosymmetrically oriented μ–OV3 groups of the decavanadate anion. Based on the analysis of IR spectra of 1 prepared from H2O and D2O, the absorption band at 871 cm−1 can be attributed to δ(V–Ob–H) vibrations.
Similar content being viewed by others
Author information
Authors and Affiliations
Additional information
Received August 3, 2001. Accepted (revised) October 8, 2001
Rights and permissions
About this article
Cite this article
Rakovský, E., Žúrková, Ľ. & Marek, J. Synthesis, Crystal Structure, and IR Spectroscopic Characterization of 1,6-Hexanediammonium Dihydrogendecavanadate. Monatshefte fuer Chemie 133, 277–283 (2002). https://doi.org/10.1007/s007060200005
Issue Date:
DOI: https://doi.org/10.1007/s007060200005