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Starch-supported cuprous iodide nanoparticles catalysed C–C bond cleavage: use of carbon-based leaving groups for bisindolylmethane synthesis

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Abstract

A starch-supported cuprous iodide nanoparticles (CuI-NPs@starch) catalysed C–C bond cleaving reaction involving carbon-based leaving groups like malononitrile, ethyl cyanoacetate, acetylacetone, and Meldrum’s acid has been developed under moisture and air insensitive conditions. This competent C–C bond cleavage reaction is studied in detail as an attractive alternative method to synthesize biologically relevant bisindolylmethanes in moderate to good yields. The CuI-NPs@starch are synthesized in aqueous medium and characterized by X-ray powder diffraction, scanning electron microscopy, energy-dispersive X-ray spectroscopy studies.

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Acknowledgements

The authors gratefully acknowledge the financial support from Science & Engineering Research Board (Grant CRG/2023/001214 & YSS/2015/001425).

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Authors and Affiliations

  1. Department of Chemistry, Central University of Jharkhand, Ranchi, Jharkhand, India

    Muthiah Suresh, Raj Bahadur Singh, Snigdha Rani Patra, Yogesh Bhaskar Singh Tanwer & Sabyasachi Bhunia

  2. Department of Physics, University College of Science, Saifabad Osmania University, Hyderabad, India

    Sadhana Katlakunta

  3. Department of Chemistry, Indira Gandhi National Tribal University (Central University), Amarkantak, India

    Sadhucharan Mallick

  4. Triveni Devi Bhalotia College, Raniganj, India

    Debjit Das

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  1. Muthiah Suresh
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  2. Raj Bahadur Singh
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  3. Sadhana Katlakunta
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  4. Snigdha Rani Patra
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  5. Yogesh Bhaskar Singh Tanwer
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  6. Sadhucharan Mallick
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  7. Sabyasachi Bhunia
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  8. Debjit Das
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Correspondence to Debjit Das.

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Suresh, M., Singh, R.B., Katlakunta, S. et al. Starch-supported cuprous iodide nanoparticles catalysed C–C bond cleavage: use of carbon-based leaving groups for bisindolylmethane synthesis. Monatsh Chem (2024). https://doi.org/10.1007/s00706-024-03215-2

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