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Simultaneous determination of 4-aminophenol and paracetamol based on CS-Ni nanocomposite-modified screen-printed disposable electrodes

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Abstract

In the present work, chitosan-coated nickel nanoparticles (CS-Ni) were successfully prepared onto screen-printed electrode (SPE) by electrodeposition method with the assistance of an anionic surfactant of sodium dodecyl sulfate (SDS) for the individual and simultaneous sensing of 4-aminophenol (4-AP) and paracetamol (PA). The as-prepared sensor was characterized via scanning electron microscopy, X-ray diffraction, and fourier transform infrared techniques. The electrochemical catalytic behaviors of the 4-AP and PA on the fabricated NiNPs-SDS/CS/SPE electrode were explored using cyclic voltammetry (CV), differential pulse voltammetry (DPV), and electrochemical impedance spectroscopy (EIS). The NiNPS-SDS/CS modified screen-printed electrode demonstrated excellent electrocatalytic activity for 4-AP and PA, indicating that nickel microstructures have a high specific surface area, excellent electrical conductivity, and high electrocatalytic activity. The results indicate that CV and DPV could be easily applied to determine 4-AP and PA using the fabricated sensor under optimized conditions. However, CV is preferred for both analysts’ sensing, with the largest linear range from 1 to 500 μM for 4-AP (R2 = 0.999) and 1 μM to 2 mM (R2 = 0.997) for PA, respectively. In terms of sensitivity and detection limit, DPVs response appeared to be a better technique choice, as it revealed the highest sensitivity values of 0.959 µA µM−1 cm−2 for 4-AP and 1.163 µA µM−1 cm−2 for PA, with the lowest detection limits of 0.06 and 0.04 μM for 4-AP and PA (S/N = 3), respectively. With a high recovery rate, good selectivity, excellent reproducibility, and strong anti-interference ability, the modified sensor was successfully applied to the simultaneous detection of 4-AP and PA in pharmaceutical tablets. It is expected to be widely used in actual sample detection.

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Data availability

The data that support the findings of this study are available from the corresponding author, upon reasonable request.

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Acknowledgements

We are very grateful to the financial support within the General Direction of Scientific Research and Technology Development of the Algerian ministry of higher education and scientific research.

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Authors and Affiliations

  1. Laboratory of Industrial Analysis and Materials Engineering, University May 8, 1945 Guelma, P.O.B. 401, 24000, Guelma, Algeria

    Sarra Abdi, Mohamed Lyamine Chelaghmia, Rafiaa Kihal, Mouna Nacef, Abed Mohamed Affoune & Mohamed E. H. Benhamza

  2. Abbes Laghrour University Khenchela, Road of Batna, P.O.B 1252, 40004, Khenchela, Algeria

    Rafiaa Kihal

  3. Faculty of Science and Engineering, Manchester Metropolitan University, Chester Street, Manchester, M1 5GD, UK

    Craig E. Banks & Alejandro Garcia-Miranda Ferrari

  4. Laboratory of Applied Chemistry, University May 8, 1945 Guelma, P.O.B. 401, 24000, Guelma, Algeria

    Hassina Fisli

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  1. Sarra Abdi
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Correspondence to Mohamed Lyamine Chelaghmia.

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Abdi, S., Chelaghmia, M.L., Kihal, R. et al. Simultaneous determination of 4-aminophenol and paracetamol based on CS-Ni nanocomposite-modified screen-printed disposable electrodes. Monatsh Chem 154, 563–575 (2023). https://doi.org/10.1007/s00706-023-03062-7

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  • DOI: https://doi.org/10.1007/s00706-023-03062-7

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