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Synthesized f-MWCNTs/CS/PB for determination of manganese (Mn2+) in drinking water

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Abstract

In this research, the manganese ion (Mn2+) in drinking water was detected using functionalized multiwalled carbon nanotubes (f-MWCNTs) and chitosan (CS) immobilised with Prussian blue. Drinking water that contained soluble manganese (Mn2+) became insoluble (Mn3+ and Mn4+) when water phytochemistry changed as a result of unpredictably high manganese emissions from human activities into the environment. Manganese toxicity has been associated with brain disorders and metabolic activity. Electrochemical parameters such as (0.1 M, pH 2) phosphate buffer saline supported 5 mM Prussian blue, scan rate = 250 mV s−1, accumulation time = 20 s, and volume 10 cm3 were optimized using the cyclic voltammetry method. The f-MWCNTs/CS/PB generated highest current signal followed by PB/AuE and AuE. The stability of f-MWCNTs/CS/PB showed less than 7% for repeatability and reproducibility. Also, f-MWCNTs/CS/PB/AuE was selective towards Mn2+ with no inferring activity detected. However, this sensor can only be kept for 14 days due to the decreased current signals. Differential pulse voltammetry method was used to detect different amounts of Mn2+ ranging from 0.2 to 3 ppm under optimal conditions. The limit of detection (LOD) was found to be 2.60 × 10–6 M, with correlation coefficient (0.2–1 ppm) y = 0.0413x + 0.0734, with R2 = 0.9679. The percent recovery of a drinking water sample ranges from 94.87 to 100.4%. The modified electrode (f-MWCNTs/CS/PB/AuE) has various advantages for detecting Mn2+ in drinking water, including a simple procedure, less operating time, high sensitivity and selectivity.

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Acknowledgements

The authors would like to acknowledge the authority of Biotechnology Research Institute (BRI), Universiti Malaysia Sabah (UMS) for providing necessary research facilities.

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Authors and Affiliations

  1. Biotechnology Research Institute, Universiti Malaysia Sabah, Kota Kinabalu, Sabah, Malaysia

    Gilbert Ringgit, Shafiquzzaman Siddiquee & Suryani Saallah

  2. Borneo Research Marine Institute, Universiti Malaysia Sabah, Kota Kinabalu, Sabah, Malaysia

    Mohammad Tamrin Mohamad Lal

  3. Environmental Horticulture, Kinsley School of Engineering, Sciences and Technology, York College of Pennsylvania, York, PA, 17403, USA

    Most Tahera Naznin

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  1. Gilbert Ringgit
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  2. Shafiquzzaman Siddiquee
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  3. Suryani Saallah
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Correspondence to Shafiquzzaman Siddiquee.

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Ringgit, G., Siddiquee, S., Saallah, S. et al. Synthesized f-MWCNTs/CS/PB for determination of manganese (Mn2+) in drinking water. Monatsh Chem 154, 191–203 (2023). https://doi.org/10.1007/s00706-022-03026-3

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  • DOI: https://doi.org/10.1007/s00706-022-03026-3

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