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Optical, electrochemical, and sensing properties of (E)‐2‐[[(4-hydroxyphenyl)imino]methyl]phenol for the detection of iodide ions

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Abstract

An electrochemical sensor based on (E)-2-[[(4-hydroxyphenyl)imino]methyl]phenol (anil) was developed for the detection of iodide anions. The complexation ability of the anil with I−, Br−, Cl−, CN−, SCN−,\({\mathrm{NO}}_{3}^{-}\), CH3COO−,\({\mathrm{SO}}_{4}^{2-}\), F−, and S2− was explored by UV–Vis spectroscopy. The results showed that the proposed probe has high sensibility for the detection of I−, with the absorption intensity changing due to the formation of anil–I− complex. The anil and iodide anion bind by a 1:1 complex stoichiometry and the association constant is determined to be 8.5 × 103 M−1. In addition, the sensing film was elaborated by drop coating on a platinum electrode. The electrochemical sensors for the detection of I− were analyzed by DPV. It showed a linear response in the range of 1 × 10–7 to 1 × 10–4 M, with a low detection limit of 4 × 10–8 M. The sensor shows good analytical performance. The developed sensor is suitable for application in water quality monitoring.

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Acknowledgements

Financial support of this research from the Ministry of Higher Education and Scientific Research of Tunisia.

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Authors and Affiliations

  1. NANOMISENE Lab, LR16CRMN01, Centre for Research on Microelectronics and Nanotechnology CRMN of Technopark of Sousse, Sahloul, B.P. 334, 4034, Sousse, Tunisia

    Mosaab Echabaane

  2. Laboratory of Advanced Materials and Interfaces (LIMA), Faculty of Sciences of Monastir, University of Monastir, Avenue of the Environment, 5000, Monastir, Tunisia

    Nadhem Moulahi & Rafik Ben Chaâbane

  3. Research Unit Materials and Organic Synthesis (UR17ES31), Preparatory Institute for Engineering Studies of Monastir, University of Monastir, Avenue of the Environment, 5000, Monastir, Tunisia

    Mohamed Hassen V. Baouab

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  1. Mosaab Echabaane
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  2. Nadhem Moulahi
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  3. Mohamed Hassen V. Baouab
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  4. Rafik Ben Chaâbane
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Correspondence to Mosaab Echabaane.

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Echabaane, M., Moulahi, N., Baouab, M.H.V. et al. Optical, electrochemical, and sensing properties of (E)‐2‐[[(4-hydroxyphenyl)imino]methyl]phenol for the detection of iodide ions. Monatsh Chem 153, 561–567 (2022). https://doi.org/10.1007/s00706-022-02937-5

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  • DOI: https://doi.org/10.1007/s00706-022-02937-5

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