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An innovative approach to use zeolite as crosslinker for synthesis of p(HEMA-co-NIPAM) hydrogel

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Abstract

This study introduced a modified method to synthesize organic–inorganic hybrid crosslinker based on zeolite. First, zeolite nanoparticles were modified with 3-(aminopropyl)trimethoxysilane. Then, the amine-functionalized zeolite has been reacted with the glycidyl methacrylate via an epoxide ring-opening mechanism. The vinyl-functionalized zeolite was applied as a crosslinking agent to form hydrogel network. A novel temperature-sensitive nanocomposite hydrogel was prepared by crosslinking N-isopropylacrylamide as a comonomer and 2-hydroxyethyl methacrylate as a monomer with free-radical polymerization. Results showed that p(2-hydroxyethyl methacrylate-co–N-isopropylacrylamide)/vinyl-functionalized zeolite nanocomposite hydrogel has a chemically crosslinked and porous network structure. The content of crosslinker and monomers had obvious effects on the swelling ratio of the nanocomposite hydrogel. The temperature and salt-sensitive behavior of the hydrogels are also discussed. We offer a multifunctional crosslinker for preparing sensitive materials that can serve biomedical or environmental applications.

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Acknowledgements

The authors thank the support of the Çanakkale Onsekiz Mart University Scientific Research Coordination Unit (project number: FBA-2020-3274).

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Authors and Affiliations

  1. School of Graduate Studies, Department of Bioengineering and Materials Engineering, Canakkale Onsekiz Mart University, Canakkale, Turkey

    Seçil Durmuş & Betül Yılmaz

  2. Laboratory of Inorganic Materials, Department of Chemistry, Faculty of Science and Arts, Canakkale Onsekiz Mart University, Canakkale, Turkey

    Alper Onder, Hava Ozay & Ozgur Ozay

  3. Department of Chemistry and Chemical Processing Technologies, Lapseki Vocational School, Canakkale Onsekiz Mart University, Lapseki, Canakkale, Turkey

    Pinar Ilgin

  4. Department of Bioengineering, Faculty of Engineering, Canakkale Onsekiz Mart University, Canakkale, Turkey

    Ozgur Ozay

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  1. Seçil Durmuş
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  2. Betül Yılmaz
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  3. Alper Onder
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  4. Pinar Ilgin
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  5. Hava Ozay
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Correspondence to Pinar Ilgin.

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Durmuş, S., Yılmaz, B., Onder, A. et al. An innovative approach to use zeolite as crosslinker for synthesis of p(HEMA-co-NIPAM) hydrogel. Monatsh Chem 153, 369–382 (2022). https://doi.org/10.1007/s00706-022-02908-w

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  • DOI: https://doi.org/10.1007/s00706-022-02908-w

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