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Voltammetric study of the affinity of divalent heavy metals for guanine-functionalized iron oxide nanoparticles

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Abstract

In this study, a novel nanobiomaterial based on (3-aminopropyl)triethoxysilane (APTES)-coated iron oxide (Fe3O4) nanoparticles functionalized with newly synthesized guanine hydrazide (GH) was elaborated. A boron-doped diamond electrode coated with GH-APTES–Fe3O4 nanoparticles was used to assess the interaction of heavy metal ions with guanine hydrazide. The adsorption isotherms were electrochemically investigated and it was shown that the adsorption capacity of the nanoparticles towards heavy metals decreased in the following order: Cu2+ > Pb2+ > Cd2+. From the calibration curves, the sensitivities of detection were as follows: 171.6 µA/µM for Cu(II), 156 µA/µM for Pb(II), and 101.4 µA/µM for Cd(II).

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Acknowledgements

The authors acknowledge the financial support of the EU H2020 research and innovation program entitled Kardia Tool Grant #768686.

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Authors and Affiliations

  1. Institute of Analytical Sciences, University of Lyon, 5, rue de la Doua, 69100, Villeurbanne, France

    Simona Sawan, Abdelhamid Errachid & Nicole Jaffrezic-Renault

  2. Department of Sciences, Faculty of Natural and Applied Sciences, Notre Dame University-Louaize, Zouk Mosbeh, Lebanon

    Simona Sawan, Rayyan Boukarroum & Rita Maalouf

  3. Department of Chemistry, American University of Beirut, Beirut, 11-0236, Lebanon

    Khalil Hamze, Ali Youssef & Kamal Bouhadir

Authors
  1. Simona Sawan
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  2. Khalil Hamze
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  3. Ali Youssef
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  4. Rayyan Boukarroum
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  5. Kamal Bouhadir
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  6. Abdelhamid Errachid
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  7. Rita Maalouf
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  8. Nicole Jaffrezic-Renault
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Correspondence to Rita Maalouf or Nicole Jaffrezic-Renault.

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Sawan, S., Hamze, K., Youssef, A. et al. Voltammetric study of the affinity of divalent heavy metals for guanine-functionalized iron oxide nanoparticles. Monatsh Chem 152, 229–240 (2021). https://doi.org/10.1007/s00706-021-02738-2

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  • DOI: https://doi.org/10.1007/s00706-021-02738-2

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